Fe3O4 magnetic nanoparticles (MNPs) as an efficient catalyst for selective oxidation of benzylic and allylic C–H bonds to carbonyl compounds with tert-butyl hydroperoxide

RSC Advances ◽  
2016 ◽  
Vol 6 (45) ◽  
pp. 38592-38601 ◽  
Author(s):  
Monireh Zarghani ◽  
Batool Akhlaghinia
Keyword(s):  
Magnetic Nanoparticles ◽  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Fe3o4 Magnetic Nanoparticles ◽  
Efficient Catalyst ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Fe3O4 MNP as an eco-friendly catalyst was prepared, characterized and applied for oxidation of benzylic and allylic C–H bonds.

scholarly journals ABOUT THE SYNTHESIS OF 1-HYDROPEROXIDES OF FLUORO-SUBSTITUTED ARENES

2020 ◽  
pp. 15-17
Author(s):  
V. V. Chapurkin ◽  
S. V. Chapurkin
Keyword(s):  
Carbonyl Compounds ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Aromatic Carbonyl Compounds

By the interaction of fluorine-substituted aromatic carbonyl compounds with tert-butyl hydroperoxide, hydroxyhydroperoxides were obtained whose non-fluorinated analogues were not obtained due to their instability. Synthesized peroxides are of interest as initiators of fluororubber structuring.

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