Synthesis, crystal structure and properties of a new 1D polymeric nitrogen-rich energetic complex {TAG[Li(BTO)(H2O)]}n based on 1H,1′H-5,5′-bitetrazole-1,1′-diolate

RSC Advances ◽  
2016 ◽  
Vol 6 (77) ◽  
pp. 73551-73559 ◽  
Author(s):  
Zhi-Bin Zhang ◽  
Cai-Xia Xu ◽  
Lei Yin ◽  
Zhen Wang ◽  
Xin Yin ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Energetic Materials ◽  
Metal Organic Frameworks ◽  
The Novel ◽  
Structure And Properties ◽  
Metal Organic ◽  
Polymeric Nitrogen ◽  
Energetic Complex

The novel polymer {TAG[Li(BTO)(H2O)]}n, based on 1H,1′H-5,5′-bitetrazole-1,1′-diolate, opened up a new field on BTO-based energetic materials and anionic metal–organic frameworks.

Solvothermal and Reflux Syntheses, Crystal Structure and Properties of Lanthanide-Thiophenedicarboxylate-Based Metal-Organic Frameworks

2009 ◽  
Vol 40 (3) ◽  
pp. 222-230 ◽  
Author(s):  
Christopher M. MacNeill ◽  
Cynthia S. Day ◽  
Sergio A. Gamboa ◽  
Abdessadek Lachgar ◽  
Ronald E. Noftle
Keyword(s):  
Crystal Structure ◽  
Metal Organic Frameworks ◽  
Structure And Properties ◽  
Metal Organic

Metal-Organic Frameworks (MOFs) as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

2019 ◽  
Author(s):  
Hatem M. Titi ◽  
Mihails Arhangelskis ◽  
Athanassis Katsenis ◽  
Cristina Mottillo ◽  
Ghada Ayoub ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energy Content ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Combustion Energy ◽  
Metal Organic ◽  
Advanced Applications ◽  
Ligand Replacement

Systematic investigation of combustion energies for popular metal-organic frameworks (MOFs) reveals energy content comparable to conventional energetic materials and can be further modified and dine-tuned by polymorphism and isostructural ligand replacement to yield materials with energy densities comparable to Diesel or kerosene.<br>

Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands

2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Uv Light ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uv Light Irradiation ◽  
Photocatalytic Activities ◽  
Metal Organic

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.

scholarly journals Synthesis, Crystal Structure, and Luminescent Properties of New Zinc(II) and Cadmium(II) Metal-Organic Frameworks Based on Flexible Bis(imidazol-1-yl)alkane Ligands

Crystals ◽  
2016 ◽  
Vol 6 (10) ◽  
pp. 132 ◽  
Author(s):  
Marina Barsukova ◽  
Tatiana Goncharova ◽  
Denis Samsonenko ◽  
Danil Dybtsev ◽  
Andrei Potapov
Keyword(s):  
Crystal Structure ◽  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Metal Organic

scholarly journals Crystal Structure Dependence of the Energy Transfer from Tb(III) to Yb(III) in Metal–Organic Frameworks Based in Bispyrazolylpyridines

Crystals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 69 ◽  
Author(s):  
Paloma Martinez-Martin ◽  
Josefina Perles ◽  
Juan Carlos Rodriguez-Ubis
Keyword(s):  
Crystal Structure ◽  
Energy Transfer ◽  
Organic Molecules ◽  
Metal Organic Frameworks ◽  
Structure Dependence ◽  
Characteristic Emission ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Coordinated Water ◽  
Luminescent Behavior

Luminescent mixed lanthanide metal−organic framwork (MOF) materials have been prepared from two polyheterocyclic diacid ligands, 2,6-bis(3-carboxy-1-pyrazolyl)pyridine and 2,6-bis(4-carboxy-1-pyrazolyl)pyridine. The crystal structures of the two organic molecules are presented together with the structures for the MOFs obtained by hydrothermal synthesis either with Yb(III) or mixed Tb(III)/Yb(III) ions. Different coordination architectures result from each ligand, revealing also important differences between the lanthanides. The mixed lanthanide metal−organic frameworks also present diverse luminescent behavior; in the case of 2,6-bis(4-carboxy-1-pyrazolyl)pyridine, where no coordinated water is present in the metal environment, Tb(III) and Yb(III) characteristic emission is observed by excitation of the bispyrazolylpyridine chromophore.

Rational design of 1-D metal–organic frameworks based on the novel pyrimidine-4,6-dicarboxylate ligand. New insights into pyrimidine through magnetic interaction

2007 ◽  
pp. 2669-2680 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko García-Couceiro ◽  
Juan P. García-Terán ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Magnetic Interaction ◽  
The Novel ◽  
Metal Organic ◽  
Dicarboxylate Ligand
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