Pyridine-functionalized organic porous polymers: applications in efficient CO2 adsorption and conversion

2017 ◽  
Vol 41 (8) ◽  
pp. 2869-2872 ◽  
Author(s):  
Zhenzhen Yang ◽  
Huan Wang ◽  
Guipeng Ji ◽  
Xiaoxiao Yu ◽  
Yu Chen ◽  
...  

Pyridine-functionalized porous organic polymers showed excellent CO2 uptake capacity and served as efficient catalysts for the formylation of amines with CO2/H2 after metallization with Ru(0) nanoparticles.

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 690 ◽  
Author(s):  
Kimberley Cousins ◽  
Renwu Zhang

Hydrogen (H2) is one of the best candidates to replace current petroleum energy resources due to its rich abundance and clean combustion. However, the storage of H2 presents a major challenge. There are two methods for storing H2 fuel, chemical and physical, both of which have some advantages and disadvantages. In physical storage, highly porous organic polymers are of particular interest, since they are low cost, easy to scale up, metal-free, and environmentally friendly. In this review, highly porous polymers for H2 fuel storage are examined from five perspectives: (a) brief comparison of H2 storage in highly porous polymers and other storage media; (b) theoretical considerations of the physical storage of H2 molecules in porous polymers; (c) H2 storage in different classes of highly porous organic polymers; (d) characterization of microporosity in these polymers; and (e) future developments for highly porous organic polymers for H2 fuel storage. These topics will provide an introductory overview of highly porous organic polymers in H2 fuel storage.


2018 ◽  
Vol 9 (36) ◽  
pp. 4585-4595 ◽  
Author(s):  
Jordy Guadalupe ◽  
Ana M. Ray ◽  
Eva M. Maya ◽  
Berta Gómez-Lor ◽  
Marta Iglesias

New, robust, insoluble porous organic polymers based on the semiconducting platform of hexamethyltruxene with high Brunauer–Emmett–Teller specific surface areas and interesting catalytic activity are presented.


2018 ◽  
Vol 20 (20) ◽  
pp. 4655-4661 ◽  
Author(s):  
Chao Xie ◽  
Jinliang Song ◽  
Haoran Wu ◽  
Yue Hu ◽  
Huizhen Liu ◽  
...  

Novel porous organic polymers with multifunctional sites using plant-derived polyphenols as the building blocks showed superior applications in CO2 fixation and I2 adsorption.


2017 ◽  
Vol 8 (11) ◽  
pp. 1833-1839 ◽  
Author(s):  
Shuang Hao ◽  
Yuchuan Liu ◽  
Chuning Shang ◽  
Zhiqiang Liang ◽  
Jihong Yu

A class of imidazole ionic liquid functionalized porous organic polymers has been synthesized by the Friedel–Crafts alkylation reaction. The resulting materials show high CO2 uptake and catalytic activity in the syntheses of benzimidazole derivatives.


2021 ◽  
Author(s):  
Neha Rani Kumar ◽  
Prasenjit Das ◽  
Abhijeet R Agrawal ◽  
Sanjay Mandal ◽  
Sanjio S Zade

A series of four thiophene and triazine containing conjugated porous polymers (CPPs) comprising of the same building block, tris(thienyl)triazine, is synthesized using the alkyne cyclotrimerization reaction for TT-CPP1, Sonogashira coupling...


2014 ◽  
Vol 50 (16) ◽  
pp. 1937 ◽  
Author(s):  
Vincent Guillerm ◽  
Łukasz J. Weseliński ◽  
Mohamed Alkordi ◽  
M. Infas H. Mohideen ◽  
Youssef Belmabkhout ◽  
...  

2017 ◽  
Vol 7 (5) ◽  
pp. 1028-1039 ◽  
Author(s):  
Ke Dong ◽  
Qi Sun ◽  
Xiangju Meng ◽  
Feng-Shou Xiao

Porous organic polymers serve as a versatile platform for the development of highly efficient heterogeneous catalysts.


Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...


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