Improved tribological and thermal properties of lubricants by graphene based nano-additives

RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 59477-59486 ◽  
Author(s):  
V. Zin ◽  
S. Barison ◽  
F. Agresti ◽  
L. Colla ◽  
C. Pagura ◽  
...  

Enhancing the tribological performance of lubricants with nanoparticle additives is a recent challenge. Addition of graphene based nanostructures in poly-alkylene glycol lubricant could significantly reduce friction and wear for compressors operating with CO2 refrigerant.

Author(s):  
Waleed Al-Sallami ◽  
Pourya Parsaeian ◽  
Abdel Dorgham ◽  
Anne Neville

Trihexyltetradecylphosphonium bis(2-ethylhexyl)phosphate (phosphonium phosphate) ionic liquid is soluble in non-polar lubricants. It has been proposed as an effective anti-wear additive comparable to zinc dialkyldithiophosphate. Previously, phosphonium phosphate has shown a better anti-wear performance under some conditions such as high temperature. In this work, the tribological performance and the lubrication mechanism of phosphonium phosphate are compared with that of zinc dialkyldithiophosphate when lubricating silicon under various tribological conditions. This can lead to an understanding of the reasons behind the superior anti-wear performance of phosphonium phosphate under some conditions. A micro-scale study is conducted using a nanotribometer. The results show that both additives lead to a considerable reduction in both friction and wear coefficients. The reduction in the wear coefficient is mainly controlled by the formation of the tribofilm on the rubbing surfaces. Zinc dialkyldithiophosphate can create a thicker tribofilm, which results in a better anti-wear performance. However, the formation of a thicker film will lead to a faster depletion and thus phosphonium phosphate can provide better anti-wear performance when the depletion of zinc dialkyldithiophosphate starts.


Author(s):  
Muhammad Sharil Yahayaa ◽  
Nurliyana Abdul Raof ◽  
Zulkifli Ibrahim ◽  
Azniza Ahmad ◽  
Chandima Gomes

Adaptation of apt chemical modifications and incorporation of suitable additives, especially, nano-additives, could improve the properties of bio-lubricants derived from palm oil. This makes it one of the best alternatives to mineral oil lubricants. Possible chemical modifications are hydrogenation, esterification/ transesterification, epoxidation and metathesis. Feasible additives and nano-additives available in the market for minimizing the drawbacks of palm oil as a lubricant are ionic liquids, phosphorus, sulphur, zinc dialkyl dithiophosphate, metal, metal oxides, metal sulphides, carbonates, borates, carbon materials, organic materials, hexagonal boron nitride, alumina, CaO, CuO, ZnO, TiO2 and lanthanum borates. Few of them may not be environmental friendly. In line with market potentials and demand, it could be predicted that ROI of funding for the research and development of palm oil as a bio-lubricant may be significantly high. The study addresses tribological performance and properties, chemical modifications and formulation with additives of palm oil as a bio-lubricant.


Friction ◽  
2021 ◽  
Author(s):  
Junhai Wang ◽  
Weipeng Zhuang ◽  
Wenfeng Liang ◽  
Tingting Yan ◽  
Ting Li ◽  
...  

AbstractIn this paper, we review recent research developments regarding the tribological performances of a series of inorganic nano-additives in lubricating fluids. First, we examine several basic types of inorganic nanomaterials, including metallic nanoparticles, metal oxides, carbon nanomaterials, and “other” nanomaterials. More specifically, the metallic nanoparticles we examine include silver, copper, nickel, molybdenum, and tungsten nanoparticles; the metal oxides include CuO, ZnO, Fe3O4, TiO2, ZrO2, Al2O3, and several double-metal oxides; the carbon nanomaterials include fullerene, carbon quantum dots, carbon nanotubes, graphene, graphene oxides, graphite, and diamond; and the “other” nanomaterials include metal sulfides, rare-earth compounds, layered double hydroxides, clay minerals, hexagonal boron nitride, black phosphorus, and nanocomposites. Second, we summarize the lubrication mechanisms of these nano-additives and identify the factors affecting their tribological performance. Finally, we briefly discuss the challenges faced by inorganic nanoparticles in lubrication applications and discuss future research directions. This review offers new perspectives to improve our understanding of inorganic nano-additives in tribology, as well as several new approaches to expand their practical applications.


Author(s):  
Tehreem Naveed ◽  
Rehan Zahid ◽  
Riaz Ahmad Mufti ◽  
Muhammad Waqas ◽  
Muhammad Talha Hanif

All the moving components in an internal combustion engine require a lubricant that allows smooth sliding and/or rolling of interacting surfaces. Lubricant not only minimizes the friction and wear but also dissipates the heat generated due to friction and removes debris from the area of contact. Environmental concerns, decreasing mineral oil reserves and difficult disposal of nonbiodegradable conventional lubricants have urged the researchers to shift towards environmental-friendly lubricants. Number of tribological studies carried out in the past have proved that ionic liquid-based bio-lubricants are sustainable and biodegradable alternative to mineral oils. This paper presents a brief review of properties of ionic liquids and their ability to reduce friction and wear between the interacting surfaces. Tribological performance and compatibility of ionic liquids with various base-oils have been compared under boundary lubrication. The results reveal that phosphonium-based ionic liquids namely tetra-decyl tri-hexyl phosphonium bis(2,4,4-trimethylpentyl) phosphinate (P66614)i(C8)2PO2 and tri-hexyl tetra-decyl phosphonium bis(2-ethylhexyl) phosphate (P-DEHP) are more suitable for tribological applications. Since, ionic liquids can be tailored according to the application and millions of combinations are possible therefore, there is a need to summarize the published data in a more systematic and logical way.


