Design and synthesis of a stable-performance P2-type layered cathode material for sodium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55327-55330 ◽  
Author(s):  
Shuo Liu ◽  
Xiaolei Jiang ◽  
Junshu Zhang ◽  
Jian Yang ◽  
Yitai Qian
Keyword(s):  
Phase Transition ◽  
Solid State ◽  
Solid State Reaction ◽  
Transition Process ◽  
Sodium Ion ◽  
Ex Situ ◽  
Sodium Ion Batteries ◽  
Design And Synthesis ◽  
Phase Transition Process ◽  
Stable Performance

P2-type Na0.6Ni0.2Co0.2Mn0.5Ti0.1O2 powders are successfully synthesized by a solid state reaction. Ex situ XRD reveals the phase transition process occurs at 4.1 V.

Fabricating Uniform Tetragonal Barium Titanate Nanocrystals via Sand Milling Assisted by an Innovative Two-Step Calcination

2018 ◽  
Vol 281 ◽  
pp. 71-77 ◽  
Author(s):  
Qian Cheng Zhao ◽  
Xiao Hui Wang ◽  
Jin Yong Kim ◽  
Hui Zhang ◽  
Hui Ling Gong ◽  
...  
Keyword(s):  
Phase Transition ◽  
Solid State ◽  
Solid State Reaction ◽  
Raw Materials ◽  
Transition Process ◽  
Milling Machine ◽  
Dwelling Time ◽  
Phase Transition Process ◽  
The Mean ◽  
Calcination Method

Sand-milling machine was firstly utilized to crush and disperse the raw materials. A homogenous and well-dispersed mixture of TiO2 and BaCO3 (<30nm) was obtained. The solid state reaction temperature can be reduced by 200°C for nanosized reactants compared with coarse ones. In order to increase tetragonality of nanosized BaTiO3, an innovative two-step calcination method, which includes solid state reaction process between reactants at a low temperature T1 and phase transition process at a high temperature T2, was subsequently adopted. The microstructure evolution of BaTiO3 by two-step calcination was investigated as a function of T2 and corresponding dwelling time t2. Pure-perovskite BaTiO3 nanopowders with the mean particle size as small as 75nm and tetragonality (c/a ratio) higher than 1.0096 could be fabricated by two-step calcination through altering T2 and/or its dwelling time t2.

Na3.12Fe2.44(P2O7)2/multi-walled carbon nanotube composite as a cathode material for sodium-ion batteries

2015 ◽  
Vol 3 (33) ◽  
pp. 17224-17229 ◽  
Author(s):  
Yubin Niu ◽  
Maowen Xu ◽  
Chuanjun Cheng ◽  
ShuJuan Bao ◽  
Junke Hou ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Solid State ◽  
Cathode Material ◽  
Solid State Reaction ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Multi Walled Carbon Nanotube ◽  
Carbon Nanotube Composite

Na3.12Fe2.44(P2O7)2/multi-walled carbon nanotube (MWCNT) composite was fabricated by a solid state reaction and was further used to fabricate a cathode for sodium-ion batteries.

scholarly journals Synthesis and electrochemical performances of Na3V2(PO4)2F3/C composites as cathode materials for sodium ion batteries

RSC Advances ◽  
2019 ◽  
Vol 9 (53) ◽  
pp. 30628-30636 ◽  
Author(s):  
Mingxue Wang ◽  
Xiaobing Huang ◽  
Haiyan Wang ◽  
Tao Zhou ◽  
Huasheng Xie ◽  
...  
Keyword(s):  
Solid State ◽  
Carbon Source ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Sodium Ion ◽  
Electrochemical Performances ◽  
Sodium Ion Batteries ◽  
Rate Performance ◽  
Cycle Stability ◽  
Reaction Method

Na3V2(PO4)2F3/C composites were synthesized by a solid-state reaction method using pitch as the carbon source, the as-prepared sample with the carbon content of 12.14% possesses an excellent rate performance and cycle stability.

Plate-Type NaV3O8 Cathode by Solid State Reaction for Sodium-Ion Batteries

2014 ◽  
Vol 3 (7) ◽  
pp. A69-A71 ◽  
Author(s):  
D. Nguyen ◽  
J. Gim ◽  
V. Mathew ◽  
J. Song ◽  
S. Kim ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Plate Type

Maricite NaFePO4/C/graphene: a novel hybrid cathode for sodium-ion batteries

2017 ◽  
Vol 5 (32) ◽  
pp. 16616-16621 ◽  
Author(s):  
Md Mokhlesur Rahman ◽  
Irin Sultana ◽  
Srikanth Mateti ◽  
Junnan Liu ◽  
Neeraj Sharma ◽  
...  
Keyword(s):  
Solid State ◽  
Ball Milling ◽  
Solid State Reaction ◽  
Storage Capacity ◽  
Milling Process ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Cycle Stability ◽  
High Sodium ◽  
Sodium Storage

A maricite hybrid cathode of NaFePO4/C/graphene with a novel microstructure is produced by a modified ball-milling process based on a solid-state reaction. This structure is capable of delivering high sodium storage capacity with outstanding cycle stability.

