A recyclable ionic liquid-oxomolybdenum(vi) catalytic system for the oxidative desulfurization of model and real diesel fuel

2016 ◽  
Vol 45 (38) ◽  
pp. 15242-15248 ◽  
Author(s):  
Diana Julião ◽  
Ana C. Gomes ◽  
Martyn Pillinger ◽  
Rita Valença ◽  
Jorge C. Ribeiro ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Diesel Fuel ◽  
Oxidative Desulfurization ◽  
Catalytic Oxidative Desulfurization

The extractive and catalytic oxidative desulfurization (ECODS) of model and real diesel has been studied using the complex [MoO2Cl2(di-tBu-bipy)](1) (di-tBu-bipy = 4,4′-di-tert-butyl-2,2′-bipyridine) as a (pre)catalyst, aq. H2O2 as an oxidant, and either acetonitrile or an ionic liquid (IL) as a solvent and extractant.

scholarly journals Phosphomolybdic acid immobilized on ionic liquid-modified hexagonal boron nitride for oxidative desulfurization of fuel

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 54266-54276 ◽  
Author(s):  
Haiyan Ji ◽  
Haitao Ju ◽  
Rong Lan ◽  
Peiwen Wu ◽  
Jia Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Oxidative Desulfurization ◽  
Supported Catalyst ◽  
Phosphomolybdic Acid ◽  
Catalytic Performance ◽  
Catalytic Oxidative Desulfurization ◽  
Enhanced Stability ◽  
Excellent Catalytic Performance

An ionic liquid modified hexagonal boron nitride was developed for preparation of a supported catalyst with enhanced stability and excellent catalytic performance in catalytic oxidative desulfurization.

Effect of activated carbon supported Ce/Fe based catalyst for catalytic oxidative desulfurization of Malaysian diesel fuel

2019 ◽  
Author(s):  
Wan Nazwanie Wan Abdullah ◽  
Wan Azelee Wan Abu Bakar ◽  
Nor Hakimin Abdullah ◽  
Wan Nur Aini Wan Mokhtar ◽  
Salmiah Jamal Mat Rosid ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Diesel Fuel ◽  
Oxidative Desulfurization ◽  
Catalytic Oxidative Desulfurization

Oxidative Desulfurization of Dibenzothiophene Catalyzed by Polyoxometalate-Based Ionic Liquid

2014 ◽  
Vol 1033-1034 ◽  
pp. 65-69
Author(s):  
Min Wang ◽  
Qin Wu ◽  
Han Sheng Li ◽  
Yun Zhao ◽  
Qing Ze Jiao
Keyword(s):  
Ionic Liquid ◽  
Sulfonic Acid ◽  
Sulfur Removal ◽  
Oxidative Desulfurization ◽  
Ionization Mass ◽  
Thermogravimetric Analyzer ◽  
Catalytic Oxidative Desulfurization ◽  
Ionization Mass Spectrum ◽  
Electrospray Ionization Mass Spectrum ◽  
Desulfurization Process

A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]3PW12O40), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]3PW12O40exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H2O2and CH3CN/H2O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.

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