Influence of TiO2 surface coating on the electrochemical properties of V2O5 micro-particles as a cathode material for lithium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 53925-53932 ◽  
Author(s):  
Xiaowei Zhou ◽  
Taoling He ◽  
Xu Chen ◽  
Li Sun ◽  
Zhu Liu

Based on V2O5 micro-particle, TiO2-coated V2O5 micro-particle was obtained by hydroxylation of tetrabutyl titanate, whose electrochemical cyclic stability as cathode for LIBs is improved due to the protective role of TiO2 coating layer.

NANO ◽  
2018 ◽  
Vol 13 (11) ◽  
pp. 1830007 ◽  
Author(s):  
Zhen Dong Hao ◽  
Xiaolong Xu ◽  
Hao Wang ◽  
Jingbing Liu ◽  
Hui Yan

Lithium ion batteries (LIBs) are one of the most promising secondary batteries due to their advantages including long cycle life, high energy density, limited self-discharge, high operating voltage and environmental friendliness. The development of electrode materials is crucial for the further application of LIBs. There are many effective ways to enhance the performance of positive electrode materials of LIBs such as surface coating, ion doping, preparation of composite materials and nanosized materials and so forth. Among them, surface coating is considered to be a promising way to improve the electrochemical performance of LIBs. Surface coating can normally form a physical barrier or a doped surface layer to play favorable roles for the electrode materials, such as hindering side reactions between positive electrode materials and the electrolyte. In this paper, different kinds of surface coating layers will be discussed according to previous research, including carbon materials, metal oxides, metal fluorides, metal phosphates, nonmetal oxides, electrode materials coating layer, hybrid coating layer, polymer and so forth. In addition, the mechanism of these coating materials will be summarized, and the future development will be discussed in this paper.


2016 ◽  
Vol 361 ◽  
pp. 150-156 ◽  
Author(s):  
Yue Xu ◽  
Yang Liu ◽  
Zhongpei Lu ◽  
Haiying Wang ◽  
Deqin Sun ◽  
...  

2010 ◽  
Vol 20 (36) ◽  
pp. 7606 ◽  
Author(s):  
Zonghai Chen ◽  
Yan Qin ◽  
Khalil Amine ◽  
Y.-K. Sun

2018 ◽  
Vol 175 ◽  
pp. 01030 ◽  
Author(s):  
Aijia Wei ◽  
Wen Li ◽  
Lihui Zhang ◽  
Zhenfa Liu

LiNi0.5Mn1.5O4 coated with 1.5 wt.% La2O3 was prepared and investigated as cathode materials for lithium ion batteries. The samples was characterized by XRD, SEM and EDX. After the 1.5 wt.% La2O3 coating, the lattice structure of LiNi0.5Mn1.5O4 is not destroyed and a La2O3 coating layer has formed on the surface of LiNi0.5Mn1.5O4 particles. The 1.5 wt.% La2O3-coated LiNi0.5Mn1.5O4 exhibits a higher rate capacity, with discharge capacity between 3.5 and 5 V of 131.9, 127.1, 126.5, 120.7, 114.1 and 101.5 mAh g-1 at rates of 0.2, 0.5, 1, 2, 3 and 5 C (1 C = 140 mAh g-1), respectively. The results indicate that the La2O3 coating could reduce the electrode polarization and enhance the rate capacities.


Ionics ◽  
2020 ◽  
Vol 27 (1) ◽  
pp. 65-74
Author(s):  
Jinhuan Yao ◽  
Yanwei Li ◽  
Renshu Huang ◽  
Jiqiong Jiang ◽  
Shunhua Xiao ◽  
...  

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