scholarly journals Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 38342-38349 ◽  
Author(s):  
Xin Qi ◽  
Liang Tao ◽  
Hendrik Hahn ◽  
Carola Schultz ◽  
Dennis Roman Gallus ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Failure Mechanism ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive ◽  
First Time

In this work, a failure mechanism of tris(trimethylsilyl)phosphite (TMSPi), as a popular additive in a LiPF6 containing electrolyte for lithium ion batteries, is proposed and elucidated for the first time.

scholarly journals 4-(Trimethylsilyl) Morpholine as a Multifunctional Electrolyte Additive in High Voltage Lithium Ion Batteries

2020 ◽  
Vol 167 (7) ◽  
pp. 070533 ◽  
Author(s):  
Jianzhong Yang ◽  
Ilya Shkrob ◽  
Kewei Liu ◽  
Justin Connell ◽  
Nancy L. Dietz Rago ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive

2-(Trifluoroacetyl) thiophene as an electrolyte additive for high-voltage lithium-ion batteries using LiCoO2 cathode

2020 ◽  
Vol 55 ◽  
pp. 198-202 ◽  
Author(s):  
Yi Sun ◽  
Jian Huang ◽  
Hongfa Xiang ◽  
Xin Liang ◽  
Yuezhan Feng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive ◽  
Licoo2 Cathode

In-situ Coating of Cathode by Electrolyte Additive for High-voltage Performance of Lithium-ion Batteries

2015 ◽  
Vol 158 ◽  
pp. 202-208 ◽  
Author(s):  
Juping Yang ◽  
Yufeng Zhang ◽  
Peng Zhao ◽  
Yuming Shang ◽  
Li Wang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive ◽  
Voltage Performance ◽  
In Situ Coating

An Electrolyte Additive for Use in High-Voltage Lithium-Ion Batteries

2013 ◽  
Vol 423-426 ◽  
pp. 503-506
Author(s):  
Ai Fang Liu
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Composition ◽  
Anode Surface ◽  
Electrochemical Test ◽  
Electrolyte Additive ◽  
Sei Film ◽  
Electrochemical Window ◽  
Lowest Unoccupied Molecular Orbital

A new compound was successfully synthesized as an additive in electrolyte used for high-voltage lithium-ion batteries, owing to its unique structure with the sulfone group that can increase conductivity and broaden the electrochemical window of existing electrolyte. Its lowest unoccupied molecular orbital (LUMO) is-2.686 eV, respectively. The lower LUMO value results in formation of solid electrolyte interface (SEI) film on anode surface which is prior to other solvents and can impede the electrolyte composition. Through the electrochemical test, the electrolyte having this additive (0.2 wt%) showed wider voltage window, enduring the potential up to 5.5V higher than that of 4.8V performed by available commercial high-voltage electrolytes. The additive to electrolyte was effective not only for Li/Li3V2(PO4)3 cell but also for Li/LiMn2O4 cells with a cut-off range of 3.0-4.8 V.

N-(triphenylphosphoranylidene) aniline as a novel electrolyte additive for high voltage LiCoO2 operations in lithium ion batteries

2011 ◽  
Vol 56 (14) ◽  
pp. 5195-5200 ◽  
Author(s):  
Je-Nam Lee ◽  
Gi-Beom Han ◽  
Myung-Hyun Ryou ◽  
Dong Jin Lee ◽  
Jongchan Song ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive

scholarly journals Novel piperidinium-based ionic liquid as electrolyte additive for high voltage lithium-ion batteries

RSC Advances ◽  
2021 ◽  
Vol 11 (25) ◽  
pp. 15091-15098
Author(s):  
Wenlin Zhang ◽  
Qingcha Ma ◽  
Xuejiao Liu ◽  
Shuangcheng Yang ◽  
Fengshou Yu
Keyword(s):  
Ionic Liquid ◽  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Cycle Performance ◽  
Electrolyte Additive ◽  
Initial Discharge ◽  
Suitable Amount ◽  
P Cells ◽  
Discharge Capacities

Cells with 5 wt%, 10 wt%, and 15 wt% PP1, CNFSI addition exhibit higher initial discharge capacities than the cell with blank electrolyte. The addition of IL with suitable amount significantly increases the cycle performance..

Lithium-cyclo-difluoromethane-1,1-bis(sulfonyl)imide as a stabilizing electrolyte additive for improved high voltage applications in lithium-ion batteries

2015 ◽  
Vol 17 (14) ◽  
pp. 9352-9358 ◽  
Author(s):  
Patrick Murmann ◽  
Benjamin Streipert ◽  
Richard Kloepsch ◽  
Nikolai Ignatiev ◽  
Peter Sartori ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive

LiDMSI was evaluated as an electrolyte additive and shows promising results as an additive for high voltage applications in lithium-ion batteries.

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