SO3H-functionalized metal organic frameworks: an efficient heterogeneous catalyst for the synthesis of quinoxaline and derivatives

RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 35135-35143 ◽  
Author(s):  
Radoelizo S. Andriamitantsoa ◽  
Jingjing Wang ◽  
Wenjun Dong ◽  
Hongyi Gao ◽  
Ge Wang
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Frameworks ◽  
Good Stability ◽  
High Catalytic Activity ◽  
General Applicability ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst

The high dispersed –SO3H groups in the framework of MIL-101-Cr–NH–RSO3H ensure high catalytic activity for the condensation of 1,2-diamines with benzil. The catalyst exhibits good stability, general applicability and excellent recycling performance.

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Controllable synthesis of urchin-like hierarchical superstructure MOFs with high catalytic activity and stability

2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Controllable Synthesis ◽  
Metal Organic ◽  
Self Assembled

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...

The photo-, electro- and photoelectro-catalytic properties and application prospects of porous coordinate polymers

2018 ◽  
Vol 6 (15) ◽  
pp. 6130-6154 ◽  
Author(s):  
Haolin Zhu ◽  
Dingxin Liu ◽  
Dianting Zou ◽  
Jianyong Zhang
Keyword(s):  
Catalytic Activity ◽  
Specific Surface ◽  
Surface Area ◽  
Gas Adsorption ◽  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Large Specific Surface Area ◽  
Metal Organic ◽  
Application Prospects

Since the discovery of metal–organic frameworks (MOFs), covalent–organic frameworks (COFs) and zeolite–imidazole frameworks (ZIFs), many of their outstanding properties have been explored such as their large specific surface area, significant gas adsorption, and high catalytic activity.

N-heterocyclic carbene-functionalized metal–organic frameworks for the chemical fixation of CO2

2020 ◽  
Vol 49 (20) ◽  
pp. 6548-6552
Author(s):  
Yilin Jiang ◽  
Xu Zhang ◽  
Honghan Fei
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Chemical Fixation ◽  
Metal Free ◽  
Metal Organic

We have summarized the recent in situ generation approaches to form metal-free NHC-functionalized MOFs, which are a unique class of CO2-conversion catalysts with high catalytic activity, selectivity and stability.

scholarly journals Ferrocene particles incorporated into Zr-based metal–organic frameworks for selective phenol hydroxylation to dihydroxybenzenes

RSC Advances ◽  
2017 ◽  
Vol 7 (61) ◽  
pp. 38691-38698 ◽  
Author(s):  
Bin Li ◽  
Wubin Wu ◽  
Tianyong Zhang ◽  
Shuang Jiang ◽  
Xingwei Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Phenol Hydroxylation ◽  
High Catalytic Activity ◽  
Metal Organic

Ferrocene@UiO-66 exhibited high catalytic activity for phenol hydroxylation with H2O2 at room temperature in water.

Application of iron-based metal–organic frameworks in catalysis: oxidant-promoted formation of coumarins using Fe3O(BPDC)3 as an efficient heterogeneous catalyst

2016 ◽  
Vol 6 (15) ◽  
pp. 5916-5926 ◽  
Author(s):  
Thien N. Lieu ◽  
Khoa D. Nguyen ◽  
Dung T. Le ◽  
Thanh Truong ◽  
Nam T. S. Phan
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Iron Based ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

An iron-based metal–organic framework Fe3O(BPDC)3 was used as an efficient heterogeneous catalyst for the synthesis of coumarins.

scholarly journals A base-free Chan–Lam reaction catalyzed by an easily assembled Cu(II)-carboxylate metal-organic framework

2021 ◽  
pp. 174751982110265
Author(s):  
Xinhai Zhang ◽  
Jianhua Qin ◽  
Ruixuan Ma ◽  
Lei Shi
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
High Catalytic Activity ◽  
Arylboronic Acids ◽  
Metal Organic ◽  
Organic Framework

A new copper(II) metal-organic framework is constructed as a sustainable copper heterogeneous catalyst. Cu-DPTCA, with high catalytic activity, can effectively promote the Chan–Lam coupling reaction of arylboronic acids and amines without adding any base or additive.

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