Synthesis of one-dimensional Bi2O2CO3–Bi(OHC2O4)·2H2O heterojunctions with excellent adsorptive and photocatalytic performance

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 42452-42460 ◽  
Author(s):  
Yin Peng ◽  
Ke Ke Wang ◽  
Pian-Pian Yu ◽  
Ting Liu ◽  
An Wu Xu
Keyword(s):  
Photocatalytic Activity ◽  
Photocatalytic Performance ◽  
High Concentration ◽  
One Dimensional

Novel one-dimensional Βi2O2CO3–Βi2(OHC2O4)·2H2O heterostructure photocatalyst exhibits outstanding photocatalytic activity for degrading high concentration RhB, MB and MO dyes, and excellent adsorptive capability to MO dye.

One dimensional hierarchical BiOCl microrods: their synthesis and their photocatalytic performance

CrystEngComm ◽  
2018 ◽  
Vol 20 (48) ◽  
pp. 7809-7817 ◽  
Author(s):  
Yin Peng ◽  
Yan Ge Mao ◽  
Peng Fei Kan
Keyword(s):  
Photocatalytic Activity ◽  
Hydrothermal Method ◽  
Sodium Citrate ◽  
Photocatalytic Performance ◽  
Organic Dyes ◽  
One Dimensional

One dimensional hierarchical BiOCl microrods are controlled synthesized via hydrothermal method using sodium citrate as structure-agent. These hierarchical BiOCl architectures exhibit outstanding photocatalytic activity for degrading organic dyes and phenol.

Synthesis of one-dimensional Bi2O3–Bi5O7I heterojunctions with high interface quality

CrystEngComm ◽  
2018 ◽  
Vol 20 (33) ◽  
pp. 4771-4780 ◽  
Author(s):  
Yin Peng ◽  
Yan Ge Mao ◽  
Ting Liu
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
High Concentration ◽  
Interface Quality ◽  
One Dimensional

One-dimensional Bi2O3–Bi5O7I heterostructures with high interface quality were first synthesized by calcining of BiOI–Bi(OHC2O4)·2H2O precursors. And the obtained Bi2O3–Bi5O7I heterostructures exhibit outstanding photocatalytic activity for degrading methyl orange and phenol with high concentration.

scholarly journals Ethanol-Quenching Introduced Oxygen Vacancies in Strontium Titanate Surface and the Enhanced Photocatalytic Activity

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 883 ◽  
Author(s):  
Yang Xiao ◽  
Shihao Chen ◽  
Yinhai Wang ◽  
Zhengfa Hu ◽  
Hui Zhao ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Oxygen Vacancies ◽  
Photocatalytic Performance ◽  
Localized States ◽  
Photoelectron Spectra ◽  
Infrared Light ◽  
Universal Method ◽  
High Concentration ◽  
Simple Method ◽  
X Ray

Modification of the surface properties of SrTiO3 crystals by regulating the reaction environment in order to improve the photocatalytic activity has been widely studied. However, the development of a facile, effective, and universal method to improve the photocatalytic activity of these crystals remains an enormous challenge. We have developed a simple method to modify the surface environment of SrTiO3 by ethanol quenching, which results in enhanced UV, visible and infrared light absorption and photocatalytic performance. The SrTiO3 nanocrystals were preheated to 800 °C and immediately quenched by submersion in ethanol. X-ray diffraction patterns, electron paramagnetic resonance spectra, and X-ray photoelectron spectra indicated that upon rapid ethanol quenching, the interaction between hot SrTiO3 and ethanol led to the introduction of a high concentration of oxygen vacancies on the surface of the SrTiO3 lattice. Consequently, to maintain the regional charge balance of SrTiO3, Sr2+ could be substituted for Ti4+. Moreover, oxygen vacancies induced localized states into the band gap of the modified SrTiO3 and acted as photoinduced charge traps, thus promoting the photocatalytic activity. The improved photocatalytic performance of the modified SrTiO3 was demonstrated by using it for the decomposition of rhodamine B and production of H2 from water under visible or solar light.

