One-step in situ preparation of liquid-exfoliated pristine graphene/Si composites: towards practical anodes for commercial lithium-ion batteries

2016 ◽  
Vol 40 (8) ◽  
pp. 7053-7060 ◽  
Author(s):  
Hong Liu ◽  
Zhigang Shen ◽  
Shuaishuai Liang ◽  
Lei Liu ◽  
Min Yi ◽  
...  

The exfoliation of graphite flakes into graphene sheets and the insertion of Si nanoparticles and surfactants into them occur simultaneously.

2019 ◽  
Vol 356 ◽  
pp. 895-903 ◽  
Author(s):  
Ming-Shan Wang ◽  
Guo-Liang Wang ◽  
Shuai Wang ◽  
Jun Zhang ◽  
Jing Wang ◽  
...  

2018 ◽  
Vol 532 ◽  
pp. 738-745 ◽  
Author(s):  
Xiaozhen Hu ◽  
Yan Jin ◽  
Bin Zhu ◽  
Zheng Liu ◽  
Defu Xu ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Yong Chen ◽  
Xuejun Zhang ◽  
Yanhong Tian ◽  
Xi Zhao

Silicon nanoparticles have been successfully inserted into graphene sheets via a novel method combining freeze-drying and thermal reduction. The structure, electrochemical performance, and cycling stability of this anode material were characterized by SEM, X-ray diffraction (XRD), charge/discharge cycling, and cyclic voltammetry (CV). CV showed that the Si/graphene nanocomposite exhibits remarkably enhanced cycling performance and rate performance compared with bare Si nanoparticles for lithium ion batteries. XRD and SEM showed that silicon nanoparticles inserted into graphene sheets were homogeneous and had better layered structure than the bare silicon nanoparticles. Graphene sheets improved high rate discharge capacity and long cycle-life performance. The initial capacity of the Si nanoparticles/graphene keeps above 850 mAhg−1after 100 cycles at a rate of 100 mAg−1. The excellent cycle performances are caused by the good structure of the composites, which ensured uniform electronic conducting sheet and intensified the cohesion force of binder and collector, respectively.


RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75653-75658 ◽  
Author(s):  
Hongyun Yue ◽  
Zhenpu Shi ◽  
Qiuxian Wang ◽  
Ting du ◽  
Yanmin Ding ◽  
...  

A cobalt doped MOF acted as a catalyst and carbon source for a CNTs containing anode material with better performance.


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