An anionic metal–organic framework based on angular tetracarboxylic acid and a mononuclear copper ion for selective gas adsorption

2016 ◽  
Vol 3 (11) ◽  
pp. 1411-1418 ◽  
Author(s):  
Jingjing Jiao ◽  
Huimin Liu ◽  
Fengli Chen ◽  
Dongjie Bai ◽  
Shunshun Xiong ◽  
...  

A rare example of a MOF, ZJNU-55, based on mononuclear Cu(COO)4 and an angular diisophthalate linker with a novel topological structure exhibiting selective adsorption of C2H2 and CO2 from CH4 at room temperature was presented.

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6314-6319 ◽  
Author(s):  
Yajing Ling ◽  
Chengling Song ◽  
Yunlong Feng ◽  
Mingxing Zhang ◽  
Yabing He

A new MOF constructed from a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibits selective adsorption of CO2 and C2H6 over CH4 at room temperature.


2015 ◽  
Vol 44 (35) ◽  
pp. 15697-15702 ◽  
Author(s):  
Xiuling Zhang ◽  
Yong-Zheng Zhang ◽  
Da-Shuai Zhang ◽  
Baoyong Zhu ◽  
Jian-Rong Li

A hydrothermally stable MOF, [Zn2(tcpt)OH]·solvents (1·solvents), was synthesized, in which an unusual paddlewheel SBU, Zn2(COO)3, was found. Furthermore, 1 can adsorb considerable amounts of H2 and displays high selective adsorption of CO2 over N2.


2015 ◽  
Vol 51 (46) ◽  
pp. 9463-9466 ◽  
Author(s):  
Hongming He ◽  
Yang Song ◽  
Chuanqi Zhang ◽  
Fuxing Sun ◽  
Rongrong Yuan ◽  
...  

A stable microporous anionic MOF based on a dendritic aromatic 12-carboxyl ligand was synthesized, which demonstrates high Qst for CO2 and highly selective gas adsorption of CO2 over CH4.


2020 ◽  
Vol 49 (4) ◽  
pp. 1135-1142 ◽  
Author(s):  
Yu Ye ◽  
Jianfeng Du ◽  
Libo Sun ◽  
Yuchuan Liu ◽  
Shun Wang ◽  
...  

Two zinc metal–organic framework isomers were designed and constructed using 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine and dipyridinylbenzene as co-ligands for gas adsorption and separation.


2020 ◽  
Vol 56 (41) ◽  
pp. 5520-5523
Author(s):  
Peng-Dan Zhang ◽  
Xue-Qian Wu ◽  
Tao He ◽  
Lin-Hua Xie ◽  
Qiang Chen ◽  
...  

The selective adsorption and separation of C2 hydrocarbons have been achieved in a “flexible-robust” MOF based on a guest-dependent gate-opening effect.


2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9688 ◽  
Author(s):  
Yangyang Liu ◽  
Ying-Pin Chen ◽  
Tian-Fu Liu ◽  
Andrey A. Yakovenko ◽  
Aaron M. Raiff ◽  
...  

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