Insights into understanding water mediated proton conductivity in an intercalated hybrid solid of kaolinite at ambient temperature

2016 ◽  
Vol 40 (12) ◽  
pp. 10233-10239 ◽  
Author(s):  
Hao Yang ◽  
Xin Sun ◽  
Shao-Xian Liu ◽  
Yang Zou ◽  
Li Li ◽  
...  
Keyword(s):  
Amino Acid ◽  
Ambient Temperature ◽  
Proton Conductivity ◽  
Room Temperature ◽  
Low Cost ◽  
Natural Amino Acid ◽  
High Proton Conductivity ◽  
High Proton

The intercalated hybrid solid of kaolinite mineral with a natural amino acidl-alanine is a green and low-cost material and shows water mediated high proton conductivity at room temperature.

Nafion – Azole Composite Membranes for High Temperature PEMFC

2014 ◽  
Vol 783-786 ◽  
pp. 1692-1697
Author(s):  
Je Deok Kim ◽  
Mun Suk Jun
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
High Temperature ◽  
Proton Conductivity ◽  
Composite Membrane ◽  
Room Temperature ◽  
Composite Membranes ◽  
Thermal And Mechanical Properties ◽  
High Proton Conductivity ◽  
High Proton

Nafion-azole (benzimidazole, 1,2,4-triazole, 1,2,3-triazole) composite membranes were prepared by room temperature and autoclave solution processing for high temperature (above 100 °C) PEMFC. Among the various Nafion – azole composite membranes, Nafion – 1,2,3-triazole membrane showed excellent flexibility, thermal stability, and homogeneous structure. Nafion – 1,2,4-triazole composite membrane had high thermal and mechanical properties, and also showed high proton conductivity of 0.02 S/cm at the temperature of 160 °C under dry (N2) condition.

A Two-Dimensional Inorganic–Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

2016 ◽  
Vol 55 (17) ◽  
pp. 8971-8975 ◽  
Author(s):  
Hai-Rong Zhao ◽  
Chen Xue ◽  
Cui-Ping Li ◽  
Kai-Ming Zhang ◽  
Hong-Bin Luo ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Room Temperature ◽  
Two Dimensional ◽  
High Proton Conductivity ◽  
Organic Hybrid ◽  
High Proton

scholarly journals Multifunctional Chiral Three-Dimensional Phosphite Frameworks Showing Dielectric Anomaly and High Proton Conductivity

2021 ◽  
Vol 9 ◽  
Author(s):  
S. S. Yu ◽  
C. Y. Xu ◽  
X. Pan ◽  
X. Q. Pan ◽  
H. B. Duan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Proton Transfer ◽  
Proton Conductivity ◽  
Dielectric Response ◽  
Room Temperature ◽  
Three Dimensional ◽  
Dielectric Anomaly ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bonding Networks

Chair 3D Co(II) phosphite frameworks have been prepared by the ionothermal method. It belongs to chiral space group P3221, and the whole framework can be topologically represented as a chiral 4-connected qtz net. It shows a multistep dielectric response arising from the reorientation of Me2-DABCO in the chiral cavities. It can also serve as a pron conductor with high conductivity, 1.71 × 10−3 S cm−1, at room temperature, which is attributed to the formation of denser hydrogen-bonding networks providing efficient proton-transfer pathways.

scholarly journals High proton conductivity behavior in a 2D metal sulfite constructed from a histidine ligand

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16130-16135 ◽  
Author(s):  
Yike Ma ◽  
Liangliang Huang ◽  
Zhijia Xiu ◽  
Yuheng Yang ◽  
Xiaodong Wang ◽  
...  
Keyword(s):  
Amino Acid ◽  
Proton Conductivity ◽  
High Proton Conductivity ◽  
Hydrothermal Conditions ◽  
Organic Hybrid ◽  
High Proton ◽  
Amino Acid Histidine ◽  
Conductivity Behavior

In the presence of the amino acid histidine, an inorganic–organic hybrid metal sulfite (compound 1), has been prepared under hydrothermal conditions. Compound 1 shows a high proton conductivity of, approximately 10−3 S cm−1 at 348 K and 98% RH.

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

2018 ◽  
Vol 47 (3) ◽  
pp. 654-658 ◽  
Author(s):  
Jingyu Shi ◽  
Kangcai Wang ◽  
Jing Li ◽  
Hongmei Zeng ◽  
Qinghua Zhang ◽  
...  
Keyword(s):  
Amino Acid ◽  
Room Temperature ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Metal Phosphate ◽  
High Proton Conductivity ◽  
System P ◽  
High Proton ◽  
Conducting Materials ◽  
Phosphate System

Presented here is the first example of an amino acid-templated metal phosphate with a three-dimensional structure, which shows excellent water stability and a high proton conductivity at room temperature under 98% relative humidity.

High proton conductivity in a nickel(ii) complex and its hybrid membrane

2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Hydrogen Bond ◽  
Proton Conductivity ◽  
Hybrid Membrane ◽  
Water Molecules ◽  
Hybrid Membranes ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bond Networks

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.

Synthesis and characterization of chemically stable sulfonated copoly(triazole imide)s with high proton conductivity

2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Synthesis And Characterization ◽  
High Proton Conductivity ◽  
High Proton

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou
Keyword(s):  
Structural Change ◽  
Relative Humidity ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Cation Substitution ◽  
High Proton Conductivity ◽  
High Proton

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.

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