scholarly journals Functionalized phosphonates as building units for multi-dimensional homo- and heterometallic 3d–4f inorganic–organic hybrid-materials

2016 ◽  
Vol 45 (32) ◽  
pp. 12854-12861 ◽  
Author(s):  
C. Köhler ◽  
E. Rentschler
Keyword(s):  
Single Crystal ◽  
Hybrid Materials ◽  
Magnetic Measurements ◽  
Diphosphonic Acid ◽  
Single Crystal Diffraction ◽  
Organic Hybrid ◽  
New Family ◽  
Multifunctional Ligand

Using the multifunctional ligand H4L (2,2′-bipyridinyl-5,5′-diphosphonic acid), a new family of 0D-3D inorganic–organic hybrid-materials was prepared and characterized by single crystal diffraction and magnetic measurements.

A vacuum chamber for low background diffraction experiments

1996 ◽  
Vol 211 (9) ◽  
Author(s):  
R. B. Neder ◽  
M. Burghammer ◽  
Th. Grasl ◽  
H. Schulz
Keyword(s):  
Single Crystal ◽  
Vacuum Chamber ◽  
Single Crystal Diffraction ◽  
Low Background

AbstractWe developed a small vacuum chamber for very low background single crystal diffraction experiments. The chamber has been designed for a large Eulerian cradle. The

Combined high resolution powder and single-crystal diffraction to determine the structure of Li1+xCeIIIxCeIV6-xF25

2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 455-460 ◽  
Author(s):  
G. Renaudin ◽  
E. Mapemba ◽  
M. El-Ghozzi ◽  
M. Dubois ◽  
D. Avignant ◽  
...  
Keyword(s):  
High Resolution ◽  
Single Crystal ◽  
Single Crystal Diffraction

scholarly journals Environmentally Friendly Nafion-Catalyzed Synthesis of Substituted 2-Ethyl-3-Methylquinolines from Aniline and Propionaldehyde under Microwave Irradiation

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 877
Author(s):  
Chieh-Kai Chan ◽  
Chien-Yu Lai ◽  
Cheng-Chung Wang
Keyword(s):  
Reaction Mechanism ◽  
Microwave Irradiation ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Environmentally Friendly ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Related Data ◽  
Heating Source ◽  
Chemical Structures

Herein, we report a facile synthetic methodology for the preparation of 2,3-dialkylquinolines from anilines and propionaldehydes. This cyclization involved environmentally friendly Nafion® NR50 as an acidic catalyst with microwave irradiation as the heating source. A series of substituted 2-ethyl-3-methylquinolines were prepared from various anilines and propionaldehyde derivatives through this protocol with good to excellent yields. Some new chemical structures were confirmed by X-ray single-crystal diffraction analysis and the related data were provided. The plausible reaction mechanism studies are also discussed.

Structure–Property Relationships in Photoluminescent Bismuth Halide Organic Hybrid Materials

2021 ◽  
Author(s):  
R. Lee Ayscue ◽  
Valérie Vallet ◽  
Jeffery A. Bertke ◽  
Florent Réal ◽  
Karah E. Knope
Keyword(s):  
Hybrid Materials ◽  
Structure Property ◽  
Organic Hybrid ◽  
Structure Property Relationships

scholarly journals Post‐synthetic modification unlocks a 2D‐to‐3D switch in MOF breathing response: a single‐crystal‐diffraction mapping study

2021 ◽  
Author(s):  
Lee Brammer ◽  
Elliot J. Carrington ◽  
Stephen F. Dodsworth ◽  
Sandra van Meurs ◽  
Mark R. Warren
Keyword(s):  
Single Crystal ◽  
Mapping Study ◽  
Single Crystal Diffraction ◽  
2D To 3D

New Methacrylate-Functionalized Ba and Ba−Ti Oxoclusters as Potential Nanosized Building Blocks for Inorganic−Organic Hybrid Materials:  Synthesis and Characterization

2007 ◽  
Vol 46 (9) ◽  
pp. 3459-3466 ◽  
Author(s):  
Alberto Albinati ◽  
Francesco Faccini ◽  
Silvia Gross ◽  
Guido Kickelbick ◽  
Silvia Rizzato ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Building Blocks ◽  
Synthesis And Characterization ◽  
Materials Synthesis ◽  
Organic Hybrid

scholarly journals Crystal structure of a new lithium iron vanadate

2014 ◽  
Vol 70 (a1) ◽  
pp. C1101-C1101
Author(s):  
Laurent Castro ◽  
Nicolas Penin ◽  
Dany Carlier ◽  
Alain Wattiaux ◽  
Stanislav Pechev ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Room Temperature ◽  
Magnetic Measurements ◽  
Charge Compensation ◽  
Li Ion Batteries ◽  
New Materials ◽  
Single Crystal Diffraction ◽  
Structural Relationships ◽  
Network Flexibility ◽  
Li Ion

Iron vanadates and phosphates have been widely explored [1-2] as possible electrode material for Li-ion batteries. In the goal of finding new materials, our approach was to consider existing materials and to investigate the flexibility of their network for possible substitutions. Among the different materials containing iron and vanadium, Cu3Fe4(XO4)6 (X = P, V) are isostructural to Fe7(PO4)6. Lafontaine et al. [3] discussed the structural relationships between β-Cu3Fe4(VO4)6 and several other vanadates, phosphates and molybdates of general formula AxBy(VO4)6. The interesting network flexibility was then demonstrated with the existence of four different crystallographic sites, which can be partially occupied depending on the x+y value : x+y = 7 for β-Cu3Fe4(VO4)6) and x+y = 8 for NaCuFe2(VO4)3. The LixFey(VO4)6 phase was then prepared considering the substitution of Li+ and Fe3+ for Cu2+ ions in β-Cu3Fe4(VO4)6 and the existence of an extra site to accommodate the charge compensation (7 ≤ x+y ≤ 8). As expected, a new lithium iron vanadate, isotructural to mineral Howardevansite was then obtained. Single crystal diffraction data were collected at room temperature on Enraf-Nonius CAD-4 diffractometer. Structure was refined with JANA-2006 program package. Mössbauer and magnetic measurements were also used to check the oxidation state of iron ions, to support the obtained crystal structure and to consider any possible structural/magnetic transitions. All the results will be presented and discussed in this presentation.

Sign in / Sign up

Export Citation Format

Share Document