Rapid surface functionalization of carbon fibres using microwave irradiation in an ionic liquid

RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 32480-32483 ◽  
Author(s):  
Kathleen M. Beggs ◽  
Magenta D. Perus ◽  
Linden Servinis ◽  
Luke A. O'Dell ◽  
Bronwyn L. Fox ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Microwave Irradiation ◽  
Organic Solvent ◽  
Low Power ◽  
Carbon Fibre ◽  
Surface Functionalization ◽  
Carbon Fibres ◽  
Power Microwave

Carbon fibre surfaces have been successfully modified using molecular grafting under low power microwave irradiation (20 W) in both 1,2-dichlorobenzene and emimTFSI. Results showed an improved IFSS by 18% for organic solvent and 28% for ionic liquid.

Membrane Damage of Human Red Blood Cells Induced by Low-Power Microwave Irradiation

1995 ◽  
Vol 14 (2) ◽  
pp. 99-105 ◽  
Author(s):  
Tudor Savopol ◽  
Roxana Moraru ◽  
Alexandru Dinu ◽  
Eugenia Kovács ◽  
Gheorghe Sajin
Keyword(s):  
Microwave Irradiation ◽  
Low Power ◽  
Red Blood Cells ◽  
Blood Cells ◽  
Membrane Damage ◽  
Human Red Blood Cells ◽  
Power Microwave

Tensometry of carbon fibres and elastomers at the diffractometer at BL20B of the Photon Factory

1998 ◽  
Vol 5 (3) ◽  
pp. 958-961
Author(s):  
D. C. Creagh ◽  
P. M. O'Neill ◽  
R. J. Mills ◽  
S. A. Holt
Keyword(s):  
Carbon Fibre ◽  
Duty Cycle ◽  
Simultaneous Recording ◽  
The Other ◽  
Imaging Plate ◽  
Relaxation Processes ◽  
Carbon Fibres ◽  
Fixed Rate ◽  
Photon Factory ◽  
System Use

Two systems have been developed for the simultaneous recording of the SAXS and the WAXS patterns from carbon fibre and elastomer samples which are placed under stress. The systems have been designed to fit inside the versatile vacuum diffractometer (BIGDIFF) at the Photon Factory. In one system, use is made of the ability to move the imaging-plate cassette. In the other, use has been made of an imaging-plate changer which can deliver up to 13 plates into position with a duty cycle of about 60 s. In this case each imaging plate can record SAXS/WAXS patterns in the range 0.5–20° due to the passage of the beam through the specimen which is mounted in a specially designed tensometer. Because BIGDIFF is a vacuum diffractometer and parasitic scattering is small, exposure times as short as 2 s can give acceptable SAXS/WAXS patterns. The systems have been used for the study of both the change of structure with strain, and the relaxation processes which occur as a result of the sample being strained at a fixed rate by a predetermined amount.

Microwave Irradiated Acetylation of p-Anisidine: A Step towards Green Chemistry

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Mousumi Chakraborty ◽  
Vaishali Umrigar ◽  
Parimal A. Parikh
Keyword(s):  
Acetic Acid ◽  
Reaction Time ◽  
Green Chemistry ◽  
Acetic Anhydride ◽  
Microwave Irradiation ◽  
Organic Solvent ◽  
Reaction Times ◽  
Microwave Energy ◽  
Operating Parameters ◽  
Feed Composition

The present study aims at assessing the effect of microwave irradiation against thermal heat on the production of N-acetyl-p-anisidine by acetylation of p-anisidine. The acetylation of p-anisidine under microwave irradiation produces N-acetyl-p-anisidine in shorter reaction times, which offers a benefit to the laboratories as well as industries. It also eliminates the use of excess solvent. Effects of operating parameters such as reaction time, feed composition, and microwave energy and reaction temperature on selectivity to the desired product have been investigated. The results indicate as high as a 98% conversion of N-acetyl-p-anisidine can be achieved within 12-15 minutes using acetic acid. The use of acetic acid as an acetylating agent against conventionally used acetic anhydride eliminates the handling of explosive acetic anhydride and also the energy intensive distillation step for separation of acetic acid. Organic solvent like acetic anhydride are not only hazardous to the environment, they are also expensive and flammable.

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