ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide

2016 ◽  
Vol 14 (31) ◽  
pp. 7468-7479 ◽  
Author(s):  
Ryota Yoshida ◽  
Katsuhiro Isozaki ◽  
Tomoya Yokoi ◽  
Nobuhiro Yasuda ◽  
Koichiro Sadakane ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
Ruthenium Complex

A Ru-bound norvaline shows enhanced catalytic activity for the oxidation of methoxybenzenes with unique chemoselectivity.

ChemInform Abstract: ONO-Pincer Ruthenium Complex-Bound Norvaline for Efficient Catalytic Oxidation of Methoxybenzenes with Hydrogen Peroxide.

ChemInform ◽  
2016 ◽  
Vol 47 (50) ◽  
Author(s):  
Ryota Yoshida ◽  
Katsuhiro Isozaki ◽  
Tomoya Yokoi ◽  
Nobuhiro Yasuda ◽  
Koichiro Sadakane ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Oxidation ◽  
Ruthenium Complex

Decomposition of hydrogen peroxide on a two-component NiO-CdO catalyst and the effect of ionizing radiation on its catalytic properties

1979 ◽  
Vol 44 (4) ◽  
pp. 1015-1022 ◽  
Author(s):  
Viliam Múčka
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Nickel Oxide ◽  
Catalytic Properties ◽  
Cadmium Oxide ◽  
Chemisorb Oxygen ◽  
Composition Region ◽  
Chemisorbed Oxygen ◽  
Two Component

The catalytic properties of two-component catalyst nickel oxide-cadmium oxide with the proportions of the components covering the whole composition region 0-100% were examined by studying the decomposition of hydrogen peroxide in aqueous solution on it. In the range 0-25 mol.% CdO, cadmium oxide is found to affect infavourably the ability of nickel oxide to chemisorb oxygen. The amount of the chemisorbed oxygen increases several times on gamma irradiation of the samples. The effect of cadmium oxide on the catalytic activity of the system shows up in fresh samples only indirectly via the changed amount of the oxygen chemisorbed. In older samples the initial catalytic activity of the system is changed, which can be explained based on the concept of bivalent catalytic centres in terms of the co-action of the catalytic centres of the two oxides, which are in equilibrium. The irradiation of the system under study speeds up the processes leading to the establishing of this equilibrium which is thermally very stable, and results in a substantial increase of the catalytic activity of the samples investigated.

Hydrogen peroxide decomposition on a two-component CuO-Cr2O3 catalyst

1988 ◽  
Vol 53 (8) ◽  
pp. 1636-1646 ◽  
Author(s):  
Viliam Múčka ◽  
Kamil Lang
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Extreme Values ◽  
Catalytic Properties ◽  
Active Components ◽  
Catalytic Systems ◽  
Heterogeneous Catalytic ◽  
Peroxide Decomposition ◽  
Two Component ◽  
Catalytically Active

Some physical and catalytic properties of the two-component copper(II)oxide-chromium(III)oxide catalyst with different content of both components were studied using the decomposition of the aqueous solution of hydrogen peroxide as a testing reaction. It has been found that along to both basic components, the system under study contains also the spinel structure CuCr2O4, chromate washable by water and hexavalent ions of chromium unwashable by water. The soluble chromate is catalytically active. During the first period of the reaction the equilibrium is being established in both homogeneous and heterogeneous catalytic systems. The catalytic activity as well as the specific surface area of the washed solid is a non-monotonous function of its composition. It seems highly probable that the extreme values of both these quantities are not connected with the detected admixtures in the catalytic system. The system under study is very insensitive with regard to the applied doses of gamma radiation. Its catalytic properties are changed rather significantly after the thermal treatment and particularly after the partial reduction to low degree by hydrogen. The observed changes of the catalytic activity of the system under study are very probably in connection with the changes of the valence state of the catalytically active components of the catalyst.

scholarly journals A new highly active La2O3–CuO–MgO catalyst for the synthesis of cumyl peroxide by catalytic oxidation

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12532-12542
Author(s):  
HanShuang Liu ◽  
KaiJun Wang ◽  
XiaoYan Cao ◽  
JiaXin Su ◽  
Zhenggui Gu
Keyword(s):  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
Highly Active

The La2O3–CuO–MgO catalyst acts on the oxidation of cumene and shows excellent catalytic activity through the coordination of surface and interior.

scholarly journals Low platinum alloy catalyst PtCo3 obtaining high catalytic activity and stability with great water and CO2 resistance for catalytic oxidation of toluene

Fuel ◽  
2022 ◽  
Vol 307 ◽  
pp. 121794
Author(s):  
Jianwu Zou ◽  
Yankun Du ◽  
Rongjia Fang ◽  
Xiaoshuang Duan ◽  
Yangjia Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
High Catalytic Activity ◽  
Platinum Alloy ◽  
Alloy Catalyst

Study on the Electrochemical Behavior of Ferric Stearate and its Electro-Catalytic Oxidation of Hydrogen Peroxide

2009 ◽  
Vol 610-613 ◽  
pp. 161-164
Author(s):  
Li Li Liang ◽  
Xue Gang Luo ◽  
Xiao Yan Lin
Keyword(s):  
Hydrogen Peroxide ◽  
Cyclic Voltammetry ◽  
Catalytic Oxidation ◽  
Tin Oxide ◽  
Electrochemical Behavior ◽  
Doctor Blade ◽  
Conductive Glass ◽  
Oxidation Of Hydrogen ◽  
Electro Catalytic Oxidation ◽  
Catalytic Effects

A ferric stearate electrode was made by doctor-blade methods using the Fluorine tin oxide (FTO) conductive glass. The electrochemical behavior of ferric stearate electrode was studied by the cyclic voltammetry. The electro-catalytic effects of ferric stearate on H2O2 were also investigated by cyclic voltammetry.

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