All-thiophene-based conjugated porous organic polymers

2016 ◽  
Vol 7 (31) ◽  
pp. 5031-5038 ◽  
Author(s):  
Chao-Jing Sun ◽  
Peng-Fei Wang ◽  
Hua Wang ◽  
Bao-Hang Han
Keyword(s):  
Ferric Chloride ◽  
Oxidative Coupling ◽  
Room Temperature ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Coupling Polymerization

Novel all-thiophene-based conjugated porous organic polymers (ThPOP-1 and ThPOP-2) were synthesized through ferric chloride-catalyzed oxidative coupling polymerization at room temperature.

Hypercrosslinked porous polycarbazoles via one-step oxidative coupling reaction and Friedel–Crafts alkylation

2015 ◽  
Vol 6 (13) ◽  
pp. 2478-2487 ◽  
Author(s):  
Long Pan ◽  
Qi Chen ◽  
Jian-Hua Zhu ◽  
Jia-Guo Yu ◽  
Yu-Jian He ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Coupling Reaction ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Oxidative Coupling Reaction ◽  
One Step ◽  
Facile Preparation

Facile preparation of hypercrosslinked carbazole-based porous organic polymers via FeCl3-promoted one-step oxidative coupling reaction and Friedel–Crafts alkylation from the vinyl or hydroxymethyl functionalized carbazole is reported.

Synthesis of Poly(Dinaphthylene Ether) by Oxidative Coupling Polymerization of Di(1-Naphthoxy)Pentane Using Cobalt (III) Acetylacetonate

1998 ◽  
Vol 10 (3) ◽  
pp. 241-247
Author(s):  
Takashi Okada ◽  
Satoru Amou ◽  
Osamu Haba ◽  
Mitsuru Ueda
Keyword(s):  
Oxidative Coupling ◽  
Room Temperature ◽  
Methanesulfonic Acid ◽  
Polymer Structure ◽  
Naphthalene Ring ◽  
Molecular Weights ◽  
Polymer Formation ◽  
Coupling Polymerization ◽  
C Nmr ◽  
Model Reactions

Poly(dinaphthylene ether) was prepared by oxidative coupling polymerization of 1,5-di(naphthoxy)pentane. Polymerizations were conducted in 1,2-dichloroethane in the presence of cobalt (III) acetylacetonate and methanesulfonic acid at room temperature and produced poly(dinaphthylene ether)s with number-average molecular weights up to 10 000. The polymer structure was characterized by 1H and 13C-NMR spectroscopies, and selective coupling was found to occur at the C-4 position of the 1-substituted naphthalene ring. The model reactions were studied to demonstrate the feasibility of polymer formation.

scholarly journals Vinylene-bridged donor–acceptor type porous organic polymers for enhanced photocatalysis of amine oxidative coupling reactions under visible light

RSC Advances ◽  
2021 ◽  
Vol 11 (53) ◽  
pp. 33653-33660
Author(s):  
Bang Wu ◽  
Xinyue Jiang ◽  
Yang Liu ◽  
Qiu-Yan Li ◽  
Xinsheng Zhao ◽  
...  
Keyword(s):  
Visible Light ◽  
Oxidative Coupling ◽  
Coupling Reactions ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Photocatalytic Activities ◽  
Highly Effective ◽  
Donor Acceptor ◽  
Oxidative Coupling Reactions

Two vinylene-bridged D–A structural POPs are constructed by the electron-rich triarylamine and electron-deficient tricyanomesitylene, which exhibited highly effective photocatalytic activities for aerobic oxidative coupling of amines to imine.

Preparation and adsorption performance of cross-linked porous polycarbazoles

2014 ◽  
Vol 2 (38) ◽  
pp. 16181-16189 ◽  
Author(s):  
Jian-Hua Zhu ◽  
Qi Chen ◽  
Zhu-Yin Sui ◽  
Long Pan ◽  
Jiaguo Yu ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Coupling Reaction ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
One Pot ◽  
Oxidative Coupling Reaction ◽  
Adsorption Performance ◽  
One Step

Hypercrosslinked carbazole-based porous organic polymers were prepared via FeCl3-promoted one-step oxidative coupling reaction and Friedel–Crafts alkylation in one pot.

Phosphorus Containing Porous Organic Polymers: Synthetic Techniques and Applications in Organic Synthesis and Catalysis

2021 ◽  
Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji
Keyword(s):  
Organic Synthesis ◽  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Organic Polymer ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer ◽  
Phosphorus Containing

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...

scholarly journals Rational design of bifunctional conjugated microporous polymers

2021 ◽  
Author(s):  
Yanpei Song ◽  
Pui Ching Lan ◽  
Kyle Martin ◽  
Shengqian Ma
Keyword(s):  
Rational Design ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
First Report ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Conjugated microporous polymers (CMPs) are an emerging class of porous organic polymers that combine -conjugated skeletons with permanent micropores. Since their first report in 2007, the enormous exploration of linkage...

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