2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Shouvik Ghosh ◽  
Prasanta Sahoo ◽  
Goutam Sutradhar

The present study considers an experimental study of tribological performance of Al-7.5% SiCp metal matrix composite and optimization of tribological testing parameters based on the Taguchi method coupled with grey relational analysis. A grey relational grade obtained from grey relational analysis is used as a performance index to study the behaviour of Al-7.5% SiCp MMC with respect to friction and wear characteristics. The tribological experiments are carried out by utilizing the combinations of tribological test parameters based on the L27 Taguchi orthogonal design with three test parameters, namely, load, speed, and time. The material Al-7.5% SiCp metal matrix composite is developed by reinforcing LM6 aluminium alloy with 7.5% (by weight) SiC particle of 400 mesh size (~37 μm) in an electric melting furnace. It is observed that sliding time has a significant contribution in controlling the friction and wear behaviour of Al-7.5% SiCp MMC. Furthermore, all the interactions between the parameters have significant influence on tribological performance. A confirmation test is also carried out to verify the accuracy of the results obtained through the optimization problem. In addition, a scanning electron microscopy (SEM) test is performed on the wear tracks to study the wear mechanism.


Lubricants ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 92 ◽  
Author(s):  
Agnieszka Lenart ◽  
Pawel Pawlus ◽  
Slawomir Wos ◽  
Andrzej Dzierwa

The effect of steel disc surface texturing on dry gross fretting in a ball-on-disc configuration was studied. Dimples were created with abrasive jet machining. The tribological performance of sliding pairs, steel–steel and steel–ceramics, was experimentally studied. The character of surface texturing effect was related to the dominant wear type. During steel–steel contact, the presence of dimples on disc surfaces could lead to increases in wear and friction. However, the escape of wear debris into dimples could result in reductions of friction and wear in the steel–ceramics configuration.


2017 ◽  
Vol 24 (4) ◽  
pp. 485-494 ◽  
Author(s):  
Iskender Ozsoy ◽  
Adullah Mimaroglu ◽  
Huseyin Unal

AbstractIn this study, the influence of micro- and nanofiller contents on the tribological performance of epoxy composites was studied. The fillers are micro-Al2O3, micro-TiO2, and micro-fly ash and nano-Al2O3, nano-TiO2, and nanoclay fillers. The microfillers were added to the epoxy by 10%, 20%, and 30% by weight. The nanofillers were added to the epoxy by 2.5%, 5%, and 10%. Friction and wear tests were conducted using the pin-on-disc arrangement. Tribo elements consisted of polymer pin and DIN 1.2344 steel counterface disc. A load value of 15 N, a sliding speed of 0.4 m/s, a sliding distance of 2000 m, and dry atmospheric conditions were applied to test conditions. The results show that the friction coefficients and the specific wear rates of the nanofilled composites increase as the filler content increases. For microfiller-filled epoxy composites, these values decrease as filler content increases. The tribological performance of epoxy composites is enhanced by the addition of microfillers, and the higher enhancement is reached with the addition of 30% fly ash filler. Finally, the pin and disc worn surface images show the presence of adhesive and some abrasive wear mechanisms.


2019 ◽  
Vol 71 (4) ◽  
pp. 515-524 ◽  
Author(s):  
Venkateswara Babu P. ◽  
Ismail Syed ◽  
Satish Ben Beera

Purpose In an internal combustion engine, piston ring-cylinder liner tribo pair is one among the most critical rubbing pairs. Most of the energy produced by an internal combustion engine is dissipated as frictional losses of which major portion is contributed by the piston ring-cylinder liner tribo pair. Hence, proper design of tribological parameters of piston ring-cylinder liner pair is essential and can effectively reduce the friction and wear, thereby improving the tribological performance of the engine. This paper aims to use surface texturing, an effective and feasible method, to improve the tribological performance of piston ring-cylinder liner tribo pair. Design/methodology/approach In this paper, influence of positive texturing (protruding) on friction reduction and wear resistance of piston ring surfaces was studied. The square-shaped positive textures were fabricated on piston ring surface by chemical etching method, and the experiments were conducted with textured piston ring surfaces against un-textured cylinder liner surface on pin-on-disc apparatus by continuous supply of lubricant at the inlet of contact zone. The parameters varied in this study are area density and normal load at a constant sliding speed. A comparison was made between the tribological properties of textured and un-textured piston ring surfaces. Findings From the experimental results, the tribological performance of the textured piston ring-cylinder liner tribo pair was significantly improved over a un-textured tribo pair. A maximum friction reduction of 67.6 per cent and wear resistance of 81.6 per cent were observed with textured ring surfaces as compared to un-textured ring surfaces. Originality/value This experimental study is helpful for better understanding of the potency of positive texturing on friction reduction and wear resistance of piston ring-cylinder liner tribo pair under lubricated sliding conditions.


Friction ◽  
2020 ◽  
Vol 9 (2) ◽  
pp. 273-287
Author(s):  
Nisha Ranjan ◽  
Rashmi C. Shende ◽  
Muthusamy Kamaraj ◽  
Sundara Ramaprabhu

AbstractThe emergence of vegetable oil as a promising alternative lubricant in the tribological application space has fueled research for making these oils as useful as mineral oils. Tribological modification of vegetable oil by the addition of TiO2/gC3N4 nanocomposite (as a nanoadditive) was studied here. The dispersion of the nanoadditive in the vegetable oil showed good oil dispersion stability without the addition of any surfactant. The tribological studies were conducted in a four-ball tester using ASTM standard D5183. In addition, the effect of temperature on tribological performance was also studied to understand the oxidation behavior of vegetable oil. The results showed a significant improvement in friction and wear properties of the optimized nano-oil. The mechanism behind the improvement in friction and wear properties is annotated in this paper.


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