scholarly journals Electrochemical and electromechanical properties of superior-performance hybrid polymer actuators exhibiting synergistic effects due to manganese oxide and multi-walled carbon nanotubes on various ionic liquids

RSC Advances ◽  
2016 ◽  
Vol 6 (70) ◽  
pp. 66360-66367 ◽  
Author(s):  
Naohiro Terasawa ◽  
Kinji Asaka

The performance of hybrid (electrostatic double-layer/faradaic capacitor) polymer actuators that exploit the synergy between MWCNTs and MnO2 was explored.

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1099 ◽  
Author(s):  
Qiuping Li

Ionogels refer to an emerging composite material made from the confinement of ionic liquids within some specific cross-linked network matrices. They have potential applications in areas such as electrochemical and optical-electric materials. Incorporation of lanthanide (Eu3+, Tb3+) complexes covalently functionalized multi-walled carbon nanotubes (MWCNTs) in ionogels provide new ideas to design and synthesize novel luminescent hybrid materials that have excellent characteristics of luminescence and ionic conductivity. Here, the multifunctional ionogels were synthesized by confining an ionic liquid and the rare earth functionalized MWCNTs in the cross-linked polymethyl methacrylate (PMMA) networks, resulting in a novel optical/electric multifunctional hybrid material. The SEM images and digital photographs suggest that the lanthanide functionalized MWCNTs are evenly dispersed in the hybrid matrices, thus leading to a certain transparency bulky gel. The resulting ionogels exhibit certain viscosity and flexibility, and display an intense red/green emission under UV-light irradiation. The intrinsic conductibility of the embedded ionic liquids and carbon nanotubes in conjunction with the outstanding photoluminescent properties of lanthanide complexes makes the soft hybrid gels a material with great potential and valuable application in the field of optical-electric materials.


2018 ◽  
Vol 42 (3) ◽  
pp. 2306-2319 ◽  
Author(s):  
Bruno Jarrais ◽  
Alexandra Guedes ◽  
Cristina Freire

Selectively oxidized multi-walled carbon nanotubes and graphene flakes showed superior performance in cis-cyclooctene epoxidation: 47% conversion and 79% selectivity for the best in class oxidized MWCNT, and 57% coversion and 85% selectivity for the best graphene flake material.


2012 ◽  
Vol 217-219 ◽  
pp. 567-570
Author(s):  
Dan Wang ◽  
Ke Qing Han ◽  
Wen Hui Zhang ◽  
Bin Yan ◽  
Yin Cai Tian ◽  
...  

Polyacrylonitrile(PAN)/multi-walled carbon nanotubes (MWNTs) composite fibers were prepared by melt spinning using ionic liquids (ILs) as a plasticizer. The effects of different MWNTs contents on the morphology, mechanical and conductive properties of the composite fibers were discussed. The results showed that property improvements have occurred with the adding of MWNTs. When the content of MWNTs reached 10%, the conductivity of PAN/MWNTs was 8.65×10-3 S/cm.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1356 ◽  
Author(s):  
Sandra Paszkiewicz ◽  
Anna Szymczyk ◽  
Agata Zubkiewicz ◽  
Jan Subocz ◽  
Rafal Stanik ◽  
...  

In this work, hybrid filler systems consisting of multi-walled carbon nanotubes (MWCNTs) and nano carbon black (nCB) were incorporated by melt mixing in low-density polyethylene (LDPE). To hybrid systems a mixture of MWCNTs and nCB a mass ratio of 1:1 and 3:1 were used. The purpose was to study if the synergistic effects can be achieved on tensile strength and electrical and thermal conductivity. The dispersion state of carbon nanofillers in the LDPE matrix has been evaluated with scanning electron microscopy. The melting and crystallization behavior of all nanocomposites was not significantly influenced by the nanofillers. It was found that the embedding of both types of carbon nanofillers into the LDPE matrix caused an increase in the value of Young’s modulus. The results of electrical and thermal conductivity were compared to LDPE nanocomposites containing only nCB or only MWCNTs presented in earlier work LDPE/MWCNTs. It was no synergistic effects of nCB in multi-walled CNTs and nCB hybrid nanocomposites regarding mechanical properties, electrical and thermal conductivity, and MWCNTs dispersion. Since LDPE/MWCNTs nanocomposites exhibit higher electrical conductivity than LDPE/MWCNTs + nCB or LDPE/nCB nanocomposites at the same nanofiller loading (wt.%), it confirms our earlier study that MWCNTs are a more efficient conductive nanofiller. The presence of MWCNTs and their concentration in hybrid nanocomposites was mainly responsible for the improvement of their thermal conductivity.


Carbon ◽  
2009 ◽  
Vol 47 (14) ◽  
pp. 3313-3321 ◽  
Author(s):  
A. Das ◽  
K.W. Stöckelhuber ◽  
R. Jurk ◽  
J. Fritzsche ◽  
M. Klüppel ◽  
...  

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