Synthesis of Fe/M (M = Mn, Co, Ni) bimetallic metal organic frameworks and their catalytic activity for phenol degradation under mild conditions

2017 ◽  
Vol 4 (1) ◽  
pp. 144-153 ◽  
Author(s):  
Qiao Sun ◽  
Min Liu ◽  
Keyan Li ◽  
Yitong Han ◽  
Yi Zuo ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Phenol Degradation ◽  
Catalytic Process ◽  
Mild Conditions ◽  
Metal Organic

Results show that the incorporation of Mn can significantly promote the catalytic process, Co exhibits no obviously favorable behavior, and Ni presents an apparently inhibitory impact.

Defective Pt nanoparticles encapsulated in mesoporous metal–organic frameworks for enhanced catalysis

2018 ◽  
Vol 54 (64) ◽  
pp. 8822-8825 ◽  
Author(s):  
Qiang Wang ◽  
Xu-Sheng Wang ◽  
Chun-Hui Chen ◽  
Xue Yang ◽  
Yuan-Biao Huang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Pt Nanoparticles ◽  
Mild Conditions ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time

Highly ultrafine defective Pt nanoparticles (NPs) encapsulated in the mesopores of MIL-101 (Pt(Co)@MIL-101) were achieved for the first time through a chemical dealloying approach. The obtained material could provide more active sites to contact reactants and showed superior catalytic activity towards the hydrogenation of nitroarenes under mild conditions.

scholarly journals On the importance of combining bulk- and surface-active sites to maximize the catalytic activity of metal–organic frameworks for the oxidative dehydrogenation of alcohols using alkyl hydroperoxides as hydride acceptors

2020 ◽  
Vol 10 (20) ◽  
pp. 6935-6947
Author(s):  
P. Gairola ◽  
Y. Millot ◽  
J.-M. Krafft ◽  
F. Averseng ◽  
F. Launay ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxidative Dehydrogenation ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Mild Conditions ◽  
Alkyl Hydroperoxides ◽  
Metal Organic ◽  
Alcohol Dehydrogenation ◽  
Surface Active

The combination of spectroscopically characterized bulk- and surface-active zirconium sites makes Zr-MOF crystals efficient catalysts for alcohol dehydrogenation under mild conditions.

Phosphotungstic acid encapsulated in the mesocages of amine-functionalized metal–organic frameworks for catalytic oxidative desulfurization

2014 ◽  
Vol 43 (31) ◽  
pp. 11950-11958 ◽  
Author(s):  
Xu-Sheng Wang ◽  
Yuan-Biao Huang ◽  
Zu-Jin Lin ◽  
Rong Cao
Keyword(s):  
Catalytic Activity ◽  
Phosphotungstic Acid ◽  
Metal Organic Frameworks ◽  
Oxidative Desulfurization ◽  
High Catalytic Activity ◽  
Exchange Method ◽  
Mild Conditions ◽  
Amine Functionalized ◽  
Catalytic Oxidative Desulfurization ◽  
Metal Organic

PTA@MIL-101(Cr)-NH2 has been prepared via an anion exchange method, and showed high catalytic activity for oxidative desulfurization under mild conditions.

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Petal-shaped MOF assembled with gold nanocage and urate oxidase used as artificial enzyme nanohybrid for tandem catalysis and dual-channel biosensing

Nanoscale ◽  
2021 ◽  
Author(s):  
Zejun Sun ◽  
Yujiao Sun ◽  
Meng Yang ◽  
Hui Jin ◽  
Rijun Gui
Keyword(s):  
Metal Organic Frameworks ◽  
Urate Oxidase ◽  
Tandem Catalysis ◽  
Artificial Enzyme ◽  
One Pot ◽  
Mild Conditions ◽  
Dual Channel ◽  
Metal Organic

A facile one-pot precipitation was employed to prepare a petal-shaped hybrid in mild conditions. The hybrid is composed of urate oxidase (UOx) encapsulated into zeolite-like metal-organic frameworks (MOF) with doping...

Efficient Solvent-Free Carbon Dioxide Fixation Reactions with Epoxides Under Mild Conditions by Mixed-Ligand Zinc(II) Metal-Organic Frameworks

ChemCatChem ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 2401-2408 ◽  
Author(s):  
Parth Patel ◽  
Bhavesh Parmar ◽  
Rukhsana I. Kureshy ◽  
Noor-ul Khan ◽  
Eringathodi Suresh
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Fixation ◽  
Mixed Ligand ◽  
Free Carbon ◽  
Solvent Free ◽  
Mild Conditions ◽  
Free Carbon Dioxide ◽  
Metal Organic

Controllable synthesis of urchin-like hierarchical superstructure MOFs with high catalytic activity and stability

2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Controllable Synthesis ◽  
Metal Organic ◽  
Self Assembled

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...

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