Mesoporous In2O3 nanofibers assembled by ultrafine nanoparticles as a high capacity anode for Li-ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 49782-49786 ◽  
Author(s):  
Yong Zhang ◽  
Chunhai Jiang ◽  
Shuxin Zhuang ◽  
Mi Lu ◽  
Yongcan Cai
Keyword(s):  
Large Volume ◽  
High Capacity ◽  
Li Ion Batteries ◽  
Initial Discharge Capacity ◽  
Storage Material ◽  
Lithium Storage ◽  
Initial Discharge ◽  
Capacity Degradation ◽  
Li Ion ◽  
Large Volume Change

As a lithium storage material, In2O3 has been hindered by its rapid capacity degradation due to the large volume change during the repeated lithiation and delithiation process, although an initial discharge capacity of more than 1600 mA h g−1.

Porous ZnTiO3 rods as a novel lithium storage material for Li-ion batteries

2020 ◽  
Vol 46 (9) ◽  
pp. 14030-14037 ◽  
Author(s):  
Meng-Cheng Han ◽  
Jun-Hong Zhang ◽  
Ping Cui ◽  
Ting-Feng Yi ◽  
Xifei Li
Keyword(s):  
Li Ion Batteries ◽  
Storage Material ◽  
Lithium Storage ◽  
Li Ion

A novel highly crystalline Fe4(Fe(CN)6)3 concave cube anode material for Li-ion batteries with high capacity and long life

2019 ◽  
Vol 7 (18) ◽  
pp. 11478-11486 ◽  
Author(s):  
Xiaowei He ◽  
Lidong Tian ◽  
Mingtao Qiao ◽  
Jianzheng Zhang ◽  
Wangchang Geng ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Hydrothermal Method ◽  
High Capacity ◽  
Li Ion Batteries ◽  
Lithium Storage ◽  
Prussian Blue Analogue ◽  
Storage Performance ◽  
One Step ◽  
Li Ion ◽  
Long Life

Hierarchically structured and ammonium-rich Prussian blue analogue materials are prepared by a one-step hydrothermal method, and show excellent lithium storage performance.

Sulfurization synthesis of a new anode material for Li-ion batteries: understanding the role of sulfurization in lithium ion conversion reactions and promoting lithium storage performance

2019 ◽  
Vol 7 (37) ◽  
pp. 21270-21279 ◽  
Author(s):  
Yanmin Qin ◽  
Zhongqing Jiang ◽  
Liping Guo ◽  
Jianlin Huang ◽  
Zhong-Jie Jiang ◽  
...  
Keyword(s):  
Anode Material ◽  
High Capacity ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Lithium Storage ◽  
Storage Performance ◽  
Carbon Coated ◽  
Li Ion ◽  
Good Cycling Stability

N, S co-doped carbon coated MnOS (MnOS@NSC) has been demonstrated to be a potential anode material for LIBs with high capacity, good cycling stability and excellent rate performance.

Nitrogen-doped carbon nanofibers with effectively encapsulated GeO2nanocrystals for highly reversible lithium storage

2015 ◽  
Vol 3 (43) ◽  
pp. 21699-21705 ◽  
Author(s):  
Lin Mei ◽  
Minglei Mao ◽  
Shulei Chou ◽  
Huakun Liu ◽  
Shixue Dou ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Large Volume ◽  
High Capacity ◽  
Lithium Ion ◽  
Germanium Dioxide ◽  
Lithium Storage ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon ◽  
Large Volume Change

Germanium dioxide is a promising high-capacity anode material for lithium-ion batteries, but it usually exhibits poor cycling stability due to its large volume change during the lithiation/delithiation process.

Al2O3 Coating of Spherical LiNi0.8Co0.2O2 for Li-Ion Batteries

2007 ◽  
Vol 336-338 ◽  
pp. 517-520 ◽  
Author(s):  
Xiang Ming He ◽  
Wei Hua Pu ◽  
Fang Hui Zhao ◽  
Jie Rong Ying ◽  
Chang Yin Jiang ◽  
...  
Keyword(s):  
Discharge Capacity ◽  
Lithium Ion ◽  
Surface Element ◽  
Li Ion Batteries ◽  
Initial Discharge Capacity ◽  
Element Analysis ◽  
Initial Discharge ◽  
Li Ion ◽  
Controlled Crystallization ◽  
First Time

