Syntheses, structures and magnetic properties of symmetrical Schiff-base supported dinuclear Ln(iii) compounds

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103035-103041 ◽  
Author(s):  
Shuang-Yan Lin ◽  
Chunlai Wang ◽  
Zhikun Xu

Two dinuclear Dy(iii) compounds bridged by respective syn–syn η1:η1-µ2-benzoato and µ2-O alkoxido groups have been synthesized by symmetrical two-arm and four-arm ligands, respectively, which show field-induced slow relaxation phenomenon.

2019 ◽  
Vol 48 (31) ◽  
pp. 11637-11641 ◽  
Author(s):  
Ahlem-Linda Boulkedid ◽  
Adel Beghidja ◽  
Chahrazed Beghidja ◽  
Yannick Guari ◽  
Joulia Larionova ◽  
...  

We report the synthesis, structure and magnetic properties of a series of heteroleptic Zn2+/Ln3+ complexes of the formula [ZnLClLn(o-van)(H2O)(NO3)]·H2O exhibiting slow relaxation of their magnetization.


1983 ◽  
Vol 48 (7) ◽  
pp. 2021-2027 ◽  
Author(s):  
Eliška Kálalová ◽  
Olga Populová ◽  
Štěpánka Štokrová ◽  
Pavel Stopka

Copper(II) and nickel(II) ions were bonded in complexes of salicylideneimine type on a glycidyl methacrylate-ethylenedimethacrylate copolymer. The geometry of the complexes on the polymer was studied by measuring their magnetic properties, EPR spectra, and ultraviolet-visible spectra.Only paramagnetic complexes possessing a pseudo-tetrahedral configuration were found. The effect of the polymer matrix and of the immobility of the bonded Schiff base on the distortion of the coordination sphere of the central ion is discussed.


2007 ◽  
Vol 180 (10) ◽  
pp. 2973-2977 ◽  
Author(s):  
Wei Li ◽  
Zongwei Li ◽  
Licun Li ◽  
Daizheng Liao ◽  
Zonghui Jiang

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