Comparison of the metabolism of inorganic and organic selenium species between two selenium accumulator plants, garlic and Indian mustard

Metallomics ◽  
2017 ◽  
Vol 9 (1) ◽  
pp. 61-68 ◽  
Author(s):  
Yasumitsu Ogra ◽  
Yurie Ogihara ◽  
Yasumi Anan

Selenomethionine (SeMet) can be metabolized into other selenoamino acids such as Se-methylselenocysteine and selenohomolanthionine in selenium-accumulator plants.

Author(s):  
J. L. Gómez-Ariza ◽  
D. Sánchez-Rodas ◽  
E. Morales ◽  
O. Herrgott ◽  
I. L. Marr

2018 ◽  
Vol 3 (12) ◽  
Author(s):  
Tristram Chivers ◽  
Risto S. Laitinen

Abstract Selenium and tellurium form binary halides in which the chalcogen can be in formal oxidation states (IV), (II) or (I). They are versatile reagents for the preparation of a wide range of inorganic and organic selenium and tellurium compounds taking advantage of the reactivity of the chalcogen–halogen bond. With the exception of the tetrafluorides, the tetrahalides are either commercially available or readily prepared. On the other hand, the low-valent species, EX2 (E = Se, Te; X = Cl, Br) and E2X2 (E = Se, Te; X = Cl, Br) are unstable with respect to disproportionation and must be used as in situ reagents. Organoselenium and tellurium halides are well-known in oxidation states (IV) and (II), as exemplified by REX3, R2EX2 and REX (R = alkyl, aryl; E = Se, Te; X = F, Cl, Br, I); mixed-valent (IV/II) compounds of the type RTeX2TeR are also known. This chapter surveys the availability and/or preparative methods for these widely used reagents followed by examples of their applications in synthetic inorganic and organic selenium and tellurium chemistry. For both the binary halides and their organic derivatives, the discussion is subdivided according to the formal oxidation state of the chalcogen.


Metallomics ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1257-1263 ◽  
Author(s):  
Yasumitsu Ogra ◽  
Maya Shimizu ◽  
Kazuaki Takahashi ◽  
Yasumi Anan

Organic selenium metabolites of plants and animals such as selenoamino acids and selenosugars are metabolized to selenomethionine in yeast.


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