Interaction of copper with dinitrogen tetroxide in 1-butyl-3-methylimidazolium-based ionic liquids

2017 ◽  
Vol 46 (13) ◽  
pp. 4430-4434
Author(s):  
I. V. Morozov ◽  
E. B. Deeva ◽  
T. Yu. Glazunova ◽  
S. I. Troyanov ◽  
F. I. Guseinov ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Copper Dissolution ◽  
Dinitrogen Tetraoxide ◽  
Dinitrogen Tetroxide ◽  
Reaction Media

Ionic liquids that are stable toward oxidation and nitration and are based on the 1-n-butyl-3-methylimidazloium cation (BMIm+) can be used as solvents and reaction media for copper dissolution in liquid dinitrogen tetraoxide N2O4.

Synthesis, Characterization and Applications of Dicationic Ionic Liquids in Organic Synthesis

2020 ◽  
Vol 17 (4) ◽  
pp. 450-464
Author(s):  
Mohammad Javaherian ◽  
Seyyed Jafar Saghanezhad
Keyword(s):  
Ionic Liquids ◽  
Organic Synthesis ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Dicationic Ionic Liquids ◽  
Physical And Chemical ◽  
Reaction Media ◽  
And Chemical Properties

Dicationic ionic liquids are an emerging group of Ionic Liquids (ILs) that are currently receiving much attention as green reaction media and catalysts. Because of a great number of possible combinations of cations and anions, the physical and chemical properties of dicationic ionic liquids are more tunable and broader than monocationic ILs. Therefore, their unique properties have made them the target of many applied and fundamental researches. Actually, dicationic ionic liquids are more effective and rather fascinating than traditional monocationic ILs. So, due to greater versatility and diversity, their applications in organic synthesis have been extensively grown. In this review, we have focused on the synthesis, characterization and applications of dicationic ionic liquids, especially, in organic synthesis.

Ionic liquids and supercritical carbon dioxide: green and alternative reaction media for chemical processes

2016 ◽  
Vol 32 (6) ◽  
Author(s):  
Ruixia Liu ◽  
Peng Zhang ◽  
Suojiang Zhang ◽  
Ting Yan ◽  
Jiayu Xin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Chemical Processes ◽  
Reaction Media ◽  
Supercritical Carbon

AbstractIonic liquids (ILs) and supercritical CO

Synthesis of organophosphorus compounds using ionic liquids

2018 ◽  
Vol 34 (5) ◽  
pp. 727-740 ◽  
Author(s):  
Lavinia Macarie ◽  
Nicoleta Plesu ◽  
Smaranda Iliescu ◽  
Gheorghe Ilia
Keyword(s):  
Ionic Liquids ◽  
Organophosphorus Compounds ◽  
Inorganic Compounds ◽  
Green Solvents ◽  
High Solubility ◽  
Chemical Reagents ◽  
Reaction Media ◽  
Organophosphorus Chemistry ◽  
Synthesis Reactions ◽  
Toxic Organic Solvents

Abstract Organophosphorus chemistry was developed in the last decade by promoting the synthesis reactions using ionic liquids either as solvent or catalyst. Ionic liquids (ILs), the so-called “green solvents”, have gained interest in the synthesis of organophosphorus compounds as alternatives to flammable and toxic organic solvents and catalysts. ILs have beneficial properties because they provide high solubility for many organic and inorganic compounds or metal complexes, have no vapor pressure, and are reusable. Also, in some cases, they can enhance the reactivity of chemical reagents. In this review, we aimed at showing the synthesis of different organophosphorus compounds under green and mild conditions using ILs as reaction media or catalysts, according to a trend developed in the last years. A novel trend is to perform these syntheses under microwave irradiation conditions together with ILs as solvents and catalysts.

Gas-liquid acetylene hydrochlorination under nonmercuric catalysis using ionic liquids as reaction media

2011 ◽  
Vol 13 (6) ◽  
pp. 1495 ◽  
Author(s):  
Gang Qin ◽  
Yuhan Song ◽  
Rui Jin ◽  
Jun Shi ◽  
Zhiyong Yu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Acetylene Hydrochlorination ◽  
Reaction Media

Solvate Ionic Liquids as Reaction Media for Electrocyclic Transformations

2016 ◽  
Vol 2016 (5) ◽  
pp. 913-917 ◽  
Author(s):  
Daniel J. Eyckens ◽  
Megan E. Champion ◽  
Bronwyn L. Fox ◽  
Prusothman Yoganantharajah ◽  
Yann Gibert ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Reaction Media

Synthesis of 1,8-dioxo-octahydro-xanthene and tetrahydrobenzo[b]pyran derivatives promoted by two bis-imidazolium-based ionic liquids