Spherical LiNi0.8Co0.2O2 powders with particle size of 8~10μm were prepared based on controlled crystallization, and coated with Al2O3 by Al(OH)3 sol, that was prepared from Al(NO3)3 and NaOH, at first time. SEM, XRD and surface element analysis showed that the nano-sized Al2O3 was coated uniformly on the surface of LiNi0.8Co0.2O2 powder. At 25 °C, the initial discharge capacity decreased from 160 to 149 mAh g-1 after coating of Al2O3. The initial discharge capacity decreased from 168 to 163 mAh g-1 after coating of Al2O at 55 °C. After coating of Al2O3, the capacity retentions increased from 83.8% to 92.6% at the 50th cycle at 25°C, and from 36.3% to 90.8% at the 10th cycle at 55°C. This paves effective way to improve the performance of LiNi0.8Co0.2O2 material for rechargeable lithium ion batteries.

scholarly journals Structural Evolution and Electrochemical Performance of Li2MnSiO4/C Nanocomposite as Cathode Material for Li-Ion Batteries

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Min Wang ◽  
Meng Yang ◽  
Liqun Ma ◽  
Xiaodong Shen ◽  
Xu Zhang
Keyword(s):  
Sol Gel ◽  
High Capacity ◽  
Structural Evolution ◽  
Cycling Performance ◽  
Li Ion Batteries ◽  
Capacity Fading ◽  
Initial Discharge ◽  
Li Ion ◽  
20 Nm ◽  
A Current

High capacity Li2MnSiO4/C nanocomposite with good rate performance was prepared via a facile sol-gel method using ascorbic acid as carbon source. It had a uniform distribution on particle size of approximately 20 nm and a thin outlayer of carbon. The galvanostatic charge-discharge measurement showed that the Li2MnSiO4/C electrode could deliver an initial discharge capacity of 257.1 mA h g−1(corresponding to 1.56 Li+) at a current density of 10 mA g−1at 30°C, while the Li2MnSiO4electrode possessed a low capacity of 25.6 mA h g−1. Structural amorphization resulting from excessive extraction of Li+during the first charge was the main reason for the drastic capacity fading. Controlling extraction of Li+could inhibit the amorphization of Li2MnSiO4/C during the delithiation, contributing to a reversible structural change and good cycling performance.

On Improving the Cycling Stability of P2-Type Na0.67Ni0.33Mn0.67O2 Cathode Material By Ti-Substitution for Na-Ion Batteries

2019 ◽  
Author(s):  
Debanjana Pahari ◽  
Sreeraj Puravankara
Keyword(s):  
Solid State ◽  
Cathode Material ◽  
Electrode Materials ◽  
Cycling Stability ◽  
Partial Substitution ◽  
Li Ion Batteries ◽  
Initial Discharge Capacity ◽  
Initial Discharge ◽  
Li Ion ◽  
Ti Substitution

The extensive studies over the last decade have established Na-ion batteries (NIBs) as one of the cheaperalternatives to Li-ion batteries. P2-type Na0.67Ni0.33Mn0.67O2 has stood out among layered oxidebased electrode materials providing the best over-all electrochemical performance. The electrodes can exertup to 92.5% of its theoretical capacity (160 mAhg-1) at a voltage higher than 3 V accounted for the Ni2+/Ni4+redox. However, at higher voltages, electrodes suffer irreversibility due to P2-O2 structural transition.Recent studies in suppressing this transition by partial substitution with various metals on either Ni or Mnlattice site have suggested enhancing cycling stability. In this study, a novel cathode material with Ti-substitution on Ni site, P2-type Na0.67Ni0.25Ti0.08Mn0.67O2 has been synthesized via solid-state synthesismethod and characterized electrochemically. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes have been observed tobe highly reversible at higher voltage ranges. The electrodes have an initial discharge capacity of 125 mAhg-1and can retain around 84% of this capacity (105 mAhg-1) even after 50 cycles at 0.1C when cycled at an uppercut-off voltage of 4.3 V. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes are believed to suppress the irreversible P2-O2 transformation by diverting the charging reaction through a more reversible P2-OP4transition.

Deep Cycling for High‐Capacity Li‐Ion Batteries

2021 ◽  
pp. 2004998
Author(s):  
Huarong Xia ◽  
Yuxin Tang ◽  
Oleksandr I. Malyi ◽  
Zhiqiang Zhu ◽  
Yanyan Zhang ◽  
...  
Keyword(s):  
High Capacity ◽  
Li Ion Batteries ◽  
Li Ion

Soft-template fabrication of hierarchical nanoparticle iron fluoride as high-capacity cathode materials for Li-ion batteries

2020 ◽  
Vol 364 ◽  
pp. 137293
Author(s):  
Jinfang Lin ◽  
Shuyi Chen ◽  
Licai Zhu ◽  
Zhongzhi Yuan ◽  
Jincheng Liu
Keyword(s):  
Cathode Materials ◽  
High Capacity ◽  
Soft Template ◽  
Li Ion Batteries ◽  
Iron Fluoride ◽  
Li Ion
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