Thiol-yne/thiol-epoxy hybrid crosslinked materials based on propargyl modified hyperbranched poly(ethyleneimine) and diglycidylether of bisphenol A resins

Cristina Acebo; Xavier Fernàndez-Francos; Xavier Ramis; Àngels Serra

doi:10.1039/c6ra13158a

Thiol-yne/thiol-epoxy hybrid crosslinked materials based on propargyl modified hyperbranched poly(ethyleneimine) and diglycidylether of bisphenol A resins

RSC Advances ◽

10.1039/c6ra13158a ◽

2016 ◽

Vol 6 (66) ◽

pp. 61576-61584 ◽

Cited By ~ 7

Author(s):

Cristina Acebo ◽

Xavier Fernàndez-Francos ◽

Xavier Ramis ◽

Àngels Serra

Keyword(s):

Bisphenol A ◽

Hyperbranched Poly ◽

Dual Curing

Photoinitiated thiol-yne reaction was combined with thermal thiol-epoxy to get thermosets by dual curing from propargyl decorated poly(ethyleneimine) and DGEBA.

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Synthesis of 1,2,3-triazole functionalized hyperbranched poly(ethyleneimine) and its use as multifunctional anionic macroinitiator for diglycidyl ether of bisphenol A curing

European Polymer Journal ◽

10.1016/j.eurpolymj.2016.10.043 ◽

2016 ◽

Vol 85 ◽

pp. 390-400

Author(s):

Cristina Acebo ◽

Albena Lederer ◽

Dietmar Appelhans ◽

Xavier Ramis ◽

Àngels Serra

Keyword(s):

Bisphenol A ◽

Diglycidyl Ether ◽

Hyperbranched Poly

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New Improved Thermosets Obtained From Diglycidylether of Bisphenol A and a Multiarm Star Copolymer Based on Hyperbranched Poly(glycidol) Core and Poly(methyl methacrylate) Arms

Macromolecular Chemistry and Physics ◽

10.1002/macp.201100497 ◽

2012 ◽

Vol 213 (3) ◽

pp. 335-343 ◽

Cited By ~ 9

Author(s):

Mireia Morell ◽

Xavier Ramis ◽

Francesc Ferrando ◽

Àngels Serra

Keyword(s):

Bisphenol A ◽

Methyl Methacrylate ◽

Poly Methyl Methacrylate ◽

Hyperbranched Poly ◽

Star Copolymer

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Dielectric spectroscopy of novel thiol-ene/epoxy thermosets obtained from allyl-modified hyperbranched poly(ethyleneimine) and diglycidylether of bisphenol A

European Polymer Journal ◽

10.1016/j.eurpolymj.2019.01.001 ◽

2019 ◽

Vol 113 ◽

pp. 98-106 ◽

Cited By ~ 2

Author(s):

J.D. Badia ◽

R. Teruel-Juanes ◽

C. Acebo ◽

O. Gil-Castell ◽

A. Serra ◽

...

Keyword(s):

Bisphenol A ◽

Dielectric Spectroscopy ◽

Hyperbranched Poly

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Dielectric and mechanical properties of diglycidyl ether of bisphenol a modified by a new fluoro-terminated hyperbranched poly(phenylene oxide)

Polymer Composites ◽

10.1002/pc.22512 ◽

2013 ◽

Vol 34 (7) ◽

pp. 1051-1060 ◽

Cited By ~ 18

Author(s):

Lijuan Luo ◽

Yan Meng ◽

Teng Qiu ◽

Zhuoxin Li ◽

Jing Yang ◽

...

Keyword(s):

Mechanical Properties ◽

Bisphenol A ◽

Diglycidyl Ether ◽

Phenylene Oxide ◽

Hyperbranched Poly ◽

Dielectric And Mechanical Properties

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Effect of Hyperbranched Poly (Trimellitic Anhydride Ethylene Glycol) Epoxy (HTME) on Thermal Degradation Activation Energies of HTME/Diglycidyl Ether of Bisphenol-A Epoxy Hybrid Resin by Kissinger and Flynn–Wall–Ozawa Method

Polymer-Plastics Technology and Engineering ◽

10.1080/03602550903283133 ◽

2010 ◽

Vol 49 (2) ◽

pp. 128-135 ◽

Cited By ~ 4

Author(s):

Jiliang Zhou ◽

Daohong Zhang ◽

Aiqing Zhang

Keyword(s):

Thermal Degradation ◽

Ethylene Glycol ◽

Bisphenol A ◽

Activation Energies ◽

Diglycidyl Ether ◽

Ozawa Method ◽

Trimellitic Anhydride ◽

Hybrid Resin ◽

Hyperbranched Poly

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Toughness and reinforcement of diglycidyl ether of bisphenol-A by hyperbranched poly(trimellitic anhydride-butanediol glycol) ester epoxy resin

Polymer Composites ◽

10.1002/pc.20633 ◽

2009 ◽

Vol 30 (7) ◽

pp. 918-925 ◽

Cited By ~ 38

Author(s):

Daohong Zhang ◽

Yukun Chen ◽

Demin Jia

Keyword(s):

Bisphenol A ◽

Epoxy Resin ◽

Diglycidyl Ether ◽

Trimellitic Anhydride ◽

Hyperbranched Poly ◽

Glycol Ester

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Novel epoxidized hyperbranched poly(phenylene oxide): Synthesis and application as a modifier for diglycidyl ether of bisphenol A

Journal of Applied Polymer Science ◽

10.1002/app.38270 ◽

2012 ◽

Vol 128 (1) ◽

pp. 907-914 ◽

Cited By ~ 24

Author(s):

Jianyong Lv ◽

Yan Meng ◽

Lifan He ◽

Teng Qiu ◽

Xiaoyu Li ◽

...

Keyword(s):

Bisphenol A ◽

Diglycidyl Ether ◽

Phenylene Oxide ◽

Hyperbranched Poly

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Probing the Chemistry and Spectroscopy of Radiation-Sensitive Polymers by Parallel-Detection EELS

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010013376x ◽

1990 ◽

Vol 48 (2) ◽

pp. 34-35

Author(s):

E. G. Rightor ◽

G. P. Young

Keyword(s):

Electron Beam ◽

Bisphenol A ◽

Energy Loss ◽

Parallel Detection ◽

Commercial Grade ◽

Incident Electron Beam ◽

Ptfe Sample ◽

Spectroscopic Information ◽

Edge Features ◽

Electron Energy Loss

Investigation of neat polymers by TEM is often thwarted by their sensitivity to the incident electron beam, which also limits the usefulness of chemical and spectroscopic information available by electron energy loss spectroscopy (EELS) for these materials. However, parallel-detection EELS systems allow reduced radiation damage, due to their far greater efficiency, thereby promoting their use to obtain this information for polymers. This is evident in qualitative identification of beam sensitive components in polymer blends and detailed investigations of near-edge features of homopolymers.Spectra were obtained for a poly(bisphenol-A carbonate) (BPAC) blend containing poly(tetrafluoroethylene) (PTFE) using a parallel-EELS and a serial-EELS (Gatan 666, 607) for comparison. A series of homopolymers was also examined using parallel-EELS on a JEOL 2000FX TEM employing a LaB6 filament at 100 kV. Pure homopolymers were obtained from Scientific Polymer Products. The PTFE sample was commercial grade. Polymers were microtomed on a Reichert-Jung Ultracut E and placed on holey carbon grids.

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