2021 ◽  
Vol 08 ◽  
Author(s):  
Maryam Shirzad ◽  
Mitra Nasiri ◽  
Nader Daneshvar ◽  
Farhad Shirini ◽  
Hassan Tajik
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Knoevenagel Condensation ◽  
Reaction Rates ◽  
Xanthene Derivatives ◽  
Acidic Ionic Liquids ◽  
Dicationic Ionic Liquids ◽  
Acidic Nature ◽  
Work Up ◽  
Reaction Media

Aim and objective: In this work, we have prepared two bis-dicationic ionic liquids with the same cationic core (Bis-imidazole) and different counter-anions using sulfuric acid and perchloric acids. After that, the efficiency and ability of these compounds as catalysts were investigated and compared in the promotion of Knoevenagel condensation and synthesis of benzo[b]pyran derivatives to see the effect of the anionic counter-part in the reaction. Material and method: In a 25 mL round-bottomed flask, a mixture of aldehyde (1.0 mmol), 1,3-cyclodicarbonyl (2.0 mmol) and the desired amount of the mentioned acidic ionic liquids was heated at 90°C in the absence of solvent (Reaction A) or In a 25 mL round-bottomed flask, a mixture of aldehyde (1.0 mmol), 1,3-cyclodicarbonyl (1.0 mmol), malononitrile, (1.1 mmol) and optimized amounts of the ionic liquid in water (3.0 mL) was heated at 80°C (Reaction B) for the appropriated time. After the completion of the reactions which were monitored by TLC (n-hexane: EtOAc; 3:1), 10 mL of water was added and the mixture was stirred for 2 minutes. Then, the products were separated by filtration and were washed several times with water. After drying, the pure products were obtained while there was no need to further. Results: Comparison of the obtained results from both of the ionic liquids revealed that [H2-Bisim][HSO4]2 because of its more acidic structure had a more catalytic activity for the preparation of 1,8-dioxo-octahydro-xanthene derivatives but [H2-Bisim][ClO4]2 was relatively more efficient for the synthesis of tetrahydrobenzo[b]pyran derivatives since the stronger acidic nature of [H2-Bisim][HSO4]2 may prevent the simple activation of malononitrile in the reaction media. Conclusion: In this study, we have introduced efficient methods for the synthesis of 1,8-dioxo-octahydro-xanthene and tetrahydrobenzo[b]pyran derivatives in the presence of catalytic amounts of [H2-Bisim][ClO4]2 and [H2-Bisim][HSO4]2 These methods have several advantages such as ease of preparation and handling of the catalysts, high reaction rates, excellent yields, eco-friendly procedures and simple work-up.

scholarly journals Synergy between Ionic Liquids and CuCl2 in Gas–Liquid Phase Reactions of Acetylene Hydrochlorination

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 504 ◽  
Author(s):  
Yi Yu ◽  
Yuxue Yue ◽  
Bolin Wang ◽  
Haihua He ◽  
Zhong-Ting Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Activated Carbon ◽  
Liquid Phase ◽  
Dft Calculations ◽  
Synergetic Effect ◽  
Good Explanation ◽  
Experimental Results ◽  
Acetylene Hydrochlorination ◽  
Reaction Media

We studied the acetylene hydrochlorination in gas–liquid phase reactions using ionic liquids (IL) as the reaction media and CuCl2 as the catalyst. The Cu-IL catalyst showed strong synergy between the IL and the Cu(II) active catalytic species. For [PrMIm]Cl, the Cu-IL catalyst exhibited significant enhancement of the catalytic activity in comparison with the CuCl2 catalyst supported on activated carbon and the IL alone as the catalyst. We have also performed DFT calculations of the reaction process, which provides a good explanation of our experimental results and for the synergetic effect. Our result suggests that ILs may be used to improve the activity of other metallic catalysts for the hydrochlorination reaction of acetylene.

InCl3·4H2O-promoted green preparation of xanthenedione derivatives in ionic liquids

2005 ◽  
Vol 83 (1) ◽  
pp. 16-20 ◽  
Author(s):  
Xuesen Fan ◽  
Xueyuan Hu ◽  
Xinying Zhang ◽  
Jianji Wang
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Green Synthesis ◽  
Novel Method ◽  
Green Procedure ◽  
Reaction Media ◽  
Operational Simplicity

A green procedure for the synthesis of xanthenedione derivatives (3) through InCl3·4H2O-promoted condensation of aldehydes (1) and 5,5-dimethyl-1,3-cyclohexanedione (2) in ionic liquids is described in this paper. This novel method has such advantages as operational simplicity and environmental benignancy together with enhanced atom utilization. Moreover, the reaction media and the catalyst can be recovered conveniently and reused effectively for at least six times.Key words: ionic liquid, xanthenedione derivatives, indium trichloride, green synthesis.

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