Tuning the Photocatalytic Performance of Plasmonic Nanocomposites (ZnO/Aux) Driven in Visible Light

2019 ◽  
Vol 8 (1) ◽  
pp. 56-61
Author(s):  
Aneeya K. Samantara ◽  
Debasrita Dash ◽  
Dipti L. Bhuyan ◽  
Namita Dalai ◽  
Bijayalaxmi Jena
Keyword(s):  
Electron Transfer ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Transfer Rate ◽  
Photocatalytic Performance ◽  
Light Exposure ◽  
Au Nanoparticle ◽  
Electron Transfer Rate ◽  
Au Nps ◽  
Zno Nanostructure

: In this article, we explored the possibility of controlling the reactivity of ZnO nanostructures by modifying its surface with gold nanoparticles (Au NPs). By varying the concentration of Au with different wt% (x = 0.01, 0.05, 0.08, 1 and 2), we have synthesized a series of (ZnO/Aux) nanocomposites (NCs). A thorough investigation of the photocatalytic performance of different wt% of Au NPs on ZnO nanosurface has been carried out. It was observed that ZnO/Au0.08 nanocomposite showed the highest photocatalytic activity among all concentrations of Au on the ZnO surface, which degrades the dye concentration within 2 minutes of visible light exposure. It was further revealed that with an increase in the size of plasmonic nanoparticles beyond 0.08%, the accessible surface area of the Au nanoparticle decreases. The photon absorption capacity of Au nanoparticle decreases beyond 0.08% resulting in a decrease in electron transfer rate from Au to ZnO and a decrease of photocatalytic activity. Background: Due to the industrialization process, most of the toxic materials go into the water bodies, affecting the water and our ecological system. The conventional techniques to remove dyes are expensive and inefficient. Recently, heterogeneous semiconductor materials like TiO2 and ZnO have been regarded as potential candidates for the removal of dye from the water system. Objective: To investigate the photocatalytic performance of different wt% of Au NPs on ZnO nanosurface and the effect of the size of Au NPs for photocatalytic performance in the degradation process. Methods: A facile microwave method has been adopted for the synthesis of ZnO nanostructure followed by a reduction of gold salt in the presence of ZnO nanostructure to form the composite. Results: ZnO/Au0.08 nanocomposite showed the highest photocatalytic activity which degrades the dye concentration within 2 minutes of visible light exposure. The schematic mechanism of electron transfer rate was discussed. Conclusion: Raspberry shaped ZnO nanoparticles modified with different percentages of Au NPs showed good photocatalytic behavior in the degradation of dye molecules. The synergetic effect of unique morphology of ZnO and well anchored Au nanostructures plays a crucial role.

scholarly journals Enhanced Visible-Light Photocatalytic Performance of SAPO-5-Based g-C3N4 Composite for Rhodamine B (RhB) Degradation

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3948
Author(s):  
Lingfang Qiu ◽  
Zhiwei Zhou ◽  
Mengfan Ma ◽  
Ping Li ◽  
Jinyong Lu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Redox Reactions ◽  
Photocatalytic Performance ◽  
Dye Degradation ◽  
Thermal Polymerization ◽  
Light Illumination ◽  
Electron Hole ◽  
Visible Light Illumination ◽  
Visible Light Photocatalytic

Novel visible-light responded aluminosilicophosphate-5 (SAPO-5)/g-C3N4 composite has been easily constructed by thermal polymerization for the mixture of SAPO-5, NH4Cl, and dicyandiamide. The photocatalytic activity of SAPO-5/g-C3N4 is evaluated by degrading RhB (30 mg/L) under visible light illumination (λ > 420 nm). The effects of SAPO-5 incorporation proportion and initial RhB concentration on the photocatalytic performance have been discussed in detail. The optimized SAPO-5/g-C3N4 composite shows promising degradation efficiency which is 40.6% higher than that of pure g-C3N4. The degradation rate improves from 0.007 min−1 to 0.022 min−1, which is a comparable photocatalytic performance compared with other g-C3N4-based heterojunctions for dye degradation. The migration of photo-induced electrons from g-C3N4 to the Al site of SAPO-5 should promote the photo-induced electron-hole pairs separation rate of g-C3N4 efficiently. Furthermore, the redox reactions for RhB degradation occur on the photo-induced holes in the g-C3N4 and Al sites in SAPO-5, respectively. This achievement not only improves the photocatalytic activity of g-C3N4 efficiently, but also broadens the application of SAPOs in the photocatalytic field.

CdS/Ag2S/g-C3N4 ternary composites with superior photocatalytic performance for hydrogen evolution under visible light irradiation

2021 ◽  
Vol 50 (9) ◽  
pp. 3253-3260 ◽  
Author(s):  
Shan Zhao ◽  
Junbiao Wu ◽  
Yan Xu ◽  
Xia Zhang ◽  
Yide Han ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Hydrogen Evolution ◽  
Visible Light Irradiation ◽  
Photocatalytic Performance ◽  
Light Irradiation ◽  
Synergic Effect

CdS/Ag2S/g-C3N4 ternary composites showed excellent photocatalytic performance toward H2 evolution. Their improved photocatalytic activity could be attributed not only to the synergic effect, but also to the introduction of Ag2S.

scholarly journals Indoor radon concentration and a diffusion model in dwellings situated in a subalkaline granitoid area, Southern Brazil

2021 ◽  
Vol 80 (17) ◽  
Author(s):  
G. Romero-Mujalli ◽  
A. Roisenberg ◽  
A. Cordova-Gonzalez ◽  
P. H. P. Stefano
Keyword(s):  
Diffusion Model ◽  
Indoor Radon ◽  
Southern Brazil ◽  
High Concentration ◽  
Indoor Radon Concentration ◽  
One Dimensional ◽  
Environmental Limits ◽  
Radon Measurements ◽  
Cr 39 Detectors

AbstractRadon (Rn), a radioactive element, has especial interest in medical geology because long-term exposure to high concentration is related to lung cancer. In this study, outdoor and indoor radon measurements were conducted in dwellings of the Piquiri Syenite Massif, located in southern Brazil, given the relative high Rn content in soils of this region. Measurements were done using CR-39 detectors and placing them inside and outside dwellings. Moreover, a one-dimensional diffusion model was performed in order to quantify the natural transport of Rn to the air in confined and aerated environments. Results indicate that the region presents relatively low air Rn concentrations, within the environmental limits; however, the health risk might increase in confined and ill-ventilated environments because of transfer from soil and exhalation from ornamental rock-material often found inside dwellings. The main north facies of the syenite, where most of the rock extractions are located, was found to have the highest air Rn concentration because of the higher soil Rn concentration, compared to other facies of the syenite.

scholarly journals Photocatalytic Decolorization of Methyl Red on Nanoporous Anodic ZrO2 of Different Crystal Structures

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 215
Author(s):  
Ewa Wierzbicka ◽  
Karolina Syrek ◽  
Klaudia Mączka ◽  
Grzegorz D. Sulka
Keyword(s):  
Photocatalytic Activity ◽  
Photocatalytic Performance ◽  
Elevated Temperatures ◽  
Aqueous Electrolyte ◽  
High Surface ◽  
High Surface Area ◽  
Methyl Red ◽  
Self Organized ◽  
Photocatalytic Decolorization ◽  
Perfect Adhesion

High surface area, self-organized nanoporous ZrO2 arrays with perfect adhesion to the Zr substrate were synthesized by anodization in an aqueous electrolyte containing (NH4)2SO4 and NH4F. The obtained semiconductor materials were tested as photocatalysts for decolorization of the methyl red (MR) as a model azo dye pollutant. It was demonstrated that as-synthesized anodic ZrO2 anodic layers are already crystalline and, therefore, do not require further thermal treatment to provide a high photocatalytic performance. However, photocatalytic efficiency could be improved by annealing at a relatively low-temperature of 350 °C. Higher annealing temperatures caused a gradual drop of photocatalytic activity. The photocatalytic behavior was correlated with the crystal phase transformation in anodic ZrO2. It was found that higher photocatalytic activity was observed for the tetragonal phase over the monoclinic phase (predominant at elevated temperatures). It results from the optimal and complex electronic structure of annealed ZrO2 with three different energy states having absorption edges at 2.0, 4.01 and 5.28 eV.

The Study on the Influential Factors of Photocatalytic Performance of Eosin-Sensitized TiO2 Nanoparticles

2013 ◽  
Vol 827 ◽  
pp. 3-7
Author(s):  
Shun Jiang He ◽  
Xue Yan Du ◽  
Qiao Wang ◽  
Jing Xu
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Photocatalytic Degradation ◽  
Degradation Rate ◽  
Photocatalytic Performance ◽  
Influential Factors ◽  
Sunlight Irradiation ◽  
Sensitization Time

The photocatalytic activity of eosin-sensitized TiO2 nanoparticles on photocatalytic degradation rate (PDR) of methyl orange under sunlight irradiation was studied. The influential factors on the degradation, such as eosin concentration, TiO2 dosage, sensitization time and sensitization temperature were also investigated. The results show that: The performance of TiO2 nanoparticles for PDR of methyl orange has been improved obviously for eosin sensitizing. The PDR of methyl orange reached 45.28% under the conditions of eosin concentration of 20mg/L, TiO2 dosage of 0.5000g/L, sensitization time of 24h and sensitization temperature of 20°C.

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