Large scale applications of immobilized enzymes call for sustainable and inexpensive solutions: rice husks as renewable alternatives to fossil-based organic resins

RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63256-63270 ◽  
Author(s):  
L. Corici ◽  
V. Ferrario ◽  
A. Pellis ◽  
C. Ebert ◽  
S. Lotteria ◽  
...  
Keyword(s):  
Rice Husk ◽  
Large Scale ◽  
Immobilized Enzymes ◽  
Covalent Immobilization ◽  
Rice Husks ◽  
Immobilization Of Enzymes

Rice husk for physical and covalent immobilization of enzymes: a sustainable and economic alternative to fossil-based organic resins.

scholarly journals Rice Husk as an Inexpensive Renewable Immobilization Carrier for Biocatalysts Employed in the Food, Cosmetic and Polymer Sectors

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 471 ◽  
Author(s):  
Marco Cespugli ◽  
Simone Lotteria ◽  
Luciano Navarini ◽  
Valentina Lonzarich ◽  
Lorenzo Del Terra ◽  
...  
Keyword(s):  
Rice Husk ◽  
Large Scale ◽  
Morphological Characterization ◽  
Industrial Processes ◽  
Lower Amount ◽  
Low Density ◽  
Unusual Combination ◽  
Immobilization Of Enzymes ◽  
Protein Contamination ◽  
Shed Light

The high cost and environmental impact of fossil-based organic carriers represent a critical bottleneck to their use in large-scale industrial processes. The present study demonstrates the applicability of rice husk as inexpensive renewable carrier for the immobilization of enzymes applicable sectors where the covalent anchorage of the protein is a pre-requisite for preventing protein contamination while assuring the recyclability. Rice husk was oxidized and then functionalized with a di-amino spacer. The morphological characterization shed light on the properties that affect the functionalization processes. Lipase B from Candida antarctica (CaLB) and two commercial asparaginases were immobilized covalently achieving higher immobilization yield than previously reported. All enzymes were immobilized also on commercial epoxy methacrylic resins and the CaLB immobilized on rice husk demonstrated a higher efficiency in the solvent-free polycondensation of dimethylitaconate. CaLB on rice husk appears particularly suitable for applications in highly viscous processes because of the unusual combination of its low density and remarkable mechanical robustness. In the case of the two asparaginases, the biocatalyst immobilized on rice husk performed in aqueous solution at least as efficiently as the enzyme immobilized on methacrylic resins, although the rice husk loaded a lower amount of protein.

scholarly journals Enhanced Wastewater Treatment by Immobilized Enzymes

2021 ◽  
Author(s):  
Jakub Zdarta ◽  
Katarzyna Jankowska ◽  
Karolina Bachosz ◽  
Oliwia Degórska ◽  
Karolina Kaźmierczak ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Process Optimization ◽  
Organic Pollutants ◽  
Large Scale ◽  
Removal Rate ◽  
Immobilized Enzymes ◽  
Future Research ◽  
Process Conditions ◽  
Removal Rates ◽  
Catalytic Cycles

Abstract Purpose of Review In the presented review, we have summarized recent achievements on the use of immobilized oxidoreductases for biodegradation of hazardous organic pollutants including mainly dyes, pharmaceuticals, phenols, and bisphenols. In order to facilitate process optimization and achievement of high removal rates, effect of various process conditions on biodegradation has been highlighted and discussed. Recent Findings Current reports clearly show that immobilized oxidoreductases are capable of efficient conversion of organic pollutants, usually reaching over 90% of removal rate. Further, immobilized enzymes showed great recyclability potential, allowing their reuse in numerous of catalytic cycles. Summary Collected data clearly indicates immobilized oxidoreductases as an efficient biocatalytic tools for removal of hazardous phenolic compounds, making them a promising option for future water purification. Data shows, however, that both immobilization and biodegradation conditions affect conversion efficiency; therefore, process optimization is required to achieve high removal rates. Nevertheless, we have demonstrated future trends and highlighted several issues that have to be solved in the near-future research, to facilitate large-scale application of the immobilized oxidoreductases in wastewater treatment.

Empirical Equilibrium Study on Rice Husk and Eggshells as Low Cost Bioadsorbent for the Methylene Blue Removal

2014 ◽  
Vol 699 ◽  
pp. 221-226
Author(s):  
Nurul Hanim Razak ◽  
Md. Razali Ayob ◽  
M.A.M. Zainin ◽  
M.Z. Hilwa
Keyword(s):  
Methylene Blue ◽  
Rice Husk ◽  
Low Cost ◽  
Agricultural Waste ◽  
Textile Wastewater ◽  
Blue Dye ◽  
Rice Husks ◽  
Equilibrium Study ◽  
Porosity Characterization

Eggshells and rice husk, two types of notable agricultural waste were used as bioadsorbent to remove Methylene Blue dye (MBD) in aqueous solution. This study was to investigate the performance of these two bioadsorbents in removing MBD. The removal percentage, adsorption capacity, and porosity characterization were examined. The method applied was a physical filtration. UV-VIS Spectrophotometer was used to determine the efficiency of the bioadsorbents in MBD adsorption. The highest removal percentage at the most concentrated MBD were 51% and 98% for eggshells and rice husks respectively. Meanwhile the characterization of rice husks pore size and volume proves that higher adsorptivity towards dye compares to eggshells porosity. It was concluded that the eggshells and rice husks bioadsorbents was successful to treat industrial textile wastewater with rice husks as the most efficient bioadsorbent in removing MBD.

