Ionic liquid-assisted thermal decomposition synthesis of carbon dots and graphene-like carbon sheets for optoelectronic application

RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61292-61300 ◽  
Author(s):  
Jia-Yun Wan ◽  
Ze Yang ◽  
Zhong-Guo Liu ◽  
Hang-Xing Wang

A facile process route for the synthesis of carbon dots and graphene-like carbon sheets is reported, which relies on direct carbonization of small organic molecules in a liquid-phase by using ionic liquid as solvent.

2001 ◽  
Vol 42 (35) ◽  
pp. 6097-6100 ◽  
Author(s):  
Joan Fraga-Dubreuil ◽  
Jean Pierre Bazureau

2017 ◽  
Vol 19 (11) ◽  
pp. 7772-7787 ◽  
Author(s):  
Soumadwip Ghosh ◽  
Souvik Dey ◽  
Mahendra Patel ◽  
Rajarshi Chakrabarti

The folding/unfolding equilibrium of proteins in aqueous medium can be altered by adding small organic molecules generally termed as co-solvents.


2016 ◽  
Vol 3 (1) ◽  
Author(s):  
Jesús I. Tapia ◽  
Mildred Quintana

AbstractWe report on the formation of different carbon nanostructures by ultrasonication of graphite in DMF upon the addition of 3 different small molecules: ferrocene carboxylic acid, dimethylamino methyl-ferrocene, and benzyl aldehyde. Our results confirm that acoustic cavitation in organic solvents generates free radicals which enable or are involved in secondary reactions. During the ultrasonication process, the addition of small molecules induces the formation of different carbon nanostructures mainly depending on the chemical nature of the molecule, as observed by transmission electron microscopy (TEM). Raman spectroscopy analysis confirms that small molecules act as radical scavengers reducing the damage caused by cavitation to graphene sheets producing long nanoribbons, squared sheets, or carbon nanoscrolls. Importantly, this strategy allows the production of different carbon nanostructures in liquid-phase making them readily available for their chemical functionalization or for their incorporation into hybrids materials enabling the development of new advanced biological applications.


2021 ◽  
Vol 17 ◽  
Author(s):  
Sakib Hussain Laghari ◽  
Najma Memon ◽  
Muhammad Yar Khuhawer ◽  
Taj Muhammad Jahangir

Background: Fluorescence-based sensing is considered highly sensitive and fluorescent probes with improved properties are always desired. Fluorescent carbon dots (CDs) are newly emerging quasi-spherical nanoparticles of less than 10 nm in size and belong to the carbon nano-material’s family. CDs have great potential as fluorescent probes and currently are under open deliberation by the researchers due to their striking properties such as low environmental hazard, high selectivity, greater sensitivity, good biocompatibility, tunable fluorescent properties and excitation dependent multicolor emission behavior. Introduction: This review demonstrates various available methods for fabrication of fluorescent CDs, capping of CDs and characterization with various techniques including UV-visible, FT-IR, and TEM. Analytical applications using CDs for the sensing of small organic molecules, specifically nitroaromatic compounds in the environmental samples are complied. Methods: The review covers literature related to synthesis and characterization of carbon dots. It includes around 171 research articles in this field. Results: Carbon dots can be synthesized using numerous routes. In all cases CDs possess spectral properties with little variation in wavelength maxima. Optical properties of CDs can be tuned by compositing these with metallic quantum dots or by modifying their surface with desired functionalities. HR-TEM is needed to see the morphology and size of particles whereas UV-Visible and FTIR are indispensable tools for this kind of research. These particles are successfully applied to sense small molecules in some matrices. Conclusion: Carbon dots are bright stars in fluorescent sensing of small molecules. However, more research is needed to determine small organic molecules in diversified areas of analysis.


Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 504 ◽  
Author(s):  
Christé ◽  
Esteves da Silva ◽  
Pinto da Silva

The efficiency and associated environmental impacts of different N-doping strategies of carbon dots (CDs) were evaluated. More specifically, N-doped CDs were prepared from citric acid via two main synthesis routes: Microwave-assisted hydrothermal treatment with addition of N-containing small organic molecules (urea and ethylenediamine (EDA)); and microwave-assisted solvothermal treatment in N-containing organic solvents (n,n-dimethylformamide (DMF), acetonitrile and pyridine). These syntheses produced CDs with similar blue emission. However, XPS analysis revealed that CDs synthesized via both hydrothermal routes presented a better N-doping efficiency (~15 at.%) than all three solvothermal-based strategies (0.6–7 at.%). However, from the former two hydrothermal strategies, only the one involving EDA as a nitrogen-source provided a non-negligible synthesis yield, which indicates that this should be the preferred strategy. This conclusion was supported by a subsequent life cycle assessment (LCA) study, which revealed that this strategy is clearly the most sustainable one from all five studied synthesis routes.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Francesco Rigodanza ◽  
Max Burian ◽  
Francesca Arcudi ◽  
Luka Đorđević ◽  
Heinz Amenitsch ◽  
...  

AbstractThe design of novel carbon dots with ad hoc properties requires a comprehensive understanding of their formation mechanism, which is a complex task considering the number of variables involved, such as reaction time, structure of precursors or synthetic protocol employed. Herein, we systematically investigated the formation of carbon nanodots by tracking structural, chemical and photophysical features during the hydrothermal synthesis. We demonstrate that the formation of carbon nanodots consists of 4 consecutive steps: (i) aggregation of small organic molecules, (ii) formation of a dense core with an extended shell, (iii) collapse of the shell and (iv) aromatization of the core. In addition, we provide examples of routes towards tuning the core-shell design, synthesizing five novel carbon dots that all consist of an electron-dense core covered by an amine rich ligand shell.


Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 11163-11172 ◽  
Author(s):  
Ashu K. Bansal ◽  
Muhammad T. Sajjad ◽  
Francesco Antolini ◽  
Lenuta Stroea ◽  
Paulius Gečys ◽  
...  

Laser patterning of luminescent metal selenide nanoparticles in organic semiconductor films is demonstrated by thermal decomposition of a precursor.


RSC Advances ◽  
2015 ◽  
Vol 5 (110) ◽  
pp. 90245-90254 ◽  
Author(s):  
Yawen Zheng ◽  
Dan Yang ◽  
Xin Wu ◽  
Haoran Yan ◽  
Yuancong Zhao ◽  
...  

In this study, vitamin-based small organic molecules were used as precursors to synthesize carbon dots by means of a hydrothermal approach.


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