The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis

2017 ◽  
Vol 46 (4) ◽  
pp. 1277-1282 ◽  
Author(s):  
Szymon Rogalski ◽  
Patrycja Żak ◽  
Natalia Tadeuszyk ◽  
Krystian Pyta ◽  
Piotr Przybylski ◽  
...  
Keyword(s):  
Hydrogen Chloride ◽  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Catalytically Active

Activation of amidobenzylidene ruthenium complexes – latent catalysts of olefin metathesis with hydrogen chloride leads to the formation of highly catalytically active carbamatobenzylidene ruthenium chelates.

Solid Supported Ruthenium Complexes for Olefin Metathesis

2013 ◽  
Vol 17 (22) ◽  
pp. 2592-2608 ◽  
Author(s):  
Fatma Hamad ◽  
Cheng Kai ◽  
Yuan Cai ◽  
Yu Xie ◽  
Yin Lu ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes

DFT Study of the Olefin Metathesis Catalyzed by Ruthenium Complexes

2003 ◽  
Vol 22 (5) ◽  
pp. 940-947 ◽  
Author(s):  
Fernando Bernardi ◽  
Andrea Bottoni ◽  
Gian Pietro Miscione
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Dft Study

scholarly journals Activation of olefin metathesis complexes containing unsymmetrical unsaturated N-heterocyclic carbenes by copper and gold transmetalation

2019 ◽  
Vol 55 (77) ◽  
pp. 11583-11586 ◽  
Author(s):  
Fadwa Kamal ◽  
Sophie Colombel-Rouen ◽  
Adrien Dumas ◽  
Jean-Paul Guégan ◽  
Thierry Roisnel ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Heterocyclic Carbenes

The activation of latent ruthenium complexes containing two unsymmetrical NHCs by copper and gold transmetalation leads to impressive initiation rates in olefin metathesis.

scholarly journals Innentitelbild: Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis (Angew. Chem. 4/2017)

2017 ◽  
Vol 129 (4) ◽  
pp. 930-930 ◽  
Author(s):  
Rafał Gawin ◽  
Anna Kozakiewicz ◽  
Piotr A. Guńka ◽  
Paweł Dąbrowski ◽  
Krzysztof Skowerski
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Efficient Tool ◽  
Highly Efficient

scholarly journals Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis

2020 ◽  
Vol 142 (47) ◽  
pp. 19895-19901
Author(s):  
Jennifer Morvan ◽  
François Vermersch ◽  
Ziyun Zhang ◽  
Laura Falivene ◽  
Thomas Vives ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Optically Pure

scholarly journals Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands

2018 ◽  
Vol 14 ◽  
pp. 3122-3149 ◽  
Author(s):  
Veronica Paradiso ◽  
Chiara Costabile ◽  
Fabia Grisi
Keyword(s):  
Olefin Metathesis ◽  
Catalytic Properties ◽  
Ruthenium Complexes ◽  
Current State ◽  
State Of Research ◽  
Metathesis Catalysts

An overview on the catalytic properties of ruthenium complexes for olefin metathesis bearing monodentate unsymmetrical N-heterocyclic diaminocarbene ligands is provided. The non-symmetric nature of these NHC architectures strongly influences activity and selectivity of the resulting catalysts. The main achievements that have been accomplished in significant areas of olefin metathesis up to the current state of research are discussed.

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