A direct carbon fuel cell with a CuO–ZnO–SDC composite anode

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 50201-50208 ◽  
Author(s):  
Wenbin Hao ◽  
Yongli Mi
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Power Density ◽  
Anode Material ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Composite Anode ◽  
Direct Carbon Fuel Cell ◽  
Direct Carbon Fuel Cells

A direct carbon fuel cell with a CuO–ZnO–SDC composite anode was demonstrated. The maximum power density was 130 mW cm−2 at 700 °C. The results indicate that CuO–ZnO can be used as a nickel-free anode material for direct carbon fuel cells.

scholarly journals Natural Wolframite Used as Cathode Photocatalyst for Improving the Performance of Microbial Fuel Cells

2018 ◽  
Vol 8 (12) ◽  
pp. 2504
Author(s):  
Junxian Shi ◽  
Anhuai Lu ◽  
Haibin Chu ◽  
Hongyu Wu ◽  
Hongrui Ding
Keyword(s):  
Fuel Cells ◽  
Power Density ◽  
Microbial Fuel Cells ◽  
Environmental Remediation ◽  
Low Cost ◽  
Reduction Process ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Graphite Cathode ◽  
Vis Spectroscopy

Developing simple and cheap electrocatalysts or photocatalysts for cathodes to increase the oxygen reduction process is a key factor for better utilization of microbial fuel cells (MFCs). Here, we report the investigation of natural wolframite employed as a low-cost cathode photocatalyst to improve the performance of MFCs. The semiconducting wolframite was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman spectroscopy. The band gap and photo respond activities were determined by UV-vis spectroscopy and linear sweep voltammetry (LSV), respectively. Compared with the normal graphite cathode, when MFCs were equipped with a wolframite-coated cathode, the maximum power density was increased from 41.47 mW·m−2 to 95.51 mW·m−2. Notably, the maximum power density further improved to 135.57 mW·m−2 under light irradiation, which was 2.4 times higher than with a graphite cathode. Our research demonstrated that natural wolframite, a low-cost and abundant natural semiconducting mineral, showed promise as an effective photocathode catalyst which has great potential applications related to utilizing natural minerals in MFCs and for environmental remediation by MFCs in the future.

Low-Temperature Operating Micro Solid Oxide Fuel Cells with Perovskite-type Proton Conductors

2011 ◽  
Vol 1330 ◽  
Author(s):  
Hiroo Yugami ◽  
Kensuke Kubota ◽  
Yu Inagaki ◽  
Fumitada Iguchi ◽  
Shuji Tanaka ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Low Temperature ◽  
Solid Oxide Fuel Cells ◽  
Power Density ◽  
Proton Conductors ◽  
Solid Oxide ◽  
Maximum Power ◽  
Barium Zirconate ◽  
Oxide Fuel ◽  
Maximum Power Density

ABSTRACTMicro-solid oxide fuel cells (Micro-SOFCs) with yttrium-doped barium zirconate (BZY) and strontium and cobalt-doped lanthanum scandate (LSScCo) electrolytes were fabricated for low-temperature operation at 300 °C. The micro-SOFC with a BZY electrolyte could operate at 300 °C with an open circuit voltage (OCV) of 1.08 V and a maximum power density of 2.8 mW/cm2. The micro-SOFC with a LSScCo electrolyte could operate at 370 °C; its OCV was about 0.8 V, and its maximum power density was 0.6 mW/cm2. Electrochemical impedance spectroscopy revealed that the electrolyte resistance in both the micro-SOFCs was lower than 0.1 Ωcm2, and almost all of the resistance was due to anode and cathode reactions. Although the obtained maximum power density was not sufficient for practical applications, improvement of electrodes will make these micro-SOFCs promising candidates for power sources of mobile electronic devices.

scholarly journals Energy Harvesting from Sugarcane Bagasse Juice using Yeast Microbial Fuel Cell Technology

REAKTOR ◽  
2021 ◽  
Vol 21 (2) ◽  
pp. 52-58
Author(s):  
Marcelinus Christwardana ◽  
Linda Aliffia Yoshi ◽  
J. Joelianingsih
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Sugarcane Bagasse ◽  
Current Density ◽  
Sugar Content ◽  
Maximum Power ◽  
Biofuel Cell ◽  
Maximum Power Density ◽  
Menten Constant

