Fabricating three-dimensional mesoporous carbon network-coated LiFePO4/Fe nanospheres using thermal conversion of alginate-biomass

RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 16933-16940 ◽  
Author(s):  
Hui Guo ◽  
Xudong Zhang ◽  
Wen He ◽  
Xuena Yang ◽  
Qinze Liu ◽  
...  

Three-dimensional mesoporous carbon network-coated LiFePO4/Fe nanospheres with high-rate capability.

Energies ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1602 ◽  
Author(s):  
Jun-Ping Hu ◽  
Hang Sheng ◽  
Qi Deng ◽  
Qiang Ma ◽  
Jun Liu ◽  
...  

LiNixCoyMnzO2 (LNCM)-layered materials are considered the most promising cathode for high-energy lithium ion batteries, but suffer from poor rate capability and short lifecycle. In addition, the LiNi1/3Co1/3Mn1/3O2 (NCM 111) is considered one of the most widely used LNCM cathodes because of its high energy density and good safety. Herein, a kind of NCM 111 with semi-closed structure was designed by controlling the amount of urea, which possesses high rate capability and long lifespan, exhibiting 140.9 mAh·g−1 at 0.85 A·g−1 and 114.3 mAh·g−1 at 1.70 A·g−1, respectively. The semi-closed structure is conducive to the infiltration of electrolytes and fast lithium ion-transfer inside the electrode material, thus improving the rate performance of the battery. Our work may provide an effective strategy for designing layered-cathode materials with high rate capability.


2016 ◽  
Vol 9 (23) ◽  
pp. 19446-19454 ◽  
Author(s):  
Debdyuti Mukherjee ◽  
Guruprasada Gowda Y. K ◽  
Harish Makri Nimbegondi Kotresh ◽  
S. Sampath

Nanoscale ◽  
2014 ◽  
Vol 6 (4) ◽  
pp. 2426-2433 ◽  
Author(s):  
Haifu Huang ◽  
Lianqiang Xu ◽  
Yanmei Tang ◽  
Shaolong Tang ◽  
Youwei Du

A Ni network supported 3d graphene electrode was synthesized by a nickel etching process, and exhibited high rate capability for supercapacitor applications.


RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10296-10303 ◽  
Author(s):  
Zhiling Du ◽  
Youshun Peng ◽  
Zhipeng Ma ◽  
Chunying Li ◽  
Jing Yang ◽  
...  

Three-dimensional (3D) interconnected N-doped porous carbons (NPCs) with different levels of pore structure are synthesized by a template method using MnOx as template and N-enriched pyrrole as carbon source.


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