Immobilized ruthenium metal-containing ionic liquid-catalyzed dehydrogenation of dimethylamine borane complex for the reduction of olefins and nitroarenes

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52347-52352 ◽  
Author(s):  
Nilesh M. Patil ◽  
Takehiko Sasaki ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Ionic Liquid ◽  
Reducing Agent ◽  
Transfer Hydrogenation ◽  
Dimethylamine Borane

An efficient immobilized ruthenium metal containing ionic liquid (ImmRu-IL) catalyst has been developed for the transfer hydrogenation of olefins and nitroarenes. This methodology uses eco-friendly dimethylamine borane as a reducing agent.

Transfer hydrogenation of nitroarenes into anilines by palladium nanoparticles via dehydrogenation of dimethylamine borane complex

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86529-86535 ◽  
Author(s):  
Nilesh M. Patil ◽  
Manohar A. Bhosale ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Catalytic System ◽  
Palladium Nanoparticles ◽  
Reducing Agent ◽  
Water Soluble ◽  
Transfer Hydrogenation ◽  
Dimethylamine Borane

Reduction of nitroarenes to corresponding amines ​via dehydrogenation of dimethylamine borane using Pd NPs as a catalyst. The developed catalytic system uses dimethylamine borane as a reducing agent which is highly stable, water soluble and non-toxic.

scholarly journals Asymmetric transfer hydrogenation of prochiral ketones catalyzed by aminosulfonamide-ruthenium complexes in ionic liquid

2011 ◽  
Vol 9 (1) ◽  
pp. 175-179 ◽  
Author(s):  
Zhongqiang Zhou ◽  
Yong Sun ◽  
Aiqing Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Prochiral Ketones

AbstractChiral aminosulfonamides containing imidazolium group were used as ligands for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of prochiral ketones in ionic liquid, affording good to excellent conversions and enantiomeric excesses. The catalytic system could be easily recovered and reused several times.

Chemoselective Transfer Hydrogenation of α,β-Unsaturated Carbonyls Using Palladium Immobilized Ionic Liquid Catalyst

2014 ◽  
Vol 144 (11) ◽  
pp. 1803-1809 ◽  
Author(s):  
Nilesh M. Patil ◽  
Takehiko Sasaki ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Ionic Liquid ◽  
Transfer Hydrogenation ◽  
Unsaturated Carbonyls

Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent

2012 ◽  
Vol 127-128 ◽  
pp. 43-53 ◽  
Author(s):  
Marek Wojnicki ◽  
Ewa Rudnik ◽  
Magdalena Luty-Błocho ◽  
Krzysztof Pacławski ◽  
Krzysztof Fitzner
Keyword(s):  
Solid Phase ◽  
Kinetic Studies ◽  
Aqueous System ◽  
Reducing Agent ◽  
Chloride Complex ◽  
Phase Precipitation ◽  
Dimethylamine Borane

A Recyclable Catalyst for Asymmetric Transfer Hydrogenation with a Formic Acid—Triethylamine Mixture in Ionic Liquid.

ChemInform ◽  
2005 ◽  
Vol 36 (37) ◽  
Author(s):  
Ikuo Kawasaki ◽  
Kazuya Tsunoda ◽  
Tomoko Tsuji ◽  
Tomoko Yamaguchi ◽  
Hiroki Shibuta ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Formic Acid ◽  
Recyclable Catalyst ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation
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