Hollow CeO2dodecahedrons: one-step template synthesis and enhanced catalytic performance

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 60975-60982 ◽  
Author(s):  
Zhengping Li ◽  
Fangchun Han ◽  
Cheng Li ◽  
Xiuling Jiao ◽  
Dairong Chen
Keyword(s):  
Co Oxidation ◽  
Template Synthesis ◽  
Catalytic Performance ◽  
Template Method ◽  
One Step

Hollow CeO2dodecahedrons are synthesized by a one-step template method and show enhanced catalytic performance for CO oxidation.

Preparation of Three Different Sphere-Like Au/CeO2 Catalysts and their Activity for the CO Oxidation

2010 ◽  
Vol 160-162 ◽  
pp. 428-433
Author(s):  
Lei Wang ◽  
Guang Sheng Guo ◽  
Fu Bo Gu ◽  
Zhi Hua Wang
Keyword(s):  
Co Oxidation ◽  
Solvothermal Method ◽  
Catalytic Performance ◽  
Vital Role ◽  
Precipitation Method ◽  
Template Method ◽  
Carbon Sphere ◽  
Test Results ◽  
Morphology And Structure ◽  
Catalytic Test

Three different CeO2 sphere nanomaterials (hollow sphere, flowerlike sphere, spherical cluster) were controllably synthesized by carbon sphere template method, hydrothermal and solvothermal method respectively. Then 2.5 wt% Au was doped on the supports by the deposition precipitation method and Au/CeO2 catalysts with three different morphologies were obtained. Composition, morphology and structure of these catalysts were characterized by the techniques of XRD, Raman, TPR, SEM and TEM, and the activity for CO oxidation of the catalysts was investigated. The catalytic test results indicated that the addition of Au could remarkably improve catalytic performance on CO oxidation. The activities of the three catalysts differ largely, the flowerlike Au/CeO2 catalyst had the highest activity for CO oxidation and its T100% was 29°C. The mechanism for the different activity of the catalysts was investigated. H2-TPR result indicated flowerlike had a more intensive peak at 125°C than others and it implied more reducible Au species in this case, that plays a vital role in the CO oxidation.

Controlled one-step synthesis of Pt decorated octahedral Fe3O4and its excellent catalytic performance for CO oxidation

Nanoscale ◽  
2015 ◽  
Vol 7 (42) ◽  
pp. 17855-17860 ◽  
Author(s):  
Gengnan Li ◽  
Liang Li ◽  
Binghan Wu ◽  
Jinxia Li ◽  
Yuan Yuan ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Catalytic Performance ◽  
One Step ◽  
Excellent Catalytic Performance

scholarly journals On the Effects of Doping on the Catalytic Performance of (La,Sr)CoO3. A DFT Study of CO Oxidation

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 312 ◽  
Author(s):  
Antonella Glisenti ◽  
Andrea Vittadini
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Density Functional Calculations ◽  
Density Functional ◽  
Formation Energy ◽  
Oxygen Vacancies ◽  
Catalytic Performance ◽  
Energy Profiles ◽  
High Concentrations ◽  
3D Impurities

The effects of modifying the composition of LaCoO3 on the catalytic activity are predicted by density functional calculations. Partially replacing La by Sr ions has benefical effects, causing a lowering of the formation energy of O vacancies. In contrast to that, doping at the Co site is less effective, as only 3d impurities heavier than Co are able to stabilize vacancies at high concentrations. The comparison of the energy profiles for CO oxidation of undoped and of Ni-, Cu-m and Zn-doped (La,Sr)CoO3(100) surface shows that Cu is most effective. However, the effects are less spectacular than in the SrTiO3 case, due to the different energetics for the formation of oxygen vacancies in the two hosts.

Growth kinetic control over MgFe2O4 to tune Fe occupancy and metal–support interactions for optimum catalytic performance

CrystEngComm ◽  
2021 ◽  
Vol 23 (13) ◽  
pp. 2538-2546
Author(s):  
Min Yang ◽  
Guangshe Li ◽  
Huixia Li ◽  
Junfang Ding ◽  
Yan Wang ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Growth Kinetic ◽  
Catalytic Performance ◽  
Growth Behavior ◽  
Kinetic Control ◽  
Size Dependent ◽  
Metal Support ◽  
Support Size ◽  
Metal Support Interactions ◽  
First Time

For the first time, the growth behavior with size-dependent Fe occupancies at different sites of MgFe2O4 was examined. Hybrid catalysts of Pt/MgFe2O4 with a support size of 20.6 nm exhibited an optimal performance of CO oxidation.

