Effect of size reduction on cation distribution and magnetic transitions in CoCr2O4 multiferroic: EXAFS, magnetic and diffused neutron scattering measurements

RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63809-63819 ◽  
Author(s):  
Jagadish K. Galivarapu ◽  
D. Kumar ◽  
A. Banerjee ◽  
V. Sathe ◽  
Giuliana Aquilanti ◽  
...  

Demonstration of rich sequences of magnetic transitions in 10 and 50 nm particles of CoCr2O4 is shown through dc, ac magnetic measurements, EXAFS and diffused neutron scattering.

2017 ◽  
Vol 46 (31) ◽  
pp. 10300-10314 ◽  
Author(s):  
D. Kumar ◽  
A. Banerjee ◽  
A. Mahmoud ◽  
Chandana Rath

Evolution of structure and rich magnetic transitions such as paramagnetic to ferrimagnetic phase transition at Curie temperature (TC), spiral ordering temperature (TS) and lock-in temperature (TL) have been discussed in CoCr2O4 spinel multiferroic after substituting Fe.


2020 ◽  
Vol 117 (10) ◽  
pp. 5168-5175 ◽  
Author(s):  
Joel M. Sarapas ◽  
Tyler B. Martin ◽  
Alexandros Chremos ◽  
Jack F. Douglas ◽  
Kathryn L. Beers

Uncharged bottlebrush polymer melts and highly charged polyelectrolytes in solution exhibit correlation peaks in scattering measurements and simulations. Given the striking superficial similarities of these scattering features, there may be a deeper structural interrelationship in these chemically different classes of materials. Correspondingly, we constructed a library of isotopically labeled bottlebrush molecules and measured the bottlebrush correlation peak position q*=2π/ξ by neutron scattering and in simulations. We find that the correlation length scales with the backbone concentration, ξ∼cBB−0.47, in striking accord with the scaling of ξ with polymer concentration cP in semidilute polyelectrolyte solutions (ξ∼cP−1/2). The bottlebrush correlation peak broadens with decreasing grafting density, similar to increasing salt concentration in polyelectrolyte solutions. ξ also scales with sidechain length to a power in the range of 0.35–0.44, suggesting that the sidechains are relatively collapsed in comparison to the bristlelike configurations often imagined for bottlebrush polymers.


1984 ◽  
Vol 29 (7) ◽  
pp. 3810-3814 ◽  
Author(s):  
B. H. Grier ◽  
S. M. Shapiro ◽  
R. J. Cava

2008 ◽  
Vol 77 (2) ◽  
Author(s):  
J. van Duijn ◽  
N. Hur ◽  
J. W. Taylor ◽  
Y. Qiu ◽  
Q. Z. Huang ◽  
...  

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