This study demonstrates the feasibility of producing bioelectricity utilizing yeast microbial fuel cell (MFC) technology with sugarcane bagasse juice as a substrate. Yeast Saccharomyces cerevisiae was employed as a bio-catalyst in the production of electrical energy. Sugarcane bagasse juice can be used as a substrate in MFC yeast because of its relatively high sugar content. When yeast was used as a biocatalyst, and Yeast Extract, Peptone, D-Glucose (YPD) Medium was used as a substrate in the MFC in the acclimatization process, current density increased over time to reach 171.43 mA/m2 in closed circuit voltage (CCV), maximum power density (MPD) reached 13.38 mW/m2 after 21 days of the acclimatization process. When using sugarcane bagasse juice as a substrate, MPD reached 6.44 mW/m2 with a sugar concentration of about 5230 ppm. Whereas the sensitivity, maximum current density (Jmax), and apparent Michaelis-Menten constant (𝐾𝑚𝑎𝑝𝑝) from the Michaelis-Menten plot were 0.01474 mA/(m2.ppm), 263.76 mA/m2, and 13594 ppm, respectively. These results indicate that bioelectricity can be produced from sugarcane bagasse juice by Saccharomyces cerevisiae.Keywords: biomass valorization, biofuel cell, acclimatization, maximum power density, Michaelis-Menten constant

Hydrocarbon Fueled Operation of Metal-Supported Solid Oxide Fuel Cell

2010 ◽  
Author(s):  
Jihoon Jeong ◽  
Seung-Wook Baek ◽  
Joongmyeon Bae
Keyword(s):  
High Temperature ◽  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Power Density ◽  
Solid Oxide ◽  
Maximum Power ◽  
Oxide Fuel ◽  
Maximum Power Density ◽  
Operating Characteristics ◽  
Synthetic Gas

The metal-supported solid oxide fuel cell (SOFC) was studied. Hydrocarbon fueled operation was used to make SOFC system. Different operating characteristics for metal-supported SOFC are used than for conventional ones. Metal-supported SOFC was successfully fabricated by a high temperature sinter-joining method and the cathode was in-situ sintered. Synthetic gas, which is compounded as the diesel reformate gas composition and low hydrocarbons was completely removed by the diesel reformer. Metal-supported SOFC with synthetic gas was operated and evaluated and its characteristics analyzed. The performance of hydrogen operation shows 0.4 W·cm−2 of maximum power density. The maximum power density of the synthetic gas operation decreased to 0.22 W·cm−2 and to 0.11 W·cm−2 after 10 hours operation, respectively. Degradation occurred because a large steam quantity made an oxidation atmosphere at high temperature, causing the metallic part damage.

Improved Maximum Power Density of Alkaline Membrane Fuel Cells (AMFCs) by the Optimization of MEA Construction

2019 ◽  
Vol 28 (30) ◽  
pp. 221-225 ◽  
Author(s):  
Kenji Fukuta ◽  
Hiroshi Inoue ◽  
Yohei Chikashige ◽  
Hiroyuki Yanagi
Keyword(s):  
Fuel Cells ◽  
Power Density ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Alkaline Membrane

scholarly journals Challenges in developing direct carbon fuel cells

2017 ◽  
Vol 46 (10) ◽  
pp. 2889-2912 ◽  
Author(s):  
Cairong Jiang ◽  
Jianjun Ma ◽  
Gael Corre ◽  
Sneh L. Jain ◽  
John T. S. Irvine
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Electrical Efficiency ◽  
Direct Carbon Fuel Cell ◽  
Direct Carbon Fuel Cells

A direct carbon fuel cell (DCFC) can produce electricity with both superior electrical efficiency and fuel utilisation compared to all other types of fuel cells.

Nitrogen and sulfur dual-doped graphene as an efficient metal-free electrocatalyst for the oxygen reduction reaction in microbial fuel cells

2019 ◽  
Vol 43 (24) ◽  
pp. 9389-9395 ◽  
Author(s):  
Cuie Zhao ◽  
Jinxiang Li ◽  
Yan Chen ◽  
Jianyu Chen
Keyword(s):  
Fuel Cells ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Power Density ◽  
Microbial Fuel Cells ◽  
Reduction Reaction ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Metal Free ◽  
Doped Graphene

In this study, nitrogen- and sulfur-codoped graphene (N/S-G) was prepared and used as an efficient metal-free electrocatalyst for the oxygen reduction reaction (ORR) in microbial fuel cells (MFCs), exhibiting a maximum power density of 1368 mW m−2, relatively higher than that of commercial Pt/C.