Nature and catalytic performance of PtSAPO-5 molecular sieve catalyst synthesized by one step

1998 ◽  
Vol 15 (5) ◽  
pp. 505-509
Author(s):  
Tian-Cun Xiao ◽  
Hai-Tao Wang ◽  
Yu-Li Lu ◽  
Li-Dun An ◽  
Hong-Li Wang
Keyword(s):  
Molecular Sieve ◽  
Catalytic Performance ◽  
One Step

Synergistic effect of co-reactant promotes one-step oxidation of cyclohexane into adipic acid catalyzed by manganese porphyrins

2015 ◽  
Vol 93 (7) ◽  
pp. 696-701 ◽  
Author(s):  
Hui Li ◽  
Yuanbin She ◽  
Haiyan Fu ◽  
Meijuan Cao ◽  
Jing Wang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Co Oxidation ◽  
Adipic Acid ◽  
Molar Ratio ◽  
Reaction Conditions ◽  
Catalyst Structure ◽  
Manganese Porphyrins ◽  
Co Oxidation Reaction ◽  
One Step ◽  
Acid Catalyzed

The synergistic effect of cyclohexane and cyclohexanone promoted synthesis of adipic acid catalyzed by [MnIIIT(p-Cl)PP]Cl with cyclohexane and cyclohexanone as co-reactants. The results showed that the conversions of cyclohexane and cyclohexanone were significantly enhanced because of the cyclohexanone synergistic effect, and the higher selectivity to adipic acid was obtained with dioxygen as an oxidant. The studies indicated that the co-oxidation of cyclohexane and cyclohexanone was influenced by the initial molar ratio of cyclohexanone and cyclohexane, catalyst structure, catalyst concentrations, and reaction conditions. The preliminary mechanism of the co-oxidation reaction of cyclohexane and cyclohexanone using [MnIIIT(p-Cl)PP]Cl as the catalyst was proposed.

scholarly journals Pd/Pt embedded CN monolayers as efficient catalysts for CO oxidation

2019 ◽  
Vol 21 (46) ◽  
pp. 25743-25748
Author(s):  
Yong-Chao Rao ◽  
Xiang-Mei Duan
Keyword(s):  
Density Functional Theory ◽  
Co Oxidation ◽  
Density Functional ◽  
Carbon Nitride ◽  
Density Functional Theory Calculations ◽  
Catalytic Performance ◽  
Functional Theory ◽  
Spin Polarized ◽  
Planar Carbon

The catalytic performance of Pd/Pt embedded planar carbon nitride for CO oxidation has been investigated via spin-polarized density functional theory calculations.

A facile synthesis for cauliflower like CeO2 catalysts from Ce-BTC precursor and their catalytic performance for CO oxidation

2017 ◽  
Vol 423 ◽  
pp. 771-779 ◽  
Author(s):  
Xiaodong Zhang ◽  
Fulin Hou ◽  
Yang Yang ◽  
Yuxin Wang ◽  
Ning Liu ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Catalytic Performance ◽  
Facile Synthesis

SnO2 nano-rods with superior CO oxidation performance

2014 ◽  
Vol 2 (16) ◽  
pp. 5616-5619 ◽  
Author(s):  
Xiang Wang ◽  
Lihong Xiao ◽  
Honggen Peng ◽  
Wenming Liu ◽  
Xianglan Xu
Keyword(s):  
Co Oxidation ◽  
Noble Metal ◽  
Catalytic Performance ◽  
Metal Catalyst ◽  
Noble Metal Catalyst ◽  
Catalytic Behavior ◽  
Oxidation Performance ◽  
Nano Rods

SnO2 with a nano-rod morphology shows a superior catalytic performance over SnO2 with other morphologies for CO oxidation. The SnO2-rods’ catalytic behavior is very similar to that of a noble metal catalyst.

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