Two-dimensional CdS intercalated ZnO nanorods: a concise study on interfacial band structure modification

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52395-52402 ◽  
Author(s):  
Hind Fadhil Oleiwi ◽  
Sin Tee Tan ◽  
Hock Beng Lee ◽  
Chi Chin Yap ◽  
Riski Titian Ginting ◽  
...  

The intercalation of CdS on ZnO nanorods modified the optical band gap effectively and improved the solar cell performance significantly.

2007 ◽  
Vol 1012 ◽  
Author(s):  
Ana Kanevce ◽  
James R. Sites

AbstractSolar-cell performance degradation due to physical nonuniformities becomes more significant as the thickness of polycrystalline absorbers is reduced. “Voltage” nonuniformities such as those due to band-gap fluctuations, variations in the back-contact proximity, and areas where the absorber is completely depleted can have very significant impact on cell performance. Similarly local shunts can seriously degrade the efficiency. “Current” nonuniformities such as optical defects have generally much less impact. The analysis presented is based on Cu(In,Ga)Se2 cells, but the qualitative results should be applicable to thin-absorber devices in general. For lateral nonuniformity studies, the solar cell is simulated by a two dimensional network of parallel diodes separated by resistors. The nonuniformities are approximated by small regions of reduced photovoltage, often referred to as “weak diodes”, and by isolated shunt resistors. The weak-diode approach allows investigation of device performance as a function of the weak-diode voltage deficit, the ratio of weak-to strong-diode area, and the weak diodes' spatial distribution. Increased TCO resistance can isolate weak diodes, thus limiting the voltage loss due to nonuniformities, but increasing fill-factor losses.


Author(s):  
Christoph Krammer ◽  
Christian Huber ◽  
Thomas Schnabel ◽  
Christian Zimmermann ◽  
Mario Lang ◽  
...  

2018 ◽  
Vol 32 (23) ◽  
pp. 1850269 ◽  
Author(s):  
Mohamed Moustafa ◽  
Tariq Alzoubi

The impact of molybdenum ditelluride (p-type MoTe2) transition metal dichalcogenide (TMDC) material formation as an interfacial layer between CdTe absorber layer and Mo back contact is investigated. The simulation is conducted using the solar cell capacitance simulator (SCAPS) software. Band gap energy, carrier concentration, and layer thickness of the p-MoTe2 have been varied in this study to investigate the possible influences of p-MoTe2 on the electrical properties and the photovoltaic parameters of CdTe thin film solar cells. It has been observed that a thickness of the p-MoTe2 interfacial layer less than 60 nm leads to a decrease in the cell performance. In regard to the effect of the band gap, a maximum efficiency of 16.4% at the optimum energy gap value of 0.95 eV has been obtained at a doping of [Formula: see text]. Additionally, increasing the acceptor carrier concentration [Formula: see text] of MoTe2 enhances the solar cell performance. The solar cell efficiency reaches 15.5% with [Formula: see text] of [Formula: see text] with layer thicknesses above 80 nm. This might be attributed to the possibility of forming a back surface field for the photogenerated electrons, which reduces recombination at the back contact and hence provides a low resistivity contact for holes. The results justify that the MoTe2 interfacial layer mediates an ohmic contact to CdTe films.


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