A simple synthesis of nanoporous Sb/C with high Sb content and dispersity as an advanced anode for sodium ion batteries

2018 ◽  
Vol 6 (14) ◽  
pp. 5555-5559 ◽  
Author(s):  
Yating Yuan ◽  
Safeer Jan ◽  
Zhiyong Wang ◽  
Xianbo Jin
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Sodium Ion ◽  
Simple Synthesis ◽  
Nanoporous Structure ◽  
Sodium Ion Batteries ◽  
Bottom Up ◽  
Sodium Storage

Amorphous Sb/C with a nanoporous structure and subnanometric dispersity is synthesized by a simple, bottom up solid state reaction between Sb2O3and CaC2. It exhibits an unprecedented performance of sodium storage.

scholarly journals In situ PDF and solid-state NMR studies of antimony anodes for Na-ion batteries

2014 ◽  
Vol 70 (a1) ◽  
pp. C354-C354
Author(s):  
Phoebe Allan ◽  
John Griffin ◽  
Olaf Borkiewicz ◽  
Kamila Wiaderek ◽  
Ali Darwiche ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Anode Materials ◽  
Large Scale ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Ex Situ ◽  
Sodium Ion Batteries ◽  
Nmr Studies

Sodium-ion batteries have attracted attention in recent years because of the natural abundance of sodium compared to lithium, making them particularly attractive in applications such as large-scale grid storage where low cost and sustainability, rather than light weight is the key issue [1]. Several materials have been suggested as cathodes but far fewer studies have been done on anode materials and, because of the reluctance of sodium to intercalate into graphite, the anode material of choice in commercial lithium-ion batteries, the anode represents a significant challenge to this technology. Materials which form alloys with sodium, particularly tin and antimony, have been suggested as anode materials; their ability to react with multiple sodium ions per metal-atom give potential for high gravimetric capacities[2]. However, relatively little is known about the reaction mechanism in the battery, primarily due to drastic reduction in crystallinity during (dis)charging conditions, but also because the structures formed on electrochemical cycling may not be alloys known to exist under ambient conditions. In this study, we present a study of antimony as an anode in sodium-ion batteries, using in situ pair distribution function (PDF) analysis combined with ex situ solid-state nuclear magnetic resonance studies. PDF experiments were performed at 11-ID-B, APS using the AMPIX electrochemical cell [3], cycling against sodium metal. Inclusion of diffuse scattering in analysis is able to circumvent some of the issues of crystallinity loss, and gain information about the local structure in all regions, independent of the presence of long-range order in the material. This approach has been used to probe local correlations in previously uncharacterised regions of the electrochemical profile and analyse phase progression over the full charge cycle. This analysis has been linked with ex situ 23Na solid-state NMR experiments to examine the local environment of the sodium; these show evidence of known NaxSb phases but indicate additional metastable phases may be present at partial discharge.

scholarly journals FeV2S4as a high capacity electrode material for sodium-ion batteries

2015 ◽  
Vol 51 (70) ◽  
pp. 13500-13503 ◽  
Author(s):  
Markus Krengel ◽  
Philipp Adelhelm ◽  
Franziska Klein ◽  
Wolfgang Bensch
Keyword(s):  
Solid State ◽  
Electrode Material ◽  
Solid State Reaction ◽  
Room Temperature ◽  
High Capacity ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
High Area

FeV2S4synthesizedviaa solid state reaction showing a high area capacity of 2.7 mA h cm−2for sodium ion batteries at room temperature.

Nanostructured WSe2/C composites as anode materials for sodium-ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (16) ◽  
pp. 12726-12729 ◽  
Author(s):  
Zhian Zhang ◽  
Xing Yang ◽  
Yun Fu
Keyword(s):  
Solid State ◽  
Discharge Capacity ◽  
Solid State Reaction ◽  
Anode Materials ◽  
Carbon Matrix ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
High Discharge ◽  
High Discharge Capacity ◽  
Excellent Cycling Stability

75.57% crystal WSe2 nanoparticles are uniformly dispersed on a carbon matrix to form WSe2/C nanomaterials using a solid-state reaction. The WSe2/C nanomaterials in sodium-ion batteries exhibit high discharge capacity and excellent cycling stability.

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