Copolymerization of l-lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer

RSC Advances ◽  
2016 ◽  
Vol 6 (53) ◽  
pp. 47402-47409 ◽  
Author(s):  
Chao Kan ◽  
Haiyan Ma

Mono- and dinuclear salen aluminum complexes bearing a racemic 6,6′-dimethyl-biphenyl bridge could efficiently catalyze the copolymerization of l-LA and ε-CL in the melt, producing practically random and tapered copolymers, respectively.

RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29412-29419 ◽  
Author(s):  
Bo Gao ◽  
Xiang Li ◽  
Ranlong Duan ◽  
Qian Duan ◽  
Yanhui Li ◽  
...  

Hemi-salen aluminum complexes bearing tridentate N, N, O-type binaphthyl-Schiff-base ligands were synthesized and studied as catalysts for living polymerisation of lactide.


2009 ◽  
Vol 15 (26) ◽  
pp. 6478-6487 ◽  
Author(s):  
Kyu Young Hwang ◽  
Hyoseok Kim ◽  
Yoon Sup Lee ◽  
Min Hyung Lee ◽  
Youngkyu Do

2014 ◽  
Vol 5 (12) ◽  
pp. 3894 ◽  
Author(s):  
Xuan Pang ◽  
Ranlong Duan ◽  
Xiang Li ◽  
Xuesi Chen

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