A Study on Absorption Coefficient of Sustainable Acoustic Panels from Rice Husks and Sugarcane Baggase

2015 ◽  
Vol 1113 ◽  
pp. 198-203 ◽  
Author(s):  
Farrah Zuhaira Ismail ◽  
Mohamad Nidzam Rahmat ◽  
Norishahaini M. Ishak
Keyword(s):  
Absorption Coefficient ◽  
Rice Husk ◽  
Sound Absorption ◽  
Phenol Formaldehyde ◽  
Agricultural Waste ◽  
Rice Husks ◽  
Porosity Level ◽  
Agriculture Waste ◽  
Single Piece ◽  
Sound Reduction

Noise has detrimental effects on human lives and it is a nuisance to the environment. As many of the available sound reduction materials in the current market are hazardous, there are demands for alternative sustainable materials to reduce the noise problem. Therefore, the aim of this research is to study the potential of using an agricultural waste as sound absorption panel. For the purpose of this study, the combination of two materials was under studied; rice husks and sugarcane baggase. There were two main objective of the research; first is to develop absorption panels from the combination of rice husks and sugarcane baggase at different percentage of mixture. Second objective is to identify the absorption rate of the panels. The study encompasses the fabrication of the sustainable sound panels using the rice husk and sugarcane fibre and bond using Phenol formaldehyde (PF). Five panels of sized 12 inch x 12 inch and 12 mm thick were fabricated. The absorption coefficient of the samples was done at the acoustic lab, Faculty of Engineering & Build Environment, Universiti Kebangsaan Malaysia (UKM), Bangi. The panels were tested using an impedance tube. The procedure of the test was carried out in accordance with ISO 10534-2:1998 standards. Based on the results, sample 1 gave the highest absorption coefficient compared to sample 2, 3, 4 and 5. It can be concluded that the acoustic panel made from a mixture of 100% rice husks had higher absorption co-efficient compared to the performance of the other samples given the fact that the characteristic of the rice husks which has air gap in every single piece of rice husk. The spongy properties of the sample 1 panel has created many void spaces which encouraged more sound absorption capability due to the porous surface of the panel. Sound absorption is very much affected by the availability of porosity level of the panel. Thus, further studies on other potential materials from waste should be conducted.Keywords. Noise, Agriculture waste, sound, absorption panels, absorption co-efficient

scholarly journals PRODUCTION OF SODIUM SILICATE FROM RICE HUSK ASH WITH REGULATORY SETS MAGNESIUM

Tibuana ◽  
2020 ◽  
Vol 3 (01) ◽  
pp. 47-52
Author(s):  
Yanatra budi Pramana ◽  
M. Amin Pahlevi ◽  
Zhulianto Ashari ◽  
M. Fariz Effendi ◽  
Fibra Gilang Ramadhan
Keyword(s):  
Sodium Silicate ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Silica Content ◽  
Cosmetic Products ◽  
Rice Husks ◽  
Mg Addition ◽  
Increase Silica Content

Utilization of rice husks in Indonesia in general is still very limited. Utilization of silica contained in rice husk ash, which has been used, among others, in the manufacture of sodium silicate. Silica compounds themselves can be used in and manufacturing basic materials for electronic and ceramic equipment, glass, rubber, cosmetic products, and pharmaceuticals. The addition of Mg can increase the silica content (SiO2) in rice husk ash. The best results show an effective Mg ratio of Mg addition to increase silica content is 1: 1. produces the highest amount of silica which is 58.12% of the rice husk ash with a size of 140 mesh

scholarly journals Environmental and economic potential of rice husk use in An Giang province, Vietnam

2017 ◽  
Vol 8 (3) ◽  
pp. 206-211
Author(s):  
Thi Mai Thao Pham
Keyword(s):  
Power Generation ◽  
Rice Husk ◽  
Life Cycle Analysis ◽  
Large Scale ◽  
Fossil Fuels ◽  
Small Scale ◽  
Emission Mitigation ◽  
Mitigation Potential ◽  
Direct Combustion ◽  
The Cost

