Narrow-band red emitting phosphor BaTiF6:Mn4+: preparation, characterization and application for warm white LED devices

2016 ◽  
Vol 45 (44) ◽  
pp. 17886-17895 ◽  
Author(s):  
Xiaoli Gao ◽  
Yan Song ◽  
Guixia Liu ◽  
Xiangting Dong ◽  
Jinxian Wang ◽  
...  

A narrow-band red emitting BaTiF6:Mn4+phosphor with a microspindle morphology is applied to warm white LEDs by combination with a blue chip and YAG:Ce3+.

2021 ◽  
Author(s):  
Kasturi Singh ◽  
R. Marikumar ◽  
Rachna Devi ◽  
Sivakumar Vaidyanathan

¬Narrow band red emitters is the key to solve the problem encountered by the current white LED technology. In this context, a series of new red emitting Li3BaSrLa3¬(MoO4)8:Eu3+ phosphors were...


2017 ◽  
Vol 5 (29) ◽  
pp. 7253-7261 ◽  
Author(s):  
L. Y. Wang ◽  
E. H. Song ◽  
Y. Y. Zhou ◽  
T. T. Deng ◽  
S. Ye ◽  
...  

Phosphor Rb2ZrF6:Mn4+has been synthesizedviaa co-precipitation method. Series of WLEDs were fabricated by combining YAG:Ce3+yellow phosphor and different amount of Rb2ZrF6:Mn4+red phosphor with InGaN blue chips.


2020 ◽  
Vol 49 (19) ◽  
pp. 6205-6219 ◽  
Author(s):  
Rachna Devi ◽  
Sivakumar Vaidyanathan

The synthesized molecular Eu-complex based hybrid white LED showed superior color rendering index. In addition, the complex also showed on-off-on luminescence with exposure to acid–base vapours.


2019 ◽  
Vol 8 ◽  
pp. 244-253
Author(s):  
Nadezhda Chayka ◽  
Danila Semenov

In this paper, we investigated the properties of the developed optical filter, that cuts off part of the blue light range in the spectrum of a white LED, which is harmful to the human eye. The developed filter allows reflecting up to 30 % of blue light in the range from 435 to 440 nm.


2018 ◽  
Vol 56 (1A) ◽  
pp. 183 ◽  
Author(s):  
Nguyen Le Anh

This study focuses on the fabrication of red-emitting phosphor based on K2SiF6: Mn4+ phosphor. Characteristic emissive peaks in the red region of the Mn4+ ions involve the energy transfer from spin-forbidden states of 2Eg → 4A2, showing narrow band emission peaks at 609, 614, 631, 635 and 647 nm. Meanwhile, their absorptive peaks involve the energy transfer from spin-allowed states of 4A2 → 4Tg; the excited wavelength of the Mn4+ is in the range 360 - 460 nm. Thus, the K2SiF6: Mn4+ phosphor is particularly suitable for redundancy of 460 nm - Light Emitting Diode (LED); it complements the red emission of the commercial White LEDs.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2706-2717
Author(s):  
Zhipeng Wang ◽  
Zhijun Wang ◽  
Yuebin Li ◽  
Jinjin Liu ◽  
Qi Bao ◽  
...  

The change of the emission spectra of Mg1.93Y2-xAl2Si2O12:0.07Ce3+, xMn2+ originates from the change of the structure and the energy transfer between ions.


2018 ◽  
Vol 6 (32) ◽  
pp. 8670-8678 ◽  
Author(s):  
L. Y. Wang ◽  
E. H. Song ◽  
Y. Y. Zhou ◽  
T. T. Deng ◽  
S. Ye ◽  
...  

A Rb-based fluorotitanate red-emitting phosphor Rb2TiF6:MnM4+ with an internal quantum efficiency of 91% was synthesized and presents exceptional luminescence properties, thermal stability and longevity under LED working conditions.


2021 ◽  
Vol 63 (3) ◽  
pp. 3-7
Author(s):  
Thi Kim Chi Nguyen ◽  
◽  
Duy Hung Nguyen ◽  
Tan Vinh Le ◽  
Thanh Vu Tran ◽  
...  

A series of Mn4+-activated CaAl2O4 (CAO) compounds were synthesized by co-precipitation to seek a candidate for a red-emitting phosphor to be employed in a white LED. The crystal structure, morphology, and fluorescence properties of the as-obtained phosphors were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL). The deep red luminescence of Mn4+ in CaAl2O4 is reported and discussed. The excitation spectrum exhibited broadband emission between 260 and 550 nm with three peaks dominating at 320 nm due to the transition of 4A24T1. Theemission spectra between 600 to 720 nm displays an overwhelming emission peak at 654 nm owing to the 2E4A2 transition of Mn4+ ion.This research demonstrates the great promise of CaAl2O4:Mn4+ as a commercial red phosphor in warm white LEDs and opens up new avenues for the exploration of novel non-rare-earth red-emitting phosphors.


2020 ◽  
Vol 49 (27) ◽  
pp. 9239-9253 ◽  
Author(s):  
Marikumar Rajendran ◽  
Sivakumar Vaidyanathan

Oxide based highly efficient narrow band red emitting phosphors are still a bottleneck in white LED applications.


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