Transition-metal-free controlled polymerization of 2-polyfluorophenyl-5-trimethylsilylthiophenes: the substituent impact of fluorine

2016 ◽  
Vol 7 (46) ◽  
pp. 7116-7125 ◽  
Author(s):  
Takanobu Sanji ◽  
Keiji Nose ◽  
Junko Kakinuma ◽  
Tomokazu Iyoda
Keyword(s):  
Transition Metal ◽  
Controlled Polymerization ◽  
Metal Free

A transition-metal-free polymerization of a series of 2-polyfluorophenyl-5-trimethylsilylthiophenes promoted by fluoride anions is reported.

Transition-metal-free and halogen-free controlled synthesis of poly(3-alkylthienylene vinylene) via the Horner–Wadsworth–Emmons condensation reaction

2018 ◽  
Vol 9 (15) ◽  
pp. 1996-2001 ◽  
Author(s):  
Eisuke Goto ◽  
Yuto Ochiai ◽  
Mitsuru Ueda ◽  
Tomoya Higashihara
Keyword(s):  
Transition Metal ◽  
Condensation Reaction ◽  
Controlled Synthesis ◽  
Controlled Polymerization ◽  
Metal Free ◽  
Halogen Free

Controlled polymerization without a transition metal or halogen.

scholarly journals Transition-metal-free controlled polymerization for poly(p-aryleneethynylene)s

2015 ◽  
Vol 6 (1) ◽  
pp. 492-496 ◽  
Author(s):  
Takanobu Sanji ◽  
Asahi Motoshige ◽  
Hideaki Komiyama ◽  
Junko Kakinuma ◽  
Rie Ushikubo ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Transition Metal ◽  
High Molecular Weight ◽  
Catalytic Amount ◽  
Chain Growth ◽  
Controlled Polymerization ◽  
High Molecular Weight Polymer ◽  
Molecular Weight Polymer ◽  
Metal Free ◽  
A Chain

A catalytic amount of fluoride anions promoted the polymerization of 1-pentafluorophenyl-4-[(trimethylsilyl)ethynyl]benzene, providing a high-molecular-weight polymer in a chain-growth-like manner.

Transition-metal-free catalytic hydroboration reduction of amides to amines

2020 ◽  
Vol 7 (21) ◽  
pp. 3515-3520
Author(s):  
Wubing Yao ◽  
Jiali Wang ◽  
Aiguo Zhong ◽  
Shiliang Wang ◽  
Yinlin Shao
Keyword(s):  
Transition Metal ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Value Added ◽  
Metal Free

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

2021 ◽  
Author(s):  
Fengqian Zhao ◽  
Xiao-Feng Wu
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Metal Free

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

2019 ◽  
Author(s):  
Arumugavel Murugan ◽  
Venkata Nagarjuna Babu ◽  
Nagaraj Sabarinathan ◽  
Sharada Duddu. S
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Practical Approach ◽  
Hypervalent Iodine ◽  
Radical Mechanism ◽  
Photoredox Catalysis ◽  
Metal Free

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2

2011 ◽  
Vol 32 (1) ◽  
pp. 118-122 ◽  
Author(s):  
Lipeng ZHOU ◽  
Chaofeng ZHANG ◽  
Tao FANG ◽  
Bingbing ZHANG ◽  
Ying WANG ◽  
...  
Keyword(s):  
Transition Metal ◽  
Selective Oxidation ◽  
Free System ◽  
Metal Free ◽  
Oxidation Of Alcohols

Defect engineering and characterization of active sites for efficient electrocatalysis

Nanoscale ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 3327-3345
Author(s):  
Xuecheng Yan ◽  
Linzhou Zhuang ◽  
Zhonghua Zhu ◽  
Xiangdong Yao
Keyword(s):  
Transition Metal ◽  
Active Sites ◽  
Defect Engineering ◽  
Metal Free

This review highlights recent advancements in defect engineering and characterization of both metal-free carbons and transition metal-based electrocatalysts.

Transition metal free, green and facile halogenation of ketene dithioacetals using a KX–oxidant system

2021 ◽  
Author(s):  
Vishakha Rai ◽  
Ganesh Shivayogappa Sorabad ◽  
Mahagundappa Rachappa Maddani
Keyword(s):  
Transition Metal ◽  
Ambient Temperature ◽  
Metal Free ◽  
Ketene Dithioacetals ◽  
System P ◽  
Oxidative Halogenation ◽  
Potassium Halide

A facile oxidative halogenation of α-oxo ketene dithioacetals is achieved by using a potassium halide and an oxidant combination under transition metal free conditions at ambient temperature.

Highly chemoselective deoxygenation of N-heterocyclic N-oxides under transition metal-free conditions

2021 ◽  
Vol 19 (16) ◽  
pp. 3735-3742
Author(s):  
Se Hyun Kim ◽  
Ju Hyeon An ◽  
Jun Hee Lee
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Eosin Y ◽  
Metal Free ◽  
Simple Protocol

Here, we provide an operationally simple protocol for the highly chemoselective deoxygenation of various functionalized N-heterocyclic N-oxides under visible light-mediated photoredox conditions with Na2-eosin Y as an organophotocatalyst.

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