To evaluate CO2 emission mitigation potential and cost effectiveness of rice husk utilization, Life Cycle Analysis was conducted for 9 scenarios. The results showed that, gasification is the most efficient CO2 mitigation. From cost analysis, the cost mitigation can be achieved by replacing the current fossil fuels in cooking scenarios. Among the power generation scenarios, it was found that 30MW combustion and 5MW gasification power generations were the most economically-efficient scenarios. The briquette combustion power generation appeared less cost-competitive than direct combustion, whilst the large-scale gasification scenarios and the pyrolysis scenarios give the increase in cost from the baseline. From the viewpoints of both CO2 and cost, it was indicated that the win-win scenarios can be the rice husk use for cooking, for large-scale combustion power generation, and for small-scale gasification. Để đánh giá tiềm năng giảm thiểu phát thải CO2 và hiệu quả chi phí của việc sử dụng trấu, phương pháp đánh giá vòng đời sản phẩm đã được thực hiện cho 9 kịch bản. Kết quả cho thấy, khí hóa trấu để sản xuất điện có tiềm năng giảm phát sinh khí CO2 nhiều nhất. Kết quả phân tích chi phí cho thấy việc giảm thiểu chi phí có thể đạt được khi thay thế sử dụng nhiên liệu hóa thạch trong kịch bản dùng trấu cho nấu ăn. Giữa các kịch bản về sản xuất điện, hiệu quả kinh tế cao nhất trong trường hợp đốt trực tiếp trấu để sản xuất điện ở quy mô công xuất lớn (30MW) và khí hóa ở quy mô trung bình (5MW). Trường hợp dùng củi trấu không mang lại hiệu quả kinh tế so với dùng trực tiếp trấu để phát điện. Hai trường hợp dùng trấu để sản xuất dầu sinh học và khí hóa gas công suất lớn (30MW) cho thấy chi phí tăng cao so với điều kiện biên. Kịch bản cho kết quả khả thi về hiệu quả kinh tế và giảm phát thải CO2 là dùng trấu để nấu ăn, đốt trực tiếp để phát điện công suất lớn và khí hóa công suất trung bình.

scholarly journals KUALITAS PAPAN PARTIKEL BERDASARKAN KOMPOSISI SEKAM PADI DAN KAYU SENGON DENGAN VARIASI KADAR PEREKAT

2019 ◽  
Vol 7 (2) ◽  
Author(s):  
Dendi Prayoga ◽  
. Dirhamsyah ◽  
. Nurhaida
Keyword(s):  
Mechanical Properties ◽  
Moisture Content ◽  
Rice Husk ◽  
Raw Materials ◽  
Urea Formaldehyde ◽  
Physical And Mechanical Properties ◽  
Solid Content ◽  
Particle Board ◽  
Rice Husks ◽  
Wood Processing

This research aimed to examine the physical and mechanical properties of particle boards based on the composition of raw materials and adhesive content and know the treatment of the composition of raw materials and the best adhesive content and meet the standard JIS A 5908-2003. The research was conducted at Wood Workshop Laboratory, Wood Processing Laboratory Faculty of Forestry,Tanjungpura University and Laboratory of PT. Duta Pertiwi Nusantara Pontianak. The adhesive used is Urea Formaldehyde with 52% Solid Content. Comparison of the composition of rice husks and sengon varies namely rice husk 50%: sengon 50%, rice husk 60%: sengon 40% and rice husk 70%: sengon 30%  and variations in the levels of UF adhesives, namely 14% and 16%, with target density 0,7 gr/cm3. The particleboard was 30 cm x 30 cm x 1 cm Pressing at temperature 140oC for 8 minutes, with  pressure of 25 kg/cm2. The research results of the study of density and moisture content meet the standards JIS A 5908-2003. The best particle values of rice husk and sengon  with composition a ratio of  rice husk 50%: sengon 50% , 16% adhesive content  16%, with density value of  0,7072 gr/cm3, moisture content 9,1949 %, thick development 12,3210 %, water absorption 68,8270 %, MOE 12110,7273 kg/cm2, MOR 161,0025 kg/cm2, firmness sticky 1,9320 kg/cm2, screw holding strength 62,3124 kg.Keywords : adhesive, composition, particle board, rice husk, sengon

Rice Husk-Derived Mesoporous Silica Nanostructure for Supercapacitors Application: A Possible Approach for Recycling Bio-Waste into a Value-Added Product

2021 ◽  
Author(s):  
P. Araichimani ◽  
K.M. Prabu ◽  
G. Suresh Kumar ◽  
Gopalu Karunakaran ◽  
S. Surendhiran ◽  
...  
Keyword(s):  
Rice Husk ◽  
Redox Reactions ◽  
Low Cost ◽  
Combustion Process ◽  
Value Added ◽  
Mesoporous Structure ◽  
Rice Husks ◽  
A Value ◽  
Current Densities ◽  
Thermal Combustion

Abstract We synthesized mesoporous SiO2 nanomatrix using rice husks as a precursor through a facile thermal combustion process. XRD, FTIR, EDX, and TEM analyses were used to validate the produced mesoporous SiO2 nanomatrix. Electrochemical measurements were used to determine the specific capacitance of mesoporous SiO2 nanomatrix, and the results showed that the specific capacitances are 216, 204, 182, 163, 152, 142, 135, 133, 124.4, 124 F/g at current densities of 0.5, 1, 2, 4, 6, 8, 10, 12, 14, and 16 A/g. The benefit of impurities, as well as the large surface area and mesoporous structure of rice husk derived SiO2 nanostructures, allow Faradaic redox reactions at the electrode surface and the resulting supercapacitive behavior. This research might lead to a low-cost technique of producing supercapacitor electrodes using rice husk-derived SiO2 as a precursor.

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