Fine-tuning the lifetimes and energy storage capacities of meta-stable vinylheptafulvenes via substitution at the vinyl position

RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 49003-49010 ◽  
Author(s):  
Martina Cacciarini ◽  
Martyn Jevric ◽  
Jonas Elm ◽  
Anne U. Petersen ◽  
Kurt V. Mikkelsen ◽  
...  
Keyword(s):  
System P ◽  

A novel set of photo/thermo switches is available by one-step synthesis from the parent system.

2019 ◽  
Author(s):  
Mark Workentin ◽  
François Lagugné-Labarthet ◽  
Sidney Legge

In this work we present a clean one-step process for modifying headgroups of self-assembled monolayers (SAMs) on gold using photo-enabled click chemistry. A thiolated, cyclopropenone-caged strained alkyne precursor was first functionalized onto a flat gold substrate through self-assembly. Exposure of the cyclopropenone SAM to UV-A light initiated the efficient photochemical decarbonylation of the cyclopropenone moiety, revealing the strained alkyne capable of undergoing the interfacial strain-promoted alkyne-azide cycloaddition (SPAAC). Irradiated SAMs were derivatized with a series of model azides with varied hydrophobicity to demonstrate the generality of this chemical system for the modification and fine-tuning of the surface chemistry on gold substrates. SAMs were characterized at each step with polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS) to confirm successful functionalization and reactivity. Furthermore, to showcase the compatibility of this approach with biochemical applications, cyclopropenone SAMs were irradiated and modified with azide-bearing cell adhesion peptides to promote human fibroblast cell adhesion, then imaged by live cell fluorescence microscopy. Thus, the “photoclick” methodology reported here represents an improved, versatile, catalyst-free protocol that allows for a high degree of control over the modification of material surfaces, with applicability in materials science as well as biochemistry.<br>


2021 ◽  
pp. 139021
Author(s):  
Linghui Peng ◽  
Di Li ◽  
Lingling Shen ◽  
Zichuan Liu ◽  
Weiren Fan ◽  
...  
Keyword(s):  

2021 ◽  
pp. 2102796
Author(s):  
Shenghui Shen ◽  
Lei Huang ◽  
Xili Tong ◽  
Rongfan Zhou ◽  
Yu Zhong ◽  
...  

CrystEngComm ◽  
2015 ◽  
Vol 17 (24) ◽  
pp. 4495-4501 ◽  
Author(s):  
Bin Yang ◽  
Lei Yu ◽  
Qi Liu ◽  
Jingyuan Liu ◽  
Wanlu Yang ◽  
...  

We synthesized the mushroom-like Ni3S2 with step by step growth that is the thin film growing on the nanorod arrays with one-step hydrothermal process, which is a novel ways to fabricate the multidimensional hierarchical electrode materials for high performance energy storage.


2018 ◽  
Vol 824 ◽  
pp. 226-237 ◽  
Author(s):  
Neha Kanaujiya ◽  
Nagesh Kumar ◽  
A.K. Srivastava ◽  
Yogesh Sharma ◽  
G.D. Varma

Author(s):  
Kathiresan Murugavel ◽  
Ambrose Bebin ◽  
Angu Lakhsmi Natarajan ◽  
Deepa Elizabeth Mathew ◽  
D Sujatha ◽  
...  

Organic redox compounds illustrate to be a fascinating class of active materials in energy-storage applications. The structural diversity as well as molecular tailoring helps in fine-tuning of the electrochemical properties...


Energies ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 512 ◽  
Author(s):  
Nayeem Chowdhury ◽  
Fabrizio Pilo ◽  
Giuditta Pisano

Energy storage systems can improve the uncertainty and variability related to renewable energy sources such as wind and solar create in power systems. Aside from applications such as frequency regulation, time-based arbitrage, or the provision of the reserve, where the placement of storage devices is not particularly significant, distributed storage could also be used to improve congestions in the distribution networks. In such cases, the optimal placement of this distributed storage is vital for making a cost-effective investment. Furthermore, the now reached massive spread of distributed renewable energy resources in distribution systems, intrinsically uncertain and non-programmable, together with the new trends in the electric demand, often unpredictable, require a paradigm change in grid planning for properly lead with the uncertainty sources and the distribution system operators (DSO) should learn to support such change. This paper considers the DSO perspective by proposing a methodology for energy storage placement in the distribution networks in which robust optimization accommodates system uncertainty. The proposed method calls for the use of a multi-period convex AC-optimal power flow (AC-OPF), ensuring a reliable planning solution. Wind, photovoltaic (PV), and load uncertainties are modeled as symmetric and bounded variables with the flexibility to modulate the robustness of the model. A case study based on real distribution network information allows the illustration and discussion of the properties of the model. An important observation is that the method enables the system operator to integrate energy storage devices by fine-tuning the level of robustness it willing to consider, and that is incremental with the level of protection. However, the algorithm grows more complex as the system robustness increases and, thus, it requires higher computational effort.


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