Surface treatment and its effect on the electrochemical behavior of Ti–15Mo–3Nb–3Al alloy

RSC Advances ◽  
2016 ◽  
Vol 6 (43) ◽  
pp. 36345-36355 ◽  
Author(s):  
R. V. Lakshmi ◽  
Parthasarathi Bera ◽  
Chinnasamy Anandan
Keyword(s):  
Chemical Composition ◽  
Surface Morphology ◽  
Surface Treatment ◽  
Electrochemical Behavior ◽  
Sol Gel

The effect of alkaline and acidic treatments on the surface morphology, chemical composition and electrochemical behavior of Ti β–21S alloy is studied. Also, the role of GPTMS–TIP sol–gel coating in obviating the effects is explored.

scholarly journals The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure

2003 ◽  
Vol 68 (12) ◽  
pp. 979-988 ◽  
Author(s):  
Vladimir Panic ◽  
Aleksandar Dekanski ◽  
Vesna Miskovic-Stankovic ◽  
Slobodan Milonjic ◽  
Branislav Nikolic
Keyword(s):  
Electrochemical Behavior ◽  
High Frequency ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Tio2 Coating ◽  
Tio2 Layer ◽  
Low Frequencies ◽  
Tio2 Coatings ◽  
Overall Resistance

In order to understand the role of TiO2 in the deactivation mechanism of an active RuO2?TiO2 coating, an additional TiO2 layer was introduced in the support coating interphase of regular Ti//[RuO2?TiO2 anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2?TiO2 coatings, which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot obtained by electrochemical impedance spectroscopy, for a regular RuO2?TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed. The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TiO2 layer at different position within RuO2?TiO2 coating.

THE ROLE OF SOL-GEL PROCEDURE CONDITIONS IN ELECTROCHEMICAL BEHAVIOR AND CORROSION STABILITY OF Ti/[RuO2-TiO2] ANODES

2005 ◽  
Vol 20 (1) ◽  
pp. 89-103 ◽  
Author(s):  
V. Panić ◽  
A. Dekanski ◽  
V. B. Mišković-Stanković ◽  
B. Nikolić ◽  
S. Milonjić
Keyword(s):  
Electrochemical Behavior ◽  
Sol Gel ◽  
Corrosion Stability

scholarly journals Hard Coating Materials Based on Photo-Reactive Silsesquioxane for Flexible Application: Improvement of Flexible and Hardness Properties by High Molecular Weight

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1564
Author(s):  
Jong Tae Leem ◽  
Woong Cheol Seok ◽  
Ji Beom Yoo ◽  
Sangkug Lee ◽  
Ho Jun Song
Keyword(s):  
Molecular Weight ◽  
Surface Morphology ◽  
High Molecular Weight ◽  
Sol Gel ◽  
Xrd Analysis ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Coating Materials ◽  
Pencil Hardness ◽  
Coated Film ◽  
Flexible Application

EPOSS of polyhedral oligomeric silsesquioxanes (POSS) mixture structure and LPSQ of ladder-like polysilsesquioxane (LPSQ) structure were synthesized via sol–gel reaction. EPSQ had a high molecular weight due to polycondensation by potassium carbonate. The EPSQ film showed uniform surface morphology due to regular double-stranded structure. In contrast, the EPOSS-coated film showed nonuniform surface morphology due to strong aggregation. Due to the aggregation, the EPOSS film had shorter d-spacing (d1) than the EPSQ film in XRD analysis. In pencil hardness and nanoindentation analysis, EPSQ film showed higher hardness than the EPOSS film due to regular double-stranded structure. In addition, in the in-folding (r = 0.5 mm) and out-folding (r = 5 mm) tests, the EPSQ film did not crack unlike the EPOSS coated film.

Elucidating the Origin of the Toxicity of Nano-CeO2 to Chlorella pyrenoidosa：the Role of Specific Surface Area and Chemical Composition

2021 ◽  
Author(s):  
Changjian Xie ◽  
Yuhui Ma ◽  
Peng Zhang ◽  
Junzhe Zhang ◽  
Xiaowei Li ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Aquatic Environment ◽  
Cerium Dioxide ◽  
Environmental Application ◽  
Ecotoxicological Effects

With the increasing environmental application and discharge of nano cerium dioxide (nano-CeO2), it is urgent to fully understand its ecotoxicological effects on the aquatic environment. This study for the first...

Synthesis of Novel Vanadium Oxide Nanotubes and Nanofibers

2002 ◽  
Vol 740 ◽  
Author(s):  
Samuel T. Lutta ◽  
Hong Dong ◽  
Peter Y. Zavalij ◽  
M. Stanley Whittingham
Keyword(s):  
Thermal Analysis ◽  
Vanadium Oxide ◽  
Electrochemical Behavior ◽  
Redox Reactions ◽  
Sol Gel ◽  
Vanadium Oxides ◽  
Organic Polymer ◽  
Fibrous Morphology ◽  
Surfactant Templates ◽  
Vanadium Oxide Nanotubes

ABSTRACTWe are exploring the synthesis and properties of structured vanadium oxides mainly nanotubes and nanorods. Nanotubes initially formed with surfactant templates have been readily exchanged with simple cations without change of the basal-plane structure. These compounds contain d-like vanadium oxide layers with the vanadium in VO6 octahedra. This structure is particularly suitable for redox reactions. In this paper we report on synthesis of vanadium oxide, (NH4)xV2O5-d·nH2O rods using organic polymer as template. This compound has been synthesized by sol-gel reaction and subsequent hydrothermal treatment. TGA, SEM, XRD and FTIR were used to characterize this compound. Thermal analysis of this compound shows that the fibrous morphology is maintained when it is heated in nitrogen and oxygen above 300 °C. However, in both cases the size of the fibers decreases. Performance of this compound as cathode material in secondary electrolyte has been investigated using LiPF6 as electrolyte. A capacity of 140 mAh/g was obtained which remained fairly constant with up to at least 10 cycles. We also investigated electrochemical behavior of thermal products.

Research on Ethanol Production by Biological Fermentation of Potato Pulp

2013 ◽  
Vol 805-806 ◽  
pp. 281-285
Author(s):  
Zhong Xu
Keyword(s):  
Chemical Composition ◽  
Ethanol Production ◽  
Production Rate ◽  
Liquid Ratio ◽  
Fermentation Time ◽  
Potato Pulp ◽  
Fermentation Temperature ◽  
Ethanol Production Rate ◽  
Solid Liquid

Bioconversion of potato pulp to fuel ethanol, analysing the potato pulp chemical composition and determining the potato pulp in the role of microorganism produce ethanol under the best conditions is the major research. An analysis of the chemical composition of potato pulp showed that : the basic ingredients are Protein (9.72%), Starch (25.52%), Cellulose (17.90%). The effects of ethanol production rate of solid-liquid ratio, fermentation temperature, inoculumconcertration, fermentation time. The results showed that: the best conditions producting ethanol from potato pulp obtained by single factor experiments are: solid-liquid ratio: 1:15, fermentation temperature: 35°C, inoculumconcertration: 3mL, fermentation time: 20h. Under this occasion, the ethanol production rate was 0.183mL·g-1.

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