Proton induced aggregation of water soluble isophthalic acid appended arylene diimides: justification with perylene derivative

RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 34027-34037 ◽  
Author(s):  
Kausik Bag ◽  
Pradip Kumar Sukul ◽  
Dines Chandra Santra ◽  
Arkapal Roy ◽  
Sudip Malik
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Isophthalic Acid ◽  
Water Soluble ◽  
The Self ◽  
Supramolecular Interactions ◽  
Π Stacking ◽  
Induced Aggregation

We report the self-assembly behaviour of five water soluble arylene diimides based on benzene, naphthalene and perylene moieties, by utilizing the essentiality of two major reversible supramolecular interactions, π-stacking and hydrogen bonding.

The influence of hydrogen bonding and π–π stacking interactions on the self-assembly properties of C3-symmetrical oligo(p-phenylenevinylene) discs

2006 ◽  
Vol 4 (8) ◽  
pp. 1539 ◽  
Author(s):  
Jeroen van Herrikhuyzen ◽  
Pascal Jonkheijm ◽  
Albertus P. H. J. Schenning ◽  
E. W. Meijer
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
The Self ◽  
Stacking Interactions ◽  
Π Stacking

Recording the Self-Assembly Behavior of Nanomaterials Directed by Hydrogen Bonding

2021 ◽  
Author(s):  
Ganghuo Pan ◽  
Jie Leng ◽  
Liye Deng ◽  
Liwen Xing ◽  
Rui Feng
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
The Self ◽  
Assembly Behavior

scholarly journals Insight into the Self-Assembly of Water-Soluble Perylene Bisimide Derivatives Through a Combined Computational and Experimental Approach

2019 ◽  
Author(s):  
Emily R. Draper ◽  
Liam Wilbraham ◽  
Dave J. Adams ◽  
Matthew Wallace ◽  
Martijn Zwijnenburg
Keyword(s):  
Density Functional Theory ◽  
Self Assembly ◽  
Density Functional ◽  
Colloidal Stability ◽  
Water Soluble ◽  
The Self ◽  
Functional Theory ◽  
Perylene Bisimide ◽  
Aggregate Growth ◽  
Perylene Bisimides

We use a combination of computational and experimental techniques to study the self-assembly and gelation of water-soluble perylene bisimides derivatised at the imide position with an amino acid. Specifically, we study the likely structure of self-assembled aggregates of the alanine-functionalised perylene bisimide (PBI-A) and the thermodynamics of their formation using density functional theory and predict the UV-vis spectra of such aggregates using time-dependent density functional theory. We compare these predictions to experiments in which we study the evolution of the UV-Vis and NMR spectra and rheology of alkaline PBI-A solutions when gradually decreasing the pH. Based on the combined computational and experimental results, we show that PBI-A self-assembles at all pH values but that aggregates grow in size upon protonation. Gelation is driven not by aggregate growth but reduction of the aggregation surface-charge and a decrease in the colloidal stability of the aggregation with respect to agglomeration.

scholarly journals Influence of the hydrophobic domain on the self-assembly and hydrogen bonding of hydroxy-amphiphiles

2019 ◽  
Vol 21 (21) ◽  
pp. 11242-11258
Author(s):  
Valery Andrushchenko ◽  
Walter Pohle
Keyword(s):  
Hydrogen Bonding ◽  
Ir Spectroscopy ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Hydrophobic Domain

IR spectroscopy paired with calculations reveals that structurally similar amphiphiles ODA and DOG form very different supramolecular assemblies.

scholarly journals Insight into the self-assembly of water-soluble perylene bisimide derivatives through a combined computational and experimental approach

Nanoscale ◽  
2019 ◽  
Vol 11 (34) ◽  
pp. 15917-15928 ◽  
Author(s):  
Emily R. Draper ◽  
Liam Wilbraham ◽  
Dave J. Adams ◽  
Matthew Wallace ◽  
Ralf Schweins ◽  
...  
Keyword(s):  
Amino Acid ◽  
Self Assembly ◽  
Experimental Approach ◽  
Water Soluble ◽  
The Self ◽  
Experimental Techniques ◽  
Perylene Bisimide ◽  
Perylene Bisimides ◽  
Insight Into

We use a combination of computational and experimental techniques to study the self-assembly and gelation of amino-acid functionalised water-soluble perylene bisimides.

