A diiodo-BODIPY postmodified metal–organic framework for efficient heterogeneous organo-photocatalysis

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 23995-23999 ◽  
Author(s):  
Ying Quan ◽  
Qiu-Yan Li ◽  
Quan Zhang ◽  
Wen-Qiang Zhang ◽  
Han Lu ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Cycloaddition Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

A diiodo-BODIPY postmodified MOF acts as a highly active and recyclable heterogeneous photocatalyst for aerobic CDC and oxidation/[3 + 2]cycloaddition reactions under visible light irradiation.

scholarly journals Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Bandgap Energy ◽  
Metal Organic ◽  
Organic Framework

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

A bifunctional cationic metal–organic framework based on unprecedented nonanuclear copper(ii) cluster for high dichromate and chromate trapping and highly efficient photocatalytic degradation of organic dyes under visible light irradiation

2018 ◽  
Vol 47 (27) ◽  
pp. 9103-9113 ◽  
Author(s):  
Tian-Rui Zheng ◽  
Lin-Lu Qian ◽  
Min Li ◽  
Zhi-Xiang Wang ◽  
Ke Li ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A bifunctional cationic MOF showed fast and highly efficient Cr2O72− and CrO42− trapping, and highly efficient photocatalytic activity.

Enhanced CO2 photoreduction by a graphene–porphyrin metal–organic framework under visible light irradiation

2018 ◽  
Vol 6 (37) ◽  
pp. 18031-18035 ◽  
Author(s):  
Nasrin Sadeghi ◽  
Shahram Sharifnia ◽  
Trong-On Do
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Functionalized Graphene ◽  
Co2 Photoreduction ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Organic Framework

A photocatalyst consisting of a porphyrin-based metal–organic framework (Al/PMOF) and amine-functionalized graphene (NH2-rGO) has been designed to reduce CO2.

scholarly journals Mesoporous Cu–Cu2O@TiO2 heterojunction photocatalysts derived from metal–organic frameworks

RSC Advances ◽  
2020 ◽  
Vol 10 (25) ◽  
pp. 14550-14555 ◽  
Author(s):  
Wenling Zhao ◽  
Chengcheng Liu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Dye Degradation ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Photocatalytic Activity ◽  
Light Irradiation ◽  
Metal Organic ◽  
Organic Framework

Cu–Cu2O@TiO2 heterojunction photocatalyst derived from a metal–organic framework shows high photocatalytic activity for dye degradation under visible light irradiation.

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