Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)

2016 ◽  
Vol 40 (8) ◽  
pp. 6720-6727 ◽  
Author(s):  
Yang Chi ◽  
Sheng-Ping Guo ◽  
Hong-Jian Kong ◽  
Huai-Guo Xue

Systematic study of RE3S3BO3 (RE = Sm, Gd) compounds with a novel structure type is demonstrated.

ChemInform ◽  
2010 ◽  
Vol 42 (4) ◽  
pp. no-no
Author(s):  
Volodymyr Babizhetskyy ◽  
Arndt Simon ◽  
Hansjuergen Mattausch ◽  
Kurt Hiebl ◽  
Chong Zheng

2014 ◽  
Vol 893 ◽  
pp. 357-360
Author(s):  
Li Ya Li ◽  
Yi Cheng Ge ◽  
Yuan Dong Peng

We reported a systematic study of the effect of Zr content on the structural and magnetic properties of rapidly quenched Sm (CobalFe0.11Cu0.10Zrx)7 alloys with x varying from 0 to 0.04. The results show that the addition of Zr greatly affected the microstructure and magnetic properties of the heat-treated ribbons. The Zr-free ribbon had crystallized as the 1:7H structure as the main phase while the ribbon with Zr addition adopted the 2:17R structure type. A Sm2Co7 phase was observed in the heat-treated ribbons when the Zr content x increased to 0.04. It is found that while the Zr content was increased from 0 to 0.04, saturation magnetization of the heat-treated ribbons was decreased from 11.9kGs to 3.3 kGs, and the intrinsic coercivity was increased from 0.07 kOe to 11.7 kOe. The highest intrinsic coercivity, Hci=11.7 kOe, was obtained in the ribbon with Zr content of 0.03.


2015 ◽  
Vol 11 (2) ◽  
Author(s):  
Juan Ren ◽  
Ning-Chao Zhang ◽  
Peng Wang ◽  
Chao Ning ◽  
Hong Zhang ◽  
...  

Author(s):  
Nian-Tzu Suen ◽  
Tae-Soo You ◽  
Svilen Bobev

The syntheses and single-crystal and electronic structures of three new ternary lithium rare earth germanides, RE5−xLixGe4(RE = Nd, Sm and Gd;x≃ 1), namely tetrasamarium lithium tetragermanide (Sm3.97Li1.03Ge4), tetraneodymium lithium tetragermanide (Nd3.97Li1.03Ge4) and tetragadolinium lithium tetragermanide (Gd3.96Li1.03Ge4), are reported. All three compounds crystallize in the orthorhombic space groupPnmaand adopt the Gd5Si4structure type (Pearson codeoP36). There are six atoms in the asymmetric unit: Li1 in Wyckoff site 4c, RE1 in 8d, RE2 in 8d, Ge1 in 8d, Ge2 in 4cand Ge3 in 4c. One of the RE sites,i.e.RE2, is statistically occupied by RE and Li atoms, accounting for the small deviation from ideal RE4LiGe4stoichiometry.


ChemInform ◽  
2009 ◽  
Vol 40 (50) ◽  
Author(s):  
Y. Q. Li ◽  
N. Hirosaki ◽  
R. J. Xie ◽  
T. Takeda ◽  
S. E. Lofland ◽  
...  

1991 ◽  
Vol 182 (1) ◽  
pp. 5-8 ◽  
Author(s):  
E. Antic-Fidancev ◽  
M. Lemaitre-Blaise ◽  
P. Porcher ◽  
I. Bueno ◽  
C. Parada ◽  
...  

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