Fabrication of a polyvinylidene fluoride tree-like nanofiber web for ultra high performance air filtration

RSC Advances ◽  
2016 ◽  
Vol 6 (94) ◽  
pp. 91243-91249 ◽  
Author(s):  
Zongjie Li ◽  
Weimin Kang ◽  
Huihui Zhao ◽  
Min Hu ◽  
Jingge Ju ◽  
...  
Keyword(s):  
Polyvinylidene Fluoride ◽  
High Performance ◽  
Air Filtration ◽  
One Step ◽  
Nanofiber Web

A novel polyvinylidene fluoride tree-like nanofiber web for high performance air filtration was successfully fabricated via one-step electrospinning.

Branched nanofibers with tiny diameters for air filtration via one-step electrospinning

2020 ◽  
pp. 152808372092377
Author(s):  
Bilal Zaarour ◽  
Hussen Tina ◽  
Lei Zhu ◽  
XiangYu Jin
Keyword(s):  
Sodium Chloride ◽  
Pressure Drop ◽  
Polyvinylidene Fluoride ◽  
Filtration Efficiency ◽  
Air Filtration ◽  
Air Filter ◽  
One Step ◽  
Tetrabutylammonium Chloride ◽  
Filtration Properties ◽  
Branched Structure

Engineering the surface morphology of fibers has been attracting significant consideration in various areas and applications. In this study, polyvinylidene fluoride (PVDF) branched nanofibers with a diameter of less than 50 nm are electrospun directly at a low relative humidity by adding tetrabutylammonium chloride. The effects of the branched structure on the specific surface area and pore size distribution are investigated, and the filtration properties of the air filter based on branched nanofiber webs with different basis weights are studied. The results exhibit that the air filter based on PVDF branched nanofibers with the basis weight of 1 g/m2 has an outstanding filtration efficiency (99.999%) to 0.26 µm sodium chloride particles under the pressure drop of 126.17 Pa. We believe that this study can be used as a useful reference for the preparation of branched nanofibers through one-step electrospinning.

Preparation of multifunctional AgNPs/PAN nanofiber membrane for air filtration by one-step process

2020 ◽  
Vol 49 (5) ◽  
pp. 355-361
Author(s):  
Wenxiu Yang ◽  
Lin Li ◽  
Shuo Wang ◽  
Jinshu Liu
Keyword(s):  
Composite Membrane ◽  
Air Conditioning ◽  
High Performance ◽  
Antibacterial Property ◽  
Air Filtration ◽  
Nanofiber Membrane ◽  
Content Type ◽  
Composite Nanofiber ◽  
One Step ◽  
Pan Nanofiber

Purpose The purpose of this paper is to fabricate a high-performance filtration electrospun nanofiber membrane with antibacterial function. The Ag nanoparticles (AgNPs) gotten by reducing AgNO3 act as antimicrobial agent. Then the AgNPs/Polyacrylonitrile (AgNPs/PAN) composite nanofiber membrane was prepared by electrospinning. Design/methodology/approach The electrospun Ag/PAN composite membrane was prepared by one step, in which the Ag particles were acting as antibacterial agent and PAN nanofiber as the upholder of the composite mat. AgNPs were obtained by reducing AgNO3 in N,N-Dimethylformamide (DMF) solution at high temperature. Meanwhile, the PAN particles were added to DMF solution and dissolved. Then the Ag/PAN nanofiber was obtained by electrospinning. Findings The thinner nanofiber can be produced with PAN concentration of 12 per cent and AgNPs concentration of 10 per cent. Finally, the filtration resistance of the composite membrane with antibacterial property is as high as 99.1 per cent, and the filtration efficiency is only 83 Pa. Therefore, the AgNPs/PAN composite membrane is the ideal choice for air filtration with antibacterial property. Originality/value The AgNPs/PAN composite nanofiber membrane has high filtration performance for particulate matter (PM)25 and outstanding antibacterial property to Escherichia coli and Staphylococcus aureus, which can be used with masks, air-conditioning filters (including car air-conditioning filters), window screening and other similar objects.

scholarly journals N, S and Transition-Metal Co-Doped Graphene Nanocomposites as High-Performance Catalyst for Glucose Oxidation in a Direct Glucose Alkaline Fuel Cell

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 202
Author(s):  
Yexin Dai ◽  
Jie Ding ◽  
Jingyu Li ◽  
Yang Li ◽  
Yanping Zong ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Active Sites ◽  
High Performance ◽  
Glucose Oxidation ◽  
Alkaline Fuel Cell ◽  
Blank Group ◽  
Graphene Nanocomposites ◽  
Doped Graphene ◽  
One Step ◽  
Hydrothermal Approach