Optimal Design of Hybrid Fuel Cell Vehicles

2006 ◽  
Author(s):  
Jeongwoo Han ◽  
Michael Kokkolaras ◽  
Panos Papalambros
Keyword(s):  
Fuel Cell ◽  
Power Density ◽  
Cell System ◽  
Maximum Power ◽  
Fuel Cell Vehicle ◽  
Maximum Power Density ◽  
Fuel Cell Vehicles ◽  
Fuel Cell System ◽  
Vehicle Performance ◽  
Cell Systems

Fuel cells are being considered increasingly as a viable alternative energy source for automobiles because of their clean and efficient power generation. Numerous technological concepts have been developed and compared in terms of safety, robust operation, fuel economy, and vehicle performance. However, several issues still exist and must be addressed to improve the viability of this emerging technology. Despite the relatively large number of models and prototypes, a model-based vehicle design capability with sufficient fidelity and efficiency is not yet available in the literature. In this article we present an analysis and design optimization model for fuel cell vehicles that can be applied to both hybrid and non-hybrid vehicles by integrating a fuel cell vehicle simulator with a physics-based fuel cell model. The integration is achieved via quasi-steady fuel cell performance maps, and provides the ability to modify the characteristics of fuel cell systems with sufficient accuracy (less than 5% error) and efficiency (98% computational time reduction on average). Thus, a vehicle can be optimized subject to constraints that include various performance metrics and design specifications so that the overall efficiency of the hybrid fuel cell vehicle can be improved by 14% without violating any constraints. The obtained optimal fuel cell system is also compared to other, not vehicle-related, fuel cell systems optimized for maximum power density or maximum efficiency. A tradeoff between power density and efficiency can be observed depending on the size of compressors. Typically, a larger compressor results in higher fuel cell power density at the cost of fuel cell efficiency because it operates in a wider current region. When optimizing the fuel cell system for maximum power density, we observe that the optimal compressor operates efficiently. When optimizing the fuel cell system to be used as a power source in a vehicle, the optimal compressor is smaller and less efficient than the one of the fuel cell system optimized for maximum power density. In spite of this compressor inefficiency, the fuel cell system is 9% more efficient on average. In addition, vehicle performance can be improved significantly because the fuel cell system is designed both for maximum power density and efficiency. For a more comprehensive understanding of the overall design tradeoffs, several constraints dealing with cost, weight, and packaging issues must be considered.

scholarly journals Evaluation of an Alkaline Fuel Cell for Multifuel System

2005 ◽  
Vol 2 (4) ◽  
pp. 234-237 ◽  
Author(s):  
A. Verma ◽  
A. K. Jha ◽  
S. Basu
Keyword(s):  
Activated Carbon ◽  
Fuel Cell ◽  
Power Density ◽  
Current Density ◽  
Sodium Borohydride ◽  
Potassium Hydroxide ◽  
Maximum Power ◽  
Carbon Paper ◽  
Maximum Power Density ◽  
Alkaline Fuel Cell

The performance of an alkaline fuel cell (AFC) is investigated using three different fuels, e.g., methanol, ethanol, and sodium borohydride. Pt∕C∕Ni was used as anode, whereas MnO2∕C∕Ni was used as standard (Electro-Chem-Technic, UK) cathode for all the fuels. Fresh mixture of electrolyte, potassium hydroxide (5M), and fuel (2M) was fed to AFC and withdrawn at a rate of 1ml∕min. The anode was prepared by dispersing platinum and activated carbon in Nafion® (DuPont USA) dispersion and placing it onto a carbon paper (Lydall, USA). Finally prepared anode material was pressed onto Ni mesh and sintered to produce the required anode. The maximum power density of 16.5mW∕cm2 is obtained at 28mA∕cm2 of current density for sodium borohydride at 25°C, whereas methanol produces 31.5mW∕cm2 of maximum power density at 44mA∕cm2 of current density at 60°C. The results obtained showed that the AFC could accept multifuels.

Study of the electrooxidation of borohydride on a directly formed CoB/Ni-foam electrode and its application in membraneless direct borohydride fuel cells

2017 ◽  
Vol 5 (30) ◽  
pp. 15879-15890 ◽  
Author(s):  
Siqi Guo ◽  
Jie Sun ◽  
Zhengyan Zhang ◽  
Aokai Sheng ◽  
Ming Gao ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Power Density ◽  
Electroless Plating ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Ni Foam ◽  
Plating Method ◽  
Direct Borohydride Fuel Cells ◽  
Electroless Plating Method

CoB/Ni-foam was directly formed on a Ni-foam substrate using the electroless plating method. A membraneless DBFC with CoB/Ni-foam (7EP) as an anode showed a maximum power density of 230 mW cm−2.

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