Impregnation vs. coprecipitation dispersion of Cr over TiO2 and ZrO2 used as active and stable nanocatalysts in oxidative dehydrogenation of ethane to ethylene by carbon dioxide

RSC Advances ◽  
2016 ◽  
Vol 6 (50) ◽  
pp. 44195-44204 ◽  
Author(s):  
Azadeh Talati ◽  
Mohammad Haghighi ◽  
Farhad Rahmani

The catalytic performance of Cr/ZrO2 and Cr/TiO2 nanocatalysts, prepared by coprecipitation and impregnation methods, was examined in oxidative dehydrogenation of ethane to ethylene using CO2 as an oxidant.

2017 ◽  
Vol 7 (2-4) ◽  
pp. 107-118 ◽  
Author(s):  
P. Thirumala Bai ◽  
S. Srinath ◽  
K. Upendar ◽  
T. V. Sagar ◽  
N. Lingaiah ◽  
...  

2017 ◽  
Vol 534 ◽  
pp. 58-69 ◽  
Author(s):  
E.V. Ishchenko ◽  
R.V. Gulyaev ◽  
T.Yu. Kardash ◽  
A.V. Ishchenko ◽  
E.Yu. Gerasimov ◽  
...  

2019 ◽  
Vol 584 ◽  
pp. 117114 ◽  
Author(s):  
Abdulrhman S. Al-Awadi ◽  
Ahmed Mohamed El-Toni ◽  
Saeed M. Al-Zahrani ◽  
Ahmed E. Abasaeed ◽  
Mansour Alhoshan ◽  
...  

1998 ◽  
Vol 63 (11) ◽  
pp. 1869-1883 ◽  
Author(s):  
Teresa Blasco ◽  
Patricia Concepción ◽  
José M. López Nieto ◽  
Arturo Martínez-Arias

MeAPO-5 (Me = V, Mg, Co, Mn) and VMeAPO-5 (Me = Mg, Co, Mn) with AFI structure were prepared by hydrothermal synthesis and characterized by nitrogen-adsorption, TPR, diffuse reflectance (UV-VIS) and ESR spectroscopies. Their catalytic performance in the oxidative dehydrogenation of ethane using molecular oxygen was also studied. Although different catalytic behaviour was observed depending on the metal incorporated, Vanadia-metal containing materials were the most selective catalysts. The importance of both redox and acid character of the catalysts on their catalytic properties is discussed.


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