Solid state conversion of a double helix thallium(i) coordination polymer to a corrugated tape silver(i) polymer

RSC Advances ◽  
2016 ◽  
Vol 6 (85) ◽  
pp. 82447-82449 ◽  
Author(s):  
Maryam Moeinian ◽  
Kamran Akhbari ◽  
Satoshi Kawata ◽  
Ryuta Ishikawa
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Double Helix ◽  
Chain Structure ◽  
Mechanochemical Reaction

Irreversible solid-state conversion of TlI coordination polymer with double helix chain structure to corrugated tape silver(i) polymer has been observed upon mechanochemical reaction of [Tl(μ2-dcpa)]n (1) with AgNO3.

scholarly journals catena-Poly[[trimethyltin(IV)]-μ-methylphenylphosphinato-κ2O:O′]

IUCrData ◽  
2017 ◽  
Vol 2 (10) ◽  
Author(s):  
Chunhua Fu ◽  
Rufen Zhang ◽  
Shaoliang Zhang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Title Compound ◽  
Sodium Ethoxide ◽  
Chain Structure ◽  
Polymeric Chain ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Trimethyltin Chloride ◽  
Distorted Trigonal Bipyramidal

A new trimethyltin(IV) coordination polymer, [Sn(CH3)3(C7H8O2P)], has been prepared by treatment of methylphenylphosphinic acid and trimethyltin chloride with sodium ethoxide in methanol. In the solid state, the title compound adopts an infinite one-dimensional polymeric chain structure with each SnIVatom adopting a distorted trigonal–bipyramidal geometry.

A Zigzag Chain Cd (II) Coordination Polymer Based on 2,4-Dinitro-benzoic Acid Ligand: Syntheses, Structure and Photoluminescence

2014 ◽  
Vol 997 ◽  
pp. 140-145
Author(s):  
Hui Bai ◽  
Hong Gao ◽  
Ming Hu
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Benzoic Acid ◽  
Room Temperature ◽  
Chain Structure ◽  
Zigzag Chain ◽  
Photoluminescent Property ◽  
X Ray ◽  
Acid Ligand ◽  
Carboxylate Groups

The coordination polymer, namely, [Cd (L)2(phen)]n (1) (HL=2,4-dinitro-benzoic acid, phen=1,10-phenanthroline) has been hydrothermally synthesized. Compound 1 was structurally characterized by IR spectra, thermogravimetric analysis and single-crystal X-ray diffractions. The carboxylate groups of L- adopt the bridging monodentate and bidentate modes to link two Cd2+ ions, resulting in a 1-D zigzag chain structure. The solid state photoluminescent property of 1 has been investigated at room temperature.

Irreversible Crystal to Crystal Transformation of Nano Lead(II) Coordination Polymer by Solid State Anion-Replacement

2014 ◽  
Vol 875-877 ◽  
pp. 208-212
Author(s):  
Ali Morsali ◽  
Vahid Safarifard
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Mechanochemical Reaction ◽  
X Ray Diffraction ◽  
Sem Images ◽  
X Ray ◽  
Iodide Ions ◽  
Crystal Transformation ◽  
Elemental Analyses

Irreversible crystal-to-crystal transformation of 3D lead (II) coordination polymer with the ligand 1H-1,2,4-triazole-3-carboxylic acid (HL), [Pb (L)(μ1,1-NCS)(H2O)]n(1) to 3D supramalecular compound [Pb (L)(μ2-I)]n(2) by solid state anion-replacement have been studied. Structural determination of compound 2 reveals the Pb (II) ion is five coordinated with hemidirected geometry, bonded to one nitrogen atom, two oxygen atoms from the Lˉ ligand and two iodide ions. The irreversible solid state structural transformation of compound 1 to compound 2, by anion-replacement processes under mechanochemical reaction have been verified by PXRD measurements. Nanoparticles of compound 1 was synthesized by sonochemical process and characterized by scanning electron microscopy (SEM), powder X-ray diffraction, IR spectroscopy and elemental analyses. The SEM images showed that no morphology change occur during this solid state anion-replacement.

A novel multichromic Zn (Ⅱ) cationic coordination polymer based on a new flexible viologen ligand exhibiting aniline detection in solid state

2021 ◽  
Author(s):  
Jiayun Zou ◽  
jie Ji ◽  
Meihong Fan ◽  
Jiayu Li ◽  
Haiyu Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Pyromellitic Acid

In this paper, a novel multichromic catioic coordination polymer, named [Zn4 (BTC)3(bcbpy)2] ·5H2O (1) based on a new flexible viologen ligand 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine-1,1'-diium (H2bcbpy·2Cl), Zn(NO3)2·6H2O and pyromellitic acid (H4BTC), was synthesized....

scholarly journals Proton-conductive coordination polymer glass for solid-state anhydrous proton batteries

2021 ◽  
Vol 12 (16) ◽  
pp. 5818-5824
Author(s):  
Nattapol Ma ◽  
Soracha Kosasang ◽  
Atsushi Yoshida ◽  
Satoshi Horike
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Coordination Polymer ◽  
Proton Battery ◽  
Polymer Glass

Melt-quenched coordination polymer glass shows exclusive H+ conductivity (8.0 × 10−3 S cm−1 at 120 °C, anhydrous) and optimal mechanical properties (42.8 Pa s at 120 °C), enables the operation of an all-solid-state proton battery from RT to 110 °C.

A paramagnetic Cu(i)/Cu(ii)/Zn(ii) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization

2006 ◽  
pp. 744 ◽  
Author(s):  
Liang Ouyang ◽  
Pedro M. Aguiar ◽  
Raymond J. Batchelor ◽  
Scott Kroeker ◽  
Daniel B. Leznoff
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Solid State Nmr ◽  
Binding Modes ◽  
Nmr Characterization

Chain Structure of Substituted Stilbene−Maleic Anhydride Alternating Copolymer Probed by Solid-State NMR

2008 ◽  
Vol 41 (2) ◽  
pp. 387-389 ◽  
Author(s):  
Min Mao ◽  
Chul Kim ◽  
Sungsool Wi ◽  
S. Richard Turner
Keyword(s):  
Solid State ◽  
Maleic Anhydride ◽  
Solid State Nmr ◽  
Chain Structure ◽  
Alternating Copolymer

Ibuprofen as linker for calcium(II) in a 1D-coordination polymer: a solid state investigation complemented with solution studies

2021 ◽  
pp. 120319
Author(s):  
Juliana Morais Missina ◽  
Luca Conti ◽  
Patrizia Rossi ◽  
Andrea Ienco ◽  
Giovana Gioppo Nunes ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
1D Coordination Polymer ◽  
Solution Studies
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