Core-double shell ZnO/ZnS@Co3O4 heterostructure as high performance pseudocapacitor

2016 ◽  
Vol 45 (22) ◽  
pp. 9103-9112 ◽  
Author(s):  
Sanjit Sarkar ◽  
Sandipan Maiti ◽  
Sourindra Mahanty ◽  
Durga Basak
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance

ZnO/ZnS@Co3O4 pseudocapacitor with high specific capacitance and energy density.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

scholarly journals Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Xiaona Wang ◽  
Zhenyu Zhou ◽  
Zhijian Sun ◽  
Jinho Hah ◽  
Yagang Yao ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Superior Performance ◽  
High Mass ◽  
Mass Loading ◽  
Energy Storage Devices ◽  
Free Standing ◽  
Cell Potential

Abstract Coaxial fiber-shaped supercapacitors are a promising class of energy storage devices requiring high performance for flexible and miniature electronic devices. Yet, they are still struggling from inferior energy density, which comes from the limited choices in materials and structure used. Here, Zn-doped CuO nanowires were designed as 3D framework for aligned distributing high mass loading of MnO2 nanosheets. Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport. The Zn–CuO@MnO2 as positive electrode obtained superior performance without sacrificing its areal and gravimetric capacitances with the increasing of mass loading of MnO2 due to 3D Zn–CuO framework enabling efficient electron transport. A novel category of free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn0.11CuO@MnO2 core electrode possesses superior specific capacitance and enhanced cell potential window. This asymmetric coaxial structure provides superior performance including higher capacity and better stability under deformation because of sufficient contact between the electrodes and electrolyte. Based on these advantages, the as-prepared asymmetric coaxial fiber-shaped supercapacitor exhibits a high specific capacitance of 296.6 mF cm−2 and energy density of 133.47 μWh cm−2. In addition, its capacitance retention reaches 76.57% after bending 10,000 times, which demonstrates as-prepared device’s excellent flexibility and long-term cycling stability.

A high performance asymmetric supercapacitor based on in situ prepared CuCo2O4 nanowires and PPy nanoparticles on a two-ply carbon nanotube yarn

2018 ◽  
Vol 47 (47) ◽  
pp. 17146-17152 ◽  
Author(s):  
Xiao Liang ◽  
Qiufan Wang ◽  
Yun Ma ◽  
Daohong Zhang
Keyword(s):  
Carbon Nanotube ◽  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
Negative Electrode ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Asymmetric Supercapacitor

A two-ply CNT yarn asymmetric supercapacitor was fabricated by assembling a CuCo2O4 nanowire positive electrode and a PPy nanoparticle negative electrode. The full cell exhibits a high specific capacitance of 59.55 mF cm−2 and a high energy density of 0.02 mW h cm−2.

High performance two-ply carbon nanocomposite yarn supercapacitors enhanced with a platinum filament and in situ polymerized polyaniline nanowires

2016 ◽  
Vol 4 (10) ◽  
pp. 3828-3834 ◽  
Author(s):  
Qiufan Wang ◽  
Yunlong Wu ◽  
Ting Li ◽  
Daohong Zhang ◽  
Menghe Miao ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Composite Electrodes ◽  
Polyaniline Nanowires ◽  
Carbon Nanocomposite

A two-ply yarn supercapacitor fabricated from Pt/CNT@PANI nanowire composite electrodes exhibits a high specific capacitance of 91.67 mF cm−2and a high energy density of 12.68 μW h cm−2.

scholarly journals Facile synthesis of NiCo 2 S 4 /CNTs nanocomposites for high-performance supercapacitors

2018 ◽  
Vol 5 (9) ◽  
pp. 180953 ◽  
Author(s):  
Yunxia Huang ◽  
Ming Cheng ◽  
Zhongcheng Xiang ◽  
Yimin cui
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
Power Density ◽  
High Performance ◽  
Aqueous Electrolyte ◽  
High Current Density ◽  
Negative Electrode ◽  
High Specific Capacitance ◽  
Maximum Energy ◽  
Facile Synthesis

Herein, porous NiCo 2 S 4 /CNTs nanocomposites were synthesized via a simple hydrothermal method followed by the sulphurization process using different sulfide sources. By comparing two different sulfur sources, the samples using thioacetamide as sulfide source delivered more remarkable electrochemical performance with a high specific capacitance of 1765 F g −1 at 1 A g −1 and an admirable cycling stability with capacitance retention of 71.7% at a high current density of 10 A g −1 after 5000 cycles in 2 M KOH aqueous electrolyte. Furthermore, an asymmetric supercapacitor (ASC) device was successfully fabricated with the NiCo 2 S 4 /CNTs electrode as the positive electrode and graphene as the negative electrode. The device provided a maximum energy density of 29.44 W h kg −1 at a power density of 812 W kg −1 . Even at a high power density of 8006 W kg −1 , the energy density still reaches 16.68 W h kg −1 . Moreover, the ASC presents 89.8% specific capacitance retention after 5000 cycles at 5 A g −1 . These results reveal its great potential for supercapacitors in electrochemical energy storage field.

Electrochemical Performance of Cu Nanoparticle/Carbonized Wood Electrode for Supercapacitor Application

2014 ◽  
Vol 1678 ◽  
Author(s):  
Shiang Teng ◽  
Ashutosh Tiwari
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Cu Nanoparticles ◽  
Supercapacitor Electrode ◽  
Supercapacitor Application ◽  
Pseudocapacitive Behavior ◽  
Cu Nanoparticle ◽  
Carbonized Wood

ABSTRACTThe electrochemical effects of embedding Cu nanoparticles in carbonized wood supercapacitor electrodes have been investigated. The nanoparticles were embedded using a solution method. Subsequent X-ray diffraction (XRD) and scanning electron microscopy (SEM) results showed that the Cu nanoparticles were anchored uniformly on the surface and deep within the pores of the electrode. Cyclic voltammetry measurements showed that the electrode has typical pseudocapacitive behavior, with two pairs of redox reaction peaks. The charge-discharge cycling also indicated that the redox charge transformation was a reversible process. An ultra-high specific capacitance of 888 F/g and an energy density of 123 Wh/kg were observed for the Cu loaded electrodes, as compared to the pure carbonized wood electrodes, which had a specific capacitance of 282 F/g and an energy density of 39 Wh/kg. Furthermore, both the carbonized wood and Cu loaded electrodes exhibited excellent long cycle abilities with at least 95% of the specific capacitance retained after 2000 cycles. These remarkable results demonstrate the potential for using Cu nanoparticle loaded carbonized wood as a high performance and environmentally friendly supercapacitor electrode material.

Integrated copper–nickel oxide mesoporous nanowire arrays for high energy density aqueous asymmetric supercapacitors

2016 ◽  
Vol 1 (2) ◽  
pp. 150-155 ◽  
Author(s):  
Ruizhi Li ◽  
Zhijun Lin ◽  
Xin Ba ◽  
Yuanyuan Li ◽  
Ruimin Ding ◽  
...  
Keyword(s):  
Energy Density ◽  
Nickel Oxide ◽  
Specific Capacitance ◽  
High Performance ◽  
Nanowire Array ◽  
High Specific Capacitance ◽  
High Energy ◽  
Nanowire Arrays ◽  
High Energy Density ◽  
Asymmetric Supercapacitors

An integrated (Cu,Ni)O mesoporous nanowire array that delivers a high specific capacitance has been used to construct high-performance aqueous asymmetric supercapacitors of (Cu,Ni)O(+)//AC(−).

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