Green organic light-emitting devices with external quantum efficiency up to nearly 30% based on an iridium complex with a tetraphenylimidodiphosphinate ligand

RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63200-63205 ◽  
Author(s):  
Yanan Li ◽  
Liang Zhou ◽  
Yunlong Jiang ◽  
Rongzhen Cui ◽  
Xuesen Zhao ◽  
...  

High performance green electroluminescent device with maximum brightness, current efficiency, power efficiency and external quantum efficiency (EQE) up to 113 610 cd m−2, 112.30 cd A−1, 97.95 lm W−1 and 29.4%, was realized.

2014 ◽  
Vol 5 (12) ◽  
pp. 4819-4830 ◽  
Author(s):  
Gang Cheng ◽  
Steven C. F. Kui ◽  
Wai-Hung Ang ◽  
Man-Ying Ko ◽  
Pui-Keong Chow ◽  
...  

Practical strongly phosphorescent platinum(II) green to white OLED emitters with bulky tetradentate O^N^C^N ligands.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4615
Author(s):  
Dovydas Blazevicius ◽  
Daiva Tavgeniene ◽  
Simona Sutkuviene ◽  
Ernestas Zaleckas ◽  
Ming-Ruei Jiang ◽  
...  

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m2. The most efficient green PhOLED with 10 wt% of Ir(ppy)3 {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m2, which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.


Author(s):  
Xiaokang Li ◽  
Wenxing Liu ◽  
Kai Chen ◽  
Ruixia Wu ◽  
Guo-Jun Liu ◽  
...  

Abstract In this work, we have experimentally demonstrated the efficacy of micro-cavity effect in realizing high-performance top-emitting organic light-emitting diodes (TEOLEDs). By optimizing the thickness of top Yb/Ag electrode and cavity length, highly efficient green TEOLED with external quantum efficiency as high as 38% was achieved. A strong dependence of electroluminescent (EL) performances and spectrum on cavity length was observed, and there was also a significant angle dependence of EL spectrum. Ultimately, ultra-high current efficiency up to 161.17 cd/A (3.2 V) was obtained by the device with emission peak at 552 nm, which is 35 nm longer than the intrinsic emission peak (517 nm) of utilized green emitter. Interestingly, this device displayed narrow emission with full-width at half-maximum (FWHM) of less than 20 nm, which was obtained by increasing the Ag layer thickness.


2017 ◽  
Vol 5 (46) ◽  
pp. 12050-12056 ◽  
Author(s):  
Chih-Chien Lee ◽  
Chun-Jen Shih ◽  
Gautham Kumar ◽  
Sajal Biring ◽  
Somaditya Sen ◽  
...  

An exciplex-forming phosphorescent OLED with nano-pinhole sputtered ITO exhibiting a maximum external quantum efficiency (power efficiency) of 34% (132.8 lm W−1) was achieved.


2013 ◽  
Vol 2013 ◽  
pp. 1-6
Author(s):  
Qi Wang ◽  
Junsheng Yu ◽  
Ming Li ◽  
Zhiyun Lu

Highly efficient phosphorescent organic light-emitting devices (PhOLEDs) had been fabricated by using a novel iridium complex, bis[2-(3′,5′-di-tert-butylbiphenyl-4-yl)benzothiazolato-N,C2′]iridium(III) (acetylacetonate) [(tbpbt)2Ir(acac)], as the emitter. With a wide doping ratio ranging from 15 wt% to 25 wt%, the PhOLEDs maintained a comparable high performance, indicating concentration-insensitive property of the (tbpbt)2Ir(acac). On the basis of the unique characteristic of concentration insensitivity, the application of this phosphor was explored by fabricating white organic light-emitting devices (WOLEDs) with altered doping ratio, indicating that trap effect of (tbpbt)2Ir(acac) could effectively tailor WOLEDs spectra. Typically, a high-power efficiency, current efficiency, and external quantum efficiency of 30.0 lm/W, 38.8 cd/A, 18.1%, were achieved by 20 wt% doped WOLEDs.


2017 ◽  
Vol 5 (39) ◽  
pp. 10122-10125 ◽  
Author(s):  
Zhimin Yan ◽  
Yanping Wang ◽  
Jiaxiu Wang ◽  
Yue Wang ◽  
Junqiao Ding ◽  
...  

A novel furo[3,2-c]pyridine Ir complex has been developed by replacing S with O in the C^N ligand, which shows a blue-shifted emission and an EQE of over 30%.


2017 ◽  
Vol 5 (23) ◽  
pp. 5749-5756 ◽  
Author(s):  
Lingcheng Chen ◽  
Shumeng Wang ◽  
Zhimin Yan ◽  
Junqiao Ding ◽  
Lixiang Wang

By fully encapsulating the heteroleptic red Ir complex with carbazole dendrons, solution-processed nondoped electrophosphorescent devices reveal over 10% EQE.


2007 ◽  
Vol 364-366 ◽  
pp. 1072-1076
Author(s):  
Rui Li Song ◽  
Yu Duan

An efficient phosphorescent white organic light-emitting diode (WOLED) was realized by using a bright blue-emitting layer, iridium (III) bis [(4, 6-di-fluoropheny)-pyridinato-N, C2’] picolinate doped 4.4’-bis (9-carbazolyl)-2, 2’-dimethyl-biphenyl, together with tris (2- Phenylpyridine) iridium and bis (1-phenyl-isoquinoline) acetylacetonate iridium (III) were codoped into 4,4’-N,N’-dicarbazole-biphenyl layer to provide blue, green, and red emission for color mixing. The device emission color was controlled by varying dopant concentrations and the thickness of blue and green-red layers as well as tuning the thickness of exciton-blocking layer. The maximum luminance and power efficiency of the WOLED were 37100cd/m2 at 17 V and 7.37lm/W at 5V, respectively. The Commission Internationale de 1’Eclairage (CIE) chromaticity coordinate changes from (0.41, 0.42) to (0.37, 0.39) when the luminance rangeed from 1000cd/m2 to 30000cd/m2.


2015 ◽  
Vol 3 (38) ◽  
pp. 9999-10006 ◽  
Author(s):  
Kunkun Liu ◽  
Xiang-Long Li ◽  
Ming Liu ◽  
Dongcheng Chen ◽  
Xinyi Cai ◽  
...  

A series of 9,9-diphenyl-9H-thioxanthene derivatives are reported as host materials in blue phosphorescent OLEDs, giving a maximum power efficiency of 69.7 lm W−1 and an external quantum efficiency of 29.0%.


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