Nanospheres from the self-assembly of an elastin-inspired triblock peptide

RSC Advances ◽  
2015 ◽  
Vol 5 (115) ◽  
pp. 95007-95013 ◽  
Author(s):  
A. Scelsi ◽  
B. Bochicchio ◽  
A. Smith ◽  
A. Saiani ◽  
A. Pepe
Keyword(s):  
Self Assembly ◽  
Conformational Flexibility ◽  
The Self ◽  
Π Stacking

The self-assembly of an elastin-inspired triblock peptide into nanospheres highlights the important role of conformational flexibility and π–π stacking.

Recent Progress of Synergistic Supramolecular Polymers: Preparation, Properties and Applications

2020 ◽  
Author(s):  
Yufeng Huo ◽  
Zhenfeng He ◽  
Chao Wang ◽  
Lei Zhang ◽  
Qianyu Xuan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Recent Progress ◽  
Noncovalent Interactions ◽  
The Self ◽  
Metal Coordination ◽  
Supramolecular Polymers ◽  
Π Stacking ◽  
Self Assembled

Supramolecular polymers combine the properties of traditional polymers and supramolecules. They are normally formed by the self-assembled polymerization driven via noncovalent interactions (such as hydrogen bonding, π-π stacking, metal coordination,...

Nanoparticles as template for porphyrin nanostructure growth

2019 ◽  
Vol 23 (04n05) ◽  
pp. 526-533 ◽  
Author(s):  
Mariana Hamer ◽  
Rolando M. Caraballo ◽  
Peter J. Eaton ◽  
Craig Medforth
Keyword(s):  
Self Assembly ◽  
Soret Band ◽  
Surface Interactions ◽  
Water Soluble ◽  
The Self ◽  
Stacking Interactions ◽  
Aromatic System ◽  
One Pot ◽  
Assembly Mechanism ◽  
Scattering Measurements

Porphyrins and metalloporphyrins are one of the most widely studied platforms for the construction of supramolecular structures. These compounds have an extended aromatic system that allows [Formula: see text]–[Formula: see text] stacking interactions which, together with hydrogen bonds, electrostatic forces and the formation of inter-metallic complexes arising from peripheral groups, offer a versatile platform to control the self-assembly mechanism. In this work, we present the study of nanostructures formed by self-assembly of the water-soluble porphyrins meso-tetra([Formula: see text]-methyl-4-pyridyl)porphyrin (TMPyP) and meso-tetra(4-sulfonatophenyl)porphyrin (TPPS) in the presence of hard nanotemplates. Different nanoparticles (silica, gold, and polystyrene), concentrations and synthetic procedures were explored. The obtained materials were characterized by SEM and AFM microscopies, UV-vis absorption spectroscopy and dynamic light scattering measurements. A clear modification of the SiO2 NP surface roughness using one-pot synthesis was observed. The results were variable depending on the porphyrin–surface interactions and concentrations used. At lower porphyrin concentrations, a shift of the Soret band was observed, while at higher concentrations, free NS were formed. This reflects a competition between surface and solution directed self-assembly.

Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic Au⋯Au interactions

2017 ◽  
Vol 53 (84) ◽  
pp. 11552-11555 ◽  
Author(s):  
Jiangjun Chen ◽  
Zhongxin Zhang ◽  
Chengming Wang ◽  
Zhao Gao ◽  
Zongchun Gao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
The Self ◽  
Self Assembled

Organogold(i)-based fibers and gels have been successfully constructed, which involve Au⋯Au interactions in the self-assembled structures.

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