scholarly journals An insight into metal organic framework derived N-doped graphene for the oxidative degradation of persistent contaminants: formation mechanism and generation of singlet oxygen from peroxymonosulfate

2017 ◽  
Vol 4 (2) ◽  
pp. 315-324 ◽  
Author(s):  
Ping Liang ◽  
Chi Zhang ◽  
Xiaoguang Duan ◽  
Hongqi Sun ◽  
Shaomin Liu ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Formation Mechanism ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Doped Graphene ◽  
Metal Organic ◽  
Insight Into ◽  
Persistent Contaminants ◽  
Organic Framework

Singlet oxygen produced during peroxymonosulfate activation by N-graphene dominated the pollutants degradation.

Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

2016 ◽  
Vol 23 (1) ◽  
pp. 214-218 ◽  
Author(s):  
Ashlee J. Howarth ◽  
Cassandra T. Buru ◽  
Yangyang Liu ◽  
Ann M. Ploskonka ◽  
Karel J. Hartlieb ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Oxidative Detoxification ◽  
Organic Framework

scholarly journals A Singlet Oxygen Reservoir Based on Poly-Pyridone and Porphyrin Nanoscale Metal–Organic Framework for Cancer Therapy

CCS Chemistry ◽  
2020 ◽  
pp. 1187-1202
Author(s):  
Bo-Ru Xie ◽  
Chu-Xin Li ◽  
Yun Yu ◽  
Jin-Yue Zeng ◽  
Ming-Kang Zhang ◽  
...  
Keyword(s):  
Cancer Therapy ◽  
Singlet Oxygen ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

H3O2 Bridging Ligand in a Metal–Organic Framework. Insight into the Aqua-Hydroxo↔Hydroxyl Equilibrium: A Combined Experimental and Theoretical Study

2013 ◽  
Vol 135 (15) ◽  
pp. 5782-5792 ◽  
Author(s):  
Richard F. D’Vries ◽  
Victor A. de la Peña-O’Shea ◽  
Natalia Snejko ◽  
Marta Iglesias ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Framework ◽  
Bridging Ligand ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

New Mechanistic Insight into Stepwise Metal-Center Exchange in a Metal-Organic Framework Based on Asymmetric Zn4Clusters

2014 ◽  
Vol 20 (10) ◽  
pp. 2945-2952 ◽  
Author(s):  
Wei Meng ◽  
Huijun Li ◽  
Zhouqing Xu ◽  
Shanshan Du ◽  
Yunxia Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Center ◽  
Mechanistic Insight ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Molecular Insight into Fluorocarbon Adsorption in Pore Expanded Metal–Organic Framework Analogs

2020 ◽  
Vol 142 (6) ◽  
pp. 3002-3012 ◽  
Author(s):  
Jian Zheng ◽  
Dushyant Barpaga ◽  
Benjamin A. Trump ◽  
Manish Shetty ◽  
Yanzhong Fan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Expanded Metal ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

Hollow Metal–Organic Framework Microparticles Assembled via a Self-Templated Formation Mechanism

2015 ◽  
Vol 15 (11) ◽  
pp. 5169-5173 ◽  
Author(s):  
Ilrang Lee ◽  
Sora Choi ◽  
Hee Jung Lee ◽  
Moonhyun Oh
Keyword(s):  
Formation Mechanism ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Hollow Metal ◽  
Organic Framework

scholarly journals Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

2019 ◽  
Vol 10 ◽  
pp. 2422-2427 ◽  
Author(s):  
Ghada Ayoub ◽  
Mihails Arhangelskis ◽  
Xuan Zhang ◽  
Florencia Son ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Chemical Warfare Agents ◽  
Mustard Gas ◽  
Air Oxidation ◽  
Substitution Pattern ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior.

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