Alkylguanidinium based ionic liquids in a screening study for the removal of anionic pollutants from aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (45) ◽  
pp. 39125-39130 ◽  
Author(s):  
Roza Bouchal ◽  
Bénédicte Prelot ◽  
Peter Hesemann

Monoalkylguanidinium bis-trifluoromethane sulfonimides are highly efficient adsorbents for the sequestration of organic anions from aqueous solutions and display strongly enhanced adsorption properties compared to conventional imidazolium ILs.

RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 64665-64675 ◽  
Author(s):  
Sheng Deng ◽  
Guangshan Zhang ◽  
Yang Li ◽  
Yuan Dou ◽  
Peng Wang

In this study, a facile and highly efficient approach, the microwave-assisted (MW-aid) method, was applied for the synthesis of amidoxime-functionalized fibrous adsorbent, which exhibited enhanced adsorption capacities for Cr(vi) in aqueous solution.


RSC Advances ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 3337-3344 ◽  
Author(s):  
Jie Ma ◽  
Mengya Sun ◽  
Yulan Zeng ◽  
Zhenhua Liu ◽  
Manman Zhang ◽  
...  

Herein, Acac-C@Fe3O4, a magnetic carbon (C@Fe3O4) modified with acetylacetone (Acac), was first prepared and used as a solid-phase adsorbent for adsorbing some heavy metal ions from aqueous solution.


Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1539 ◽  
Author(s):  
Chongxiong Duan ◽  
Yi Zhang ◽  
Jiexin Li ◽  
Le Kang ◽  
Yawei Xie ◽  
...  

The effective removal of uranium from an aqueous solution is a highly valuable process for the environment and health. In this study, we developed a facile and rapid method to synthesize hierarchically porous Cu-BTC (RT-Cu-BTC) using a cooperative template strategy. The as-synthesized RT-Cu-BTC exhibited hierarchically porous structure and excellent thermostability, as revealed by X-ray powder diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. Compared with conventional metal–organic frameworks (MOFs) and zeolites, the obtained RT-Cu-BTC exhibited enhanced adsorption capacity (839.7 mg·g−1) and high removal efficiency (99.8%) in the capture of uranium (VI) from aqueous solutions. Furthermore, the conditions such as adsorbent dose, contact time, and temperature in adsorption of uranium (VI) by RT-Cu-BTC were investigated in detail. The thermodynamics data demonstrated the spontaneous and endothermic nature of the uranium (VI) adsorption process. The Langmuir isotherm and pseudo-second-order models could better reflect the adsorption process of uranium (VI) onto RT-Cu-BTC. In addition, the as-synthesized RT-Cu-BTC showed excellent stability in removing uranium (VI) from an aqueous solution. This work provides a facile and rapid approach for fabricating hierarchically porous MOFs to realize a highly efficient removal of uranium (VI) from aqueous systems.


Molecules ◽  
2021 ◽  
Vol 27 (1) ◽  
pp. 119
Author(s):  
Zeenat Zara ◽  
Deepti Mishra ◽  
Saurabh Kumar Pandey ◽  
Eva Csefalvay ◽  
Fatemeh Fadaei ◽  
...  

The effect of aqueous solutions of selected ionic liquids solutions on Ideonella sakaiensis PETase with bis(2-hydroxyethyl) terephthalate (BHET) substrate were studied by means of molecular dynamics simulations in order to identify the possible effect of ionic liquids on the structure and dynamics of enzymatic Polyethylene terephthalate (PET) hydrolysis. The use of specific ionic liquids can potentially enhance the enzymatic hydrolyses of PET where these ionic liquids are known to partially dissolve PET. The aqueous solution of cholinium phosphate were found to have the smallest effect of the structure of PETase, and its interaction with (BHET) as substrate was comparable to that with the pure water. Thus, the cholinium phosphate was identified as possible candidate as ionic liquid co-solvent to study the enzymatic hydrolyses of PET.


2014 ◽  
Vol 50 (95) ◽  
pp. 14979-14982 ◽  
Author(s):  
Jie Yang ◽  
Huiyong Wang ◽  
Jianji Wang ◽  
Yue Zhang ◽  
Zhongjia Guo

2015 ◽  
Vol 39 (12) ◽  
pp. 9181-9190 ◽  
Author(s):  
Yi Liu ◽  
Yongfeng Liu ◽  
Ting Huo ◽  
Xiaoyu Wu ◽  
Jianteng Wei ◽  
...  

Combining the advantages of ionic liquids with interpenetrating polymer networks, a novel ionic liquid modified adsorbent (PS/PVIm) was prepared and then used to enrich oleuropein to investigate the interactive forces between the adsorbent and oleuropein.


2019 ◽  
Vol 33 (7) ◽  
pp. 73-77 ◽  
Author(s):  
Ning Deng ◽  
Min Li ◽  
Sergio L. De Rooy ◽  
Bilal El-Zahab ◽  
Isiah Warner

2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.


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