Copolymerization of l-lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer
Mono- and dinuclear salen aluminum complexes bearing a racemic 6,6′-dimethyl-biphenyl bridge could efficiently catalyze the copolymerization of l-LA and ε-CL in the melt, producing practically random and tapered copolymers, respectively.
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