The highly selective aerobic oxidation of cyclohexane to cyclohexanone and cyclohexanol over V2O5@TiO2 under simulated solar light irradiation

2017 ◽  
Vol 19 (1) ◽  
pp. 311-318 ◽  
Author(s):  
Dexin Yang ◽  
Tianbin Wu ◽  
Chunjun Chen ◽  
Weiwei Guo ◽  
Huizhen Liu ◽  
...  
Keyword(s):  
Photocatalytic Oxidation ◽  
Aerobic Oxidation ◽  
Light Irradiation ◽  
Solar Light ◽  
Simulated Solar Light ◽  
Solar Light Irradiation ◽  
Selective Aerobic Oxidation

V2O5@TiO2 is very efficient for the photocatalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol under simulated solar light irradiation.

Simultaneous photocatalytic redox removal of chromium(vi) and arsenic(iii) by hydrothermal carbon-sphere@nano-Fe3O4

2019 ◽  
Vol 6 (3) ◽  
pp. 937-947 ◽  
Author(s):  
Feng Liu ◽  
Weifang Zhang ◽  
Le Tao ◽  
Boyuan Hao ◽  
Jing Zhang
Keyword(s):  
Iron Oxide ◽  
Light Irradiation ◽  
Solar Light ◽  
Carbon Sphere ◽  
Simulated Solar Light ◽  
Chromium Vi ◽  
Solar Light Irradiation ◽  
Nano Fe3o4

The reduction of Cr(vi) and oxidation of As(iii) were markedly accelerated by employing iron oxide encapsulated in hydrothermal carbon sphere under simulated solar light irradiation.

Simultaneous evaporation and decontamination of water on a novel membrane under simulated solar light irradiation

2020 ◽  
Vol 267 ◽  
pp. 118695 ◽  
Author(s):  
Zhao Gao ◽  
Hanpei Yang ◽  
Jingwei Li ◽  
Li Kang ◽  
Lina Wang ◽  
...  
Keyword(s):  
Light Irradiation ◽  
Solar Light ◽  
Simulated Solar Light ◽  
Solar Light Irradiation

Nonmetal–metal–semiconductor-promoted P/Ag/Ag2O/Ag3PO4/TiO2 photocatalyst with superior photocatalytic activity and stability

2015 ◽  
Vol 3 (34) ◽  
pp. 17858-17865 ◽  
Author(s):  
Xiaohong Hu ◽  
Qi Zhu ◽  
Xinlong Wang ◽  
Naoki Kawazoe ◽  
Yingnan Yang
Keyword(s):  
Photocatalytic Activity ◽  
Sol Gel ◽  
Light Irradiation ◽  
Solar Light ◽  
Tio2 Photocatalyst ◽  
Photocatalytic Ability ◽  
Composite Photocatalyst ◽  
Gel Method ◽  
Simulated Solar Light ◽  
Solar Light Irradiation

P/Ag/Ag2O/Ag3PO4/TiO2 composite photocatalyst has been successfully prepared by a sol–gel method. It shows highly enhanced photocatalytic ability and stability under simulated solar light irradiation.

Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation

2012 ◽  
Vol 9 (6) ◽  
pp. 558 ◽  
Author(s):  
Lei Wu ◽  
Xuefeng Hu
Keyword(s):  
Aqueous Solutions ◽  
Aromatic Amines ◽  
Saline Water ◽  
Chloride Ions ◽  
Light Irradiation ◽  
Solar Light ◽  
Natural Seawater ◽  
Simulated Solar Light ◽  
Solar Light Irradiation ◽  
Transformation Pathway

Environmental context Aromatic amines are widely used chemicals, which show enhanced toxicity and longer environmental persistence when halogenated. We investigated the chlorination of aniline in seawater and in natural aqueous solutions containing Fe3+ and Cl–, under simulated sunlight irradiation. The results increase our understanding of the transformation pathway of typical nitrogen-containing aromatic contaminants in the environment. Abstract Photochlorination of aniline was observed in aqueous solutions containing dissolved FeIII and chloride ions under simulated solar light irradiation. Effects of O2, Cl–, Fe3+ and pH on the formation of chloroanilines (CAs) were investigated. para-chloroaniline (4CA) was identified as the main chlorinated product. The formation of 4CA is enhanced with increased concentrations of Cl– or Fe3+, and decreased pH, whereas oxygen plays a negligible role in the process. The results indicate that, Cl• is formed mainly by the photodissociation of FeCl2+–FeCl2+ complexes, and reacts with Cl– to produce Cl2•–. Aniline is then oxidised by Cl2•– into an anilino radical cation, which further reacts with Cl2•– to generate CAs. The photochlorination of aniline in natural seawater was also observed. Other phototransformation products of aniline were detected and a transformation pathway was proposed. This work provides evidence for the photochemical chlorination path of aniline-based aromatic amines in aqueous solutions.

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