Regio- and stereoselective synthesis of conjugated trienes from silaborated 1,3-enynes

2016 ◽  
Vol 40 (7) ◽  
pp. 6340-6346 ◽  
Author(s):  
Ende Li ◽  
Hui Zhou ◽  
Victor Östlund ◽  
Robin Hertzberg ◽  
Christina Moberg
Keyword(s):  
Stereoselective Synthesis ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Conjugated Trienes

Palladium-catalyzed silaboration of 1,3-enynes followed by Suzuki–Miyaura coupling with alkenyl iodides and Hiyama coupling with aryl iodides provides access to 1,3,5-trienes with defined regio- and stereochemistry.

scholarly journals Palladium-catalyzed three-component tandem reaction of sulfonyl hydrazones, aryl iodides and allenes: highly stereoselective synthesis of (Z)-α-hydroxymethyl allylic sulfones

RSC Advances ◽  
2017 ◽  
Vol 7 (79) ◽  
pp. 50372-50377 ◽  
Author(s):  
Yunlei Hou ◽  
Qi Shen ◽  
Liangyu Zhu ◽  
Yufei Han ◽  
Yanfang Zhao ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Tandem Reaction ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Sulfonyl hydrazones have been identified as an excellent sulfonyl anion surrogate in the tandem reaction with aryl iodides and allenes for the synthesis of functionalized (Z)-allylic sulfones.

ChemInform Abstract: Stereoselective Synthesis of Tricyclic Compounds by Intramolecular Palladium-Catalyzed Addition of Aryl Iodides to Carbonyl Groups.

ChemInform ◽  
2016 ◽  
Vol 47 (36) ◽  
Author(s):  
Jakub Saadi ◽  
Christoph Bentz ◽  
Kai Redies ◽  
Dieter Lentz ◽  
Reinhold Zimmer ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Carbonyl Groups ◽  
Aryl Iodides ◽  
Tricyclic Compounds ◽  
Palladium Catalyzed
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