In this work, reduced graphene oxide (rGO) nanocomposites doped with nitrogen (N), sulfur (S) and transitional metal (Ni, Co, Fe) were synthesized by using a simple one-step in-situ hydrothermal approach. Electrochemical characterization showed that rGO-NS-Ni was the most prominent catalyst for glucose oxidation. The current density of the direct glucose alkaline fuel cell (DGAFC) with rGO-NS-Ni as the anode catalyst reached 148.0 mA/cm2, which was 40.82% higher than the blank group. The DGAFC exhibited a maximum power density of 48 W/m2, which was more than 2.08 folds than that of blank group. The catalyst was further characterized by SEM, XPS and Raman. It was speculated that the boosted performance was due to the synergistic effect of N, S-doped rGO and the metallic redox couples, (Ni2+/Ni3+, Co2+/Co3+ and Fe2+/Fe3+), which created more active sites and accelerated electron transfer. This research can provide insights for the development of environmental benign catalysts and promote the application of the DGAFCs.

scholarly journals Facile Synthesis of Uniform Mesoporous Nb2O5 Micro-Flowers for Enhancing Photodegradation of Methyl Orange

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3783
Author(s):  
Jian-Qing Qiu ◽  
Huan-Qing Xie ◽  
Ya-Hao Wang ◽  
Lan Yu ◽  
Fang-Yuan Wang ◽  
...  
Keyword(s):  
Methyl Orange ◽  
Active Sites ◽  
High Performance ◽  
Diffuse Reflectance Spectroscopy ◽  
X Ray Diffraction ◽  
Flower Structure ◽  
Electron Microscopies ◽  
Bet Method ◽  
One Step ◽  
Catalytic Active Sites

The removal of organic pollutants using green environmental photocatalytic degradation techniques urgently need high-performance catalysts. In this work, a facile one-step hydrothermal technique has been successfully applied to synthesize a Nb2O5 photocatalyst with uniform micro-flower structure for the degradation of methyl orange (MO) under UV irradiation. These nanocatalysts are characterized by transmission and scanning electron microscopies (TEM and SEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) method, and UV-Vis diffuse reflectance spectroscopy (DRS). It is found that the prepared Nb2O5 micro-flowers presents a good crystal phases and consist of 3D hierarchical nanosheets with 400–500 nm in diameter. The surface area is as large as 48.6 m2 g−1. Importantly, the Nb2O5 micro-flowers exhibit superior catalytic activity up to 99.9% for the photodegradation of MO within 20 mins, which is about 60-fold and 4-fold larger than that of without catalysts (W/O) and commercial TiO2 (P25) sample, respectively. This excellent performance may be attributed to 3D porous structure with abundant catalytic active sites.

One-step Synthesis of Amorphous Nickel Iron Phosphide Hierarchical Nanostructures for Water Electrolysis with Superb Stability at High Current Density

2021 ◽  
Author(s):  
Yuefeng Yu ◽  
Xun He ◽  
Rong Li ◽  
Xinglong Gou
Keyword(s):  
High Performance ◽  
High Current Density ◽  
Water Electrolysis ◽  
Bifunctional Catalysts ◽  
High Current ◽  
Hierarchical Nanostructures ◽  
Iron Phosphide ◽  
Nickel Iron ◽  
Metal Free ◽  
One Step

Development of noble-metal-free high-performance bifunctional catalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is essential but challenging for hydrogen production from water electrolysis. Herein, amorphous bimetallic...

scholarly journals Computational and experimental investigations of one-step conversion of poly(carbonate)s into value-added poly(aryl ether sulfone)s

2016 ◽  
Vol 113 (28) ◽  
pp. 7722-7726 ◽  
Author(s):  
Gavin O. Jones ◽  
Alexander Yuen ◽  
Rudy J. Wojtecki ◽  
James L. Hedrick ◽  
Jeannette M. García
Keyword(s):  
High Performance ◽  
Density Functional ◽  
Value Added ◽  
Single Step ◽  
Nucleophilic Attack ◽  
Experimental Investigations ◽  
Aryl Ether ◽  
One Step ◽  
Poly Carbonate

It is estimated that ∼2.7 million tons poly(carbonate)s (PCs) are produced annually worldwide. In 2008, retailers pulled products from store shelves after reports of bisphenol A (BPA) leaching from baby bottles, reusable drink bottles, and other retail products. Since PCs are not typically recycled, a need for the repurposing of the PC waste has arisen. We report the one-step synthesis of poly(aryl ether sulfone)s (PSUs) from the depolymerization of PCs and in situ polycondensation with bis(aryl fluorides) in the presence of carbonate salts. PSUs are high-performance engineering thermoplastics that are commonly used for reverse osmosis and water purification membranes, medical equipment, as well as high temperature applications. PSUs generated through this cascade approach were isolated in high purity and yield with the expected thermal properties and represent a procedure for direct conversion of one class of polymer to another in a single step. Computational investigations performed with density functional theory predict that the carbonate salt plays two important catalytic roles in this reaction: it decomposes the PCs by nucleophilic attack, and in the subsequent polyether formation process, it promotes the reaction of phenolate dimers formed in situ with the aryl fluorides present. We envision repurposing poly(BPA carbonate) for the production of